scholarly journals The impacts of Ba2Li2Si2O7:Sn2+,Mn2+ and CaMgSi2O6:Eu2+,Mn2+ particles on the optical properties of remote phosphor LED

2020 ◽  
Vol 38 (1) ◽  
pp. 197-205
Author(s):  
Ming-Jui Chen ◽  
Nguyen Thi Phuong Loan ◽  
Le Van Tho ◽  
Thuc Minh Bui ◽  
Phan Xuan Le ◽  
...  

AbstractAs implied in the title, the triple-layer remote phosphor (TRP), constructed with the yellow YAG:Ce3+ layer at the bottom, the red CaMgSi2O6:Eu2+,Mn2+ phosphor layer on the top, and the green Ba2Li2Si2O7:Sn2+,Mn2+ phosphor layer between these two layers, is suggested in this paper to improve the color and luminescence of white LEDs (WLEDs). In order to control the red light for the purpose of increasing the color rendering index (CRI), it is suggested that the red CaMgSi2O6:Eu2+,Mn2+ phosphor should be applied in the TRP structure. Simultaneously, the structure uses the green Ba2Li2Si2O7:Sn2+,Mn2+ phosphor layer to control the green light, which increases the luminous efficacy (LE) of WLEDs. In addition, when the concentration of these two phosphors increases, the yellow YAG:Ce3+ concentration must be reduced to keep the average correlated color temperatures (ACCTs) stable at 6000 K to 8500 K. Besides, appropriate adjusting of CRI, LE, and color quality scale (CQS) is also analyzed by modifying the concentration of the green phosphor and red phosphor. The results show that the CRI can get better values if CaMgSi2O6:Eu2+,Mn2+ concentration is higher. In contrast, the CRI decreases dramatically when the concentration of Ba2Li2Si2O7:Sn2+,Mn2+ increases. Meanwhile, CQS can be significantly increased in the range of 10 % to 14 % CaMgSi2O6:Eu2+,Mn2+, regardless of the concentration of Ba2Li2Si2O7:Sn2+,Mn2+. In particular, along with the improvement of CRI and CQS, LE can also be increased by more than 40 % by reducing the scattered light and adding the green light. Obtained results are a valuable reference for manufacturers for improving WLEDs color and luminescence quality to produce a broader range of WLEDs with better quality fulfilling social needs.

2020 ◽  
Vol 4 (1) ◽  
pp. 74
Author(s):  
Min-Feng Lai ◽  
Hsiao-Yi Lee ◽  
Doan Quoc Anh Nguyen

This study proposed a triple-layer remote phosphor (TRP) structure to improve the color and luminous flux of white LEDs (WLEDs). TRP structure consists of 3 different phosphor layers: yellow YAG:Ce3+ layer below, red CaMgSi2O6:Eu2+,Mn2+ phosphor on top and green layer Ba2Li2Si2O7:Sn2+,Mn2+  phosphor in the middle. Using red CaMgSi2O6:Eu2+,Mn2+ to control the red light component leads to increased color rendering index (CRI). Utilize the green CaMgSi2O6:Eu2+,Mn2+ phosphor to control the green light component results in the increase in luminous efficacy (LE) of WLEDs. Furthermore, when the concentration of these two phosphors increased, yellow layer concentration YAG:Ce3+ decreased to maintain average correlated color temperatures (ACCTs) in the range from 6000 K-8500K. Besides CRI and LE, color quality scale (CQS) is also analyzed through concentration control of green phosphor and red phosphor. The research results show that the higher the concentration of CaMgSi2O6:Eu2+,Mn2+, the better for CRI. In contrast, CRI decreased significantly when increasing the concentration of Ba2Li2Si2O7:Sn2+,Mn2+. Meanwhile, CQS achieve notable enhancement in the concentration range of 10% -14% CaMgSi2O6:Eu2+,Mn2+, regardless of Ba2Li2Si2O7:Sn2+,Mn2+ concentration. LE, in particular, can also increase by more than 40% along with the improvement of CRI and CQS with the reduction of the backscattered light and addition of green light. Research results are a valuable reference for producers who wish to improve the color quality and enhance the luminous flux of WLEDs. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium provided the original work is properly cited.


