Simultaneous Experimental Analysis of Oil Content And Molecular Composition of Shale Fractions

The important research content and basis of exploration and development is to evaluate the reservoir property, oil bearing property, fluidity and compressibility of shale reservoir.The key of exploration and development is to evaluate the oil-bearing and fluidity of shale reservoir.In this paper, the "shale oil content and fine components synchronous experimental analysis device" is used. Five temperature ranges of 30 ℃-90 ℃, 90 ℃-150 ℃, 100 ℃- 200 ℃, 150 ℃-250 ℃ and 250 ℃-300 ℃ were adopted. The heating rate of each temperature segment was 25 ℃ / min, and the final temperature was kept constant for 5 min. The oil content of shale (pyrolysis S1) was cut into five fractions.Simultaneous determination of oil content and molecular composition of shale fractions,and the external standard method was used to evaluate the oil content and fluidity.The results show that the five fractions of shale are mainly composed of nC1-nC9 gas, nC10-nC15 gasoline, nC12-nC20 kerosene, nC15-nC22 diesel oil and nC18-nC26 heavy oil of the first member of Qingshangkou formation in Songliao basin.There are differences in the fractionation and oil content characteristics of samples with different maturity in different wells.The parent material, properties and quality of crude oil are reflected in shale. The higher the maturity of shale oil is, the more light components are, the larger the light / heavy ratio parameter value of (gasoline + kerosene + diesel) and heavy oil is, the better the fluidity is, and the easier to exploit effectively.

Petroleum Hydrocarbon Quarterly Boiling Range Distribution of Iraqi Crude Oil by Simulated Distillation Method

This study includes analysis of different crude oil stock for various field Iraqi oil by gas chromatography instrument, using simulated distillation technique for determining the initial and final boiling point distribution and specified compound distillation information (normal paraffins) (Recovery W/W) for (nC5 – nC44), ASTM-D5307 becomes the analytical method. This method need tow samples; the first one spiked with internal standard and the second without internal standard. This analysis for quantitative and qualitative oil characterization which is often useful for evaluating the range of hydrocarbons in crude oil using Simulated Distillation. The study was performed using: Quarterly analysis of SIMDIS GC Distillation for three field (East Baghdad, Badra, Amara) Comparison of analyzes of SIMDIS GC Distillation with Different API (light, intermediate, heavy) with Initial boiling point (IBP). Finding experimental relationship between API and Initial boiling point (IBP): The result of this study shows that the boiling point increase as the number of carbon is increase, the values of n-Pentane (nC5) to n- Tetratetracontane (nC44) (w/w) changes from winter and summer (difference in temperatures), Positive correlation between C6 and C5 with API, where their percentages increase with increasing API for crude oil and C6 and C5 are lower in summer than in winter due to the evaporation of light components of the samples in summer. Initial boiling point increase as the API is decrease that mean in crude oil have heavy component increases and light component decrease (inverse relationship).

Daily Administered Dual-Light Photodynamic Therapy Provides a Sustained Antibacterial Effect on Staphylococcus aureus

New means to reduce excessive antibiotic use are urgently needed. This study tested dual-light aPDT against Staphylococcus aureus biofilm with different relative ratios of light energy with indocyanine green. We applied single-light aPDT (810 nm aPDT, 405 aBL) or dual-light aPDT (simultaneous 810 nm aPDT and 405 nm aBL), in both cases, together with the ICG photosensitizer with constant energy of 100 or 200 J/cm2. Single-dose light exposures were given after one-day, three-day, or six-day biofilm incubations. A repeated daily dose of identical light energy was applied during biofilm incubations for the three- and six-day biofilms. Using 100 J/cm2 light energy against the one-day biofilm, the dual-light aPDT consisting of more than half of aBL was the most effective. On a three-day maturated biofilm, single-dose exposure to aPDT or dual-light aPDT was more effective than aBL alone. With total light energy of 200 J/cm2, all dual-light treatments were effective. Dual-light aPDT improves the bactericidal effect on Staphylococcus aureus biofilm compared to aPDT or aBL and provides a sustained effect. An increase in the relative ratio of aBL strengthens the antibacterial effect, mainly when the treatment is repeatedly applied. Thus, the light components’ energy ratio is essential with dual-light.

Multiscale mechanisms of asphalt performance enhancement by crumbed waste tire rubber: Insight from molecular dynamics simulation

The recycling of crumbled waste tire rubber (CWTB) is a major environmental problem facing mankind, and the incorporation of CWTB as a modifier into asphalt is an extremely promising approach. However, the modification mechanism of CWTB to asphalt is not well understood, which restricts the development of CWTB-modified asphalt. In this study, the mechanism of CWTB modification of asphalt was explored in depth by dynamic mechanical analysis (DMA), fluorescence microscopy, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and molecular dynamics (MD) simulations. The results of the study showed that CWTB enhanced the high temperature performance of the base asphalt. The microscopic mechanism by which this phenomenon occurs is that CWTB has the largest binding energy with the aromatics (1100–1400 kcal/mol), followed by the saturates (700–900 kcal/mol), followed by the resins (200–450 kcal/mol), and the smallest binding energy with the asphaltenes (110–160 kcal/mol), which causes CWTB to absorb the light components of the asphalt (aromatics and saturates). In the process of absorbing the light components, CWTB will gradually swell, which causes CWTB to bind more and more tightly with the base asphalt, and eventually the good high temperature performance of CWTB is transferred to the base asphalt. The macroscopic manifestation of this process is that the rutting factor of CWTB modified asphalt is significantly higher than that of virgin asphalt. This study can provide basic theoretical support for the application of CWTB modified asphalt.