2021 ◽  
Vol 10 (5) ◽  
pp. 2513-2519
Author(s):  
Dieu An Nguyen Thi ◽  
Phung Ton That ◽  
Hoang Nam Nguyen

The concept of the analysis is to put a CaAl2O4:Mn2+ green phosphor layer on top of the YAG:Ce3+ yellow phosphor layer. After that, find the added CaAl2O4:Mn2+ concentration appropriate for the highest luminous flux (LF) and color homogeneity (CH). In this analysis, five equivalent WLEDs were applied but with distinct color temperatures, including 5600 K - 8500 K. The findings showed that CaAl2O4:Mn2+ brings great benefits to increase not only the luminous flux but also the color homogeneity. Especially, the higher the CaAl2O4:Mn2+ concentration, the more the luminous flux released by WLEDs, owing to the risen content of the light of green in WLEDs. Nevertheless, as the CaAl2O4:Mn2+ concentration raised significantly, a small reduction in the color rendering metric (CRI) and color quality scale (CQS) occurred. This is supported by simulation and calculation according to the theory of Monte Carlo. The paper results are the crucial contribution to the manufacture of WLEDs with better optical performance and color homogeneity of remote phosphor configurations.


2021 ◽  
Vol 10 (4) ◽  
pp. 1930-1935
Author(s):  
Phan Xuan Le ◽  
Le Hung Tien

Among the structures using for fabricating white light-emitting diodes (WLEDs) such as the conformal coating or in-cup geometries, the remote phosphor structure gives the highest luminous efficacy. However, in terms of color quality, its performance is not as good as the others. The red-light compensation has been reported as the effective solution for enhancing the color quality of WLEDs. Hence, this study adopted the idea and applied to the dual-layer phosphor structure. The phosphor used to boost the red color in light formation is (Y,Gd)BO3:Eu particle. The dual-layer remote phosphor structure was simulated with the red (Y,Gd)BO3:Eu phosphor layer above the original yellow phosphor YAG:Ce3+ one. The WLEDs with different correlated color temperatures of 5600 K, 6600 K and 7700K were experimented. Mie-theory and Lambert-Beer law were applied to examine the results. The growth in color rendering index (CRI) and color quality scale (CQS) with the increase of (Y,Gd)BO3:Eu phosphor concentration was observed. Nevertheless, the lumen efficacy would be degraded if the concentration was over a certain number. The information provided in this article is useful for the development of high-power WLED production with greater color quality.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
My Hanh Nguyen Thi ◽  
Phung Ton That ◽  
Nguyen Doan Quoc Anh ◽  
Tran Thanh Trang

Abstract The remote phosphor as a lighting structure has outstanding luminous efficiency compared to other options, such as conformal or in-cup. However, the lack of uniformity in distributed color has prevented remote phosphor from wider development. The answer to the chromatic performance enhancement that has been suggested by numerous researchers is the multi-layer configuration with two or three different types of chromatic phosphor. The research purpose is to select the best configuration for multi-chip white LEDs (WLEDs) to achieve optimal results in color quality scale (CQS), color rendering index (CRI), light output and color homogeneity. WLEDs mentioned in this paper have two distinct color temperatures, 6600 K and 7700 K. Experimental results show that the remote phosphor structure with three phosphor layers is superior in terms of color rendering, chromatic performance, and emitted light. The deviation of correlated color measured in this structure is also low, which means that the color uniformity is greatly enhanced in this multi-layer lighting structure. This result can be demonstrated by analyzing the scattering characteristics of the phosphoric layers using the Mie theory. The research findings have proven the effectiveness of the multi-phosphor configuration and can serve as a guideline to fabricate WLEDs with better performance.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Phung Ton That ◽  
Nguyen Thi Phuong Loan ◽  
Le Van Tho ◽  
Nguyen Doan Quoc Anh ◽  
Hsing-Yuan Liao ◽  
...  

Abstract Usually, remote phosphor structures are beneficial in terms of flux but unfavorable in terms of color quality compared to conformal phosphor or in-cup phosphor packages. To eliminate this disadvantage, many studies have focused on increasing the chromatic quality of the remote phosphor configuration, which requires great efforts in improving two parameters of color: color rendering index (CRI) and color quality scale (CQS). CRI is known as the most useful quantitative method used to measure the ability of a light source to reproduce the colors of illuminated objects faithfully and naturally. Similarly, CQS is also a method of lighting quality determination and analysis, especially used as an alternative to the unsaturated CRI colors. In this paper, we proposed dual-layer remote phosphor structure as a novel method of CRI and CQS enhancement to improve WLEDs’ color quality. Five alike WLEDs but having different color temperatures in the range of 5600 K to 8500 K were applied in this study. The idea behind the study is to place a red phosphor layer SrwFxByOz:Eu2+,Sm2+ on the yellow phosphor layer YAG:Ce3+ and then determining an appropriate concentration of SrwFxByOz:Eu2+,Sm2+ added to achieve the highest color quality. The results point out that SrwFxByOz:Eu2+,Sm2+ brings great benefits to the improvement of CRI and CQS parameters. Specifically, the higher the SrwFxByOz:Eu2+,Sm2+ concentration results in the greater CRI and CQS, owning to the enriched red light components in the WLEDs. However, the flux has a tendency of dropping when SrwFxByOz:Eu2+,Sm2+ concentration rises excessively. This has been proved by using the Mie-scattering theory and the Lambert-Beer law. The results of this article are essential references for manufacturing WLEDs with higher chromatic quality.


Author(s):  
Phung Ton That ◽  
Thuc Minh Bui ◽  
Nguyen Thi Phuong Loan ◽  
Phan Xuan Le ◽  
Nguyen Doan Quoc Anh ◽  
...  

The effects of red light-emitting phosphor CaMgSi2O6:Eu2+,Mn2+ on the optical properties of single-layer remote phosphor structure (SRPS) and dual-layer remote phosphor structure (DRPS) are the focus of this study. The differences in color quality and luminous flux (LF) of white light-emitting diodes (WLEDs) between these two structures are also revealed and demonstrated based on the Mie theory. SRPS consists of one mixed phosphor layer betweenCaMgSi2O6:Eu2+,Mn2+ andYAG:Ce3+particles, while DRPS includes two separated layers: red phosphor layer and yellow phosphor layer. In this work, 5% SiO2 is added into the phosphor layers to increase scattering abilities. Discrepancies in structures greatly affect the optical characteristics of WLEDs. The results showed that the color rendering index (CRI) increased with the concentration in both structures with nearly equal values. Meanwhile, color quality scale (CQS) of DPRS is 74 at ACCTs ranging from 5600K to 8500K, higher than CQS of SRPS which is only 71 at 8500K. In addition, the luminous flux of DRPS is significantly higher than SRPS at 2% -14% of CaMgSi2O6:Eu2+,Mn2+. In summary, DRPS is better for color quality and lumen outputin comparison to SRPS and adding the right amount of red phosphor can enhance CQS and LF.


2019 ◽  
Vol 3 (3) ◽  
pp. 464
Author(s):  
Hsiao-Yi Lee ◽  
Phan Xuan Le ◽  
Doan Quoc Anh Nguyen

In terms of luminous flux, the remote phosphor structure is better than conformal structure or in-cup phosphor structure, however, this structure often has inferior color quality compared to the others. As a result, many studies have been conducted to nd a solution to the drawback mentioned above. In this research, we are after the same goal using WLEDs structure with color temperature of 5600 K and come to the conclusion that dual-layer phosphor structure can improve the color rendering index (CRI) and the color quality scale (CQS). The concept of the research is to place red phosphor layer Mg2TiO4:Mn4+ on a yellow phosphor layer YAG:Ce3+ and locate the concentration of Mg2TiO4:Mn4+ that allows the color quality to reach the highest value. The result shows that Mg2TiO4:Mn4+ benets CRI and CQS, more specifically, the addition of Mg2TiO4:Mn4+ in WLEDs boosts the red light component, thus, enhancing CRI and CQS. However, it is demonstrated through the application of Mie-scattering theory and Lambert-Beer law that when the concentration of Mg2TiO4:Mn4+ exceed the limit, it can harm the luminous flux of WLEDs. The result of this research is a valuable contribution to improving the techniques of manufacturing better WLEDs with higher white light quality.  This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium provided the original work is properly cited.