Enhancing color quality of WLEDs with dual-layer remote phosphor geometry

Usually, remote phosphor structures are beneficial in terms of flux but unfavorable in terms of color quality compared to conformal phosphor or in-cup phosphor packages. To eliminate this disadvantage, many studies have focused on increasing the chromatic quality of the remote phosphor configuration, which requires great efforts in improving two parameters of color: color rendering index (CRI) and color quality scale (CQS). CRI is known as the most useful quantitative method used to measure the ability of a light source to reproduce the colors of illuminated objects faithfully and naturally. Similarly, CQS is also a method of lighting quality determination and analysis, especially used as an alternative to the unsaturated CRI colors. In this paper, we proposed dual-layer remote phosphor structure as a novel method of CRI and CQS enhancement to improve WLEDs’ color quality. Five alike WLEDs but having different color temperatures in the range of 5600 K to 8500 K were applied in this study. The idea behind the study is to place a red phosphor layer SrwFxByOz:Eu2+,Sm2+ on the yellow phosphor layer YAG:Ce3+ and then determining an appropriate concentration of SrwFxByOz:Eu2+,Sm2+ added to achieve the highest color quality. The results point out that SrwFxByOz:Eu2+,Sm2+ brings great benefits to the improvement of CRI and CQS parameters. Specifically, the higher the SrwFxByOz:Eu2+,Sm2+ concentration results in the greater CRI and CQS, owning to the enriched red light components in the WLEDs. However, the flux has a tendency of dropping when SrwFxByOz:Eu2+,Sm2+ concentration rises excessively. This has been proved by using the Mie-scattering theory and the Lambert-Beer law. The results of this article are essential references for manufacturing WLEDs with higher chromatic quality.

Research on the Mechanism of Interaction between Styrene–Butadiene–Styrene (SBS) and Asphalt Based on Molecular Vibration Frequency

Based on the four-component theory of asphalt, molecular models of the saturate, aromatic, resin, and asphaltene were constructed, respectively. The styrene–butadiene–styrene (SBS) polymer was used as the modifier. Using density functional theory (DFT) to study the effect of SBS on the molecular vibration of each component of asphalt, the vibration spectrums and binding energy of the systems composed of SBS and each component molecule of asphalt were calculated. Prepared SBS modified asphalt and measured Fourier transform infrared spectroscopy (FTIR) before and after the experiment. The results show that after SBS was added to asphalt, no chemical reaction occurred, and the system was mainly physical blending. The vibrational peak intensity of SBS and the light components of asphalt (saturate and aromatic) is stronger than that of SBS and the heavy components of asphalt (resin and asphaltene). The interaction strengths of asphalt components and polybutadiene (PB) blocks, polystyrene (PS) blocks of SBS are different. The binding energy of SBS and the saturate is the lowest and the bonding of the system is weakest. The bonding of the systems of SBS and the aromatic, resin, asphaltene is stable, and the stability of these systems are all stronger than that of SBS and the saturate.

Research on Quantum Confinement Effect and Enhanced Luminescence of Red-emitting Phosphors P5+-doped CaAl12O19:Mn4+,Mg2+

Mn4+-activated oxide red phosphors is always a hot topic in the luminescent material field to solve the lack of red light components in white-light-emitting diodes (WLEDs). Herein, a series of...

Super-Earths, M Dwarfs, and Photosynthetic Organisms: Habitability in the Lab

In a few years, space telescopes will investigate our Galaxy to detect evidence of life, mainly by observing rocky planets. In the last decade, the observation of exoplanet atmospheres and the theoretical works on biosignature gasses have experienced a considerable acceleration. The most attractive feature of the realm of exoplanets is that 40% of M dwarfs host super-Earths with a minimum mass between 1 and 30 Earth masses, orbital periods shorter than 50 days, and radii between those of the Earth and Neptune (1–3.8 R⊕). Moreover, the recent finding of cyanobacteria able to use far-red (FR) light for oxygenic photosynthesis due to the synthesis of chlorophylls d and f, extending in vivo light absorption up to 750 nm, suggests the possibility of exotic photosynthesis in planets around M dwarfs. Using innovative laboratory instrumentation, we exposed different cyanobacteria to an M dwarf star simulated irradiation, comparing their responses to those under solar and FR simulated lights. As expected, in FR light, only the cyanobacteria able to synthesize chlorophyll d and f could grow. Surprisingly, all strains, both able or unable to use FR light, grew and photosynthesized under the M dwarf generated spectrum in a similar way to the solar light and much more efficiently than under the FR one. Our findings highlight the importance of simulating both the visible and FR light components of an M dwarf spectrum to correctly evaluate the photosynthetic performances of oxygenic organisms exposed under such an exotic light condition.

Changes in the Compressive Strength of Concrete in Thin Horizontally Formed Slabs

During compaction of a concrete mix, when thin slabs are formed in a horizontal position, the components of this mix become segregated. Heavy components fall to the bottom, and light components (air and water) move to the top. This process may suggest that the upper layers of concrete elements formed in a horizontal position may have lower compressive strength than the remaining part of the element. This problem is recognized and documented in many publications, but there was a publication whose test results indicate a lack of variability in the compressive strength of concrete across the thickness of tested elements. The discrepancies appearing in the evaluation of concrete homogeneity was the reason for conducting destructive tests of the compressive strength of concrete across the thickness of horizontally concreted test elements that imitate thin slabs. The obtained results of the destructive compressive strength confirmed previous results regarding the heterogeneity of concrete. They clearly indicate that there is a differentiation of the compressive strength of concrete across the thickness of a thin element, which remained in a liquefied state for a certain time during its formation. The longer the duration of this state across the entire thickness of the formed element, the greater the differentiation of the compressive strength between the top and bottom layers.