2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Guo-Feng Luo ◽  
Nguyen Thi Phuong Loan ◽  
Le Van Tho ◽  
Nguyen Doan Quoc Anh ◽  
Hsiao-Yi Lee

AbstractSiO2 particles and red-emitting CaMgSi2O6:Eu2+,Mn2+ phosphor have been added into a yellow phosphor compound YAG:Ce3+ to enhance the optical efficiency of white light LEDs whose average correlated color temperature (CCT) is in the range of 5600 K ÷ 8500 K. It was observed that altering CaMgSi2O6:Eu2+,Mn2+ concentration from 2 % to 30 % while maintaining 5 % of the SiO2 strongly influenced the color rendering index (CRI), color quality scale (CQS), and lumen efficiency of the compound. Besides, through the application of Monte Carlo simulation and Mie-scattering theory, it was possible to improve the optical properties by CaMgSi2O6:Eu2+,Mn2+ and SiO2 addition. The results provided a practical approach to achieve higher luminous efficiency and better color uniformity in remote-phosphor white LEDs (RP-WLEDs).


2017 ◽  
Vol 35 (3) ◽  
pp. 618-625
Author(s):  
Tran Hoang Quang Minh ◽  
Nguyen Huu Khanh Nhan ◽  
Nguyen Doan Quoc Anh ◽  
Hsiao-Yi Lee

AbstractThis paper investigates a method for improving the lighting performance of white light-emitting diodes (WLEDs), packaged using two separating remote phosphor layers, yellow-emitting YAG:Ce phosphor layer and red-emitting α-SrO·3B2O3:Sm2+ phosphor layer. The thicknesses of these two layers are 800 μm and 200 μm, respectively. Both of them have been examined at average correlated color temperatures (CCT) of 7700 K and 8500 K. For this two-layer model, the concentration of red phosphor has been varied from 2 % to 30 % in the upper layer, while in the lower layer the yellow phosphor concentration was kept at 15 %. It was found interesting that the lighting properties, such as color rendering index (CRI) and luminous flux, are enhanced significantly, while the color uniformity is maintained at a level relatively close to the level in one-layer configuration (measured at the same correlated color temperature). Besides, the transmitted and reflected light of each phosphor layer have been revised by combining Kubelka-Munk and Mie-Lorenz theories. Through the analysis, it is demonstrated that the packaging configuration of two-layered remote phosphor that contains red-emitting α-SrO·3B2O3:Sm2+ phosphor particles provides a practical solution to general WLEDs lighting.


2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Guo-Feng Luo ◽  
Nguyen Thi Phuong Loan ◽  
Le Van Tho ◽  
Phung Ton That ◽  
Nguyen Doan Quoc Anh ◽  
...  

AbstractThe remote phosphor structure produces higher luminous flux but delivers poorer color quality than the conformal or in-cup phosphor structure. To eliminate this weakness, researchers have attempted to improve the chromatic properties of remote phosphor package. This study tends to enhance lighting features for WLEDs including color quality and luminous flux in general or color rendering index (CRI) and color quality scale (CQS) in particular by applying dual-layer remote phosphor structure. In the simulation section, we utilize two identical LEDs that only differ in correlated color temperature values which are 6600 K and 7700 K. The study offers an idea of placing a yellow-green phosphor layer SrBaSiO4:Eu2+ or a red phosphor layer SrwFxByOz:Eu2+,Sm2+ on the yellow phosphor layer YAG:Ce3+ and then modifying the concentrations of SrwFxByOz:Eu2+,Sm2+ and SrBaSiO4:Eu2+ to the suitable values to improve the color quality and lumen output of WLEDs. The results show that red phosphor layer SrwFxByOz:Eu2+,Sm2+ has a significant influence on CRI and CQS improvement. Particularly, the increase of SrwFxByOz:Eu2+,Sm2+ concentration leads to increased CRI and CQS because the red light component increases in WLEDs. On the other hand, the green phosphor layer SrBaSiO4:Eu2+ only brings benefit to the luminous flux. However, the WLEDs’ luminous flux and color quality drop sharply, when SrwFxByOz:Eu2+,Sm2+ and SrBaSiO4:Eu2+ concentrations rise extremely, which is verified based on the Mie-scattering theory and the Lambert-Beer law. In short, the article provides general knowledge and primary information for the production of higher-quality WLEDs.


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