Using CaCO3-doped package to improve correlated color temperature uniformity of white light-emitting diodes

<span>The white light-emitting diode (WLED) has been the most advance lighting method currently, however, the fabrication process of this configuration still has drawbacks which negatively affect its color quality. This research was conducted to provide a method for WLED’s lighting output enhancement. Since CaCO₃ particles are excellent for thermal stability enhancement, especially when being combined with an adhesive substance, we decided to integrate CO₃ particles into resin matrix such as melamine formaldehyde (MF) and investigate their influences on the optical properties, including color uniformity and lumen output, of the WLED. The results showed that CaCO3 and MF resin are beneficial to the light scattering efficiency, which results in higher luminous flux and chromatic quality for WLED packages. In addition to that, the appropriate amounts of MF resin and CaCO₃ for reaching the best lumen efficiency and color quality are figured out at 1% and 10%, respectively. Moreover, another advantage of using MF resin and CaCO₃ for fabricating WLEDs is cost effectiveness. Hence, it has turned out that CaCO₃ and MF resins can be potential materials for next high-quality WLED generations.</span>

Using SiO2 nano-particles for better color uniformity and lumen output in 8500 K conformal and in-cup white LEDs

<span>In the effort of improving the performance of white light LEDs devices (WLEDs), the SiO₂ nano-particles were applied and have shown a significant impact on the optical properties. Specifically, the light output of the lighting devices is enhanced when a mixture of SiO₂ particles and silicone gel is diffused on the encapsulation layer surface. This enhancement is the result of light scattering from SiO₂ that strengthens the emitted blue light at further angles and reduces the color discrepancy. The evidence is that CCT deviation in SiO₂-doped structure decline from 1000 K to 420 K in -70° to 70°. In addition, the SiO₂ with refractive index in between the phosphor material and outside environment allows light to be emitted outward more effectively. This lighting enhancement of SiO₂-doped structure increases the lumen output by 2.25% at 120 mA power source in comparison to structure without SiO₂. These experimental outcomes suggest that SiO₂ is an effective material to add in WLEDs structure for better lighting efficiency.</span>

Micro-Prism Patterned Remote Phosphor Film for Enhanced Luminous Efficiency and Color Uniformity of Phosphor-Converted Light-Emitting Diodes

In this work, we propose micro-prism patterned remote phosphor (RP) films to enhance both luminous efficiency and color uniformity (CU) of remote phosphor-converted light-emitting diodes (rpc-LEDs) simultaneously. On the incident surface of the RP film, one micro-prism film is used to extract backward light by double reflection. On the exit surface, the other micro-prism film is adopted to retain blue light inside the RP film, thus enhancing the phosphor excitation. Experimental results show that double prism-patterned RP (DP-RP) film configuration shows a luminous flux of 55.16 lm, which is 45.1% higher than that of RP film configuration at 300 mA. As regards the CU, the DP-RP film configuration reduces the angular CIE-x and CIE-y standard variations by 68% and 69.32%, respectively, compared with the pristine device. Moreover, the DP-RP film configuration shows excellent color stability under varying driving currents. Since micro-prism films can be easily fabricated by a roll-to-roll process, the micro-prism patterned RP film can be an alternative to a conventional RP layer to enable the practical application of rpc-LEDs.

Applying SiO2 nano-particles for improving optical properties of WLED conformal and in-cup structures

This article is the analysis of SiO2 nano-particles’ influences on the luminous efficiency and the color temperature uniformity of a remote phosphor structure in a WLED. The purpose of integrating SiO2 into the silicone layer in the remote phosphor structure is to significantly promote the scattering occurrences. Particularly, with an appropriate proportion of SiO2, there could be more blue lights generated at large angles, leading to reducing the angular-dependent color temperature deviation. The luminous flux also can get benefits from SiO2 addition owing to a proper air-phosphor layer refractive index ratio provided by this SiO2/silicone compound. The attained experimental results were compared with optical values of a non-SiO2 remote phosphor configuration and showed a notable enhancement. The color deviation was reduced by approximately 600 K in the angles from -700 ­to 700. Additionally, the lumen efficiency was improved by 2.25% at 120 mA driving current. Hence, SiO2 can be used to boost both color uniformity and luminous efficacy for remote-phosphor WLED.

Improving the optical efficiency of white light-emitting diodes based on phosphor-in-glass by a dual-layer remote phosphorus structure with the application of LiLaO2:Eu3+ and CaSO4:Ce3+, Mn2+

While the remote phosphor structure is not an appropriate solution for WLED color uniformity, it is more advantageous for the luminous output of WLED than the conformal phosphor or in-cup phosphor structure. Acknowledging the ability of the remote phosphor structure, many studies have been carried out to surmount the color quality disadvantage of this structure. A dual-layer remote phosphor configuration is proposed in this research paper to acquire better color quality for WLEDs through heightening the color rendering index (CRI) and the color quality scale (CQS). The color temperature of the WLED packages this study is 8500 K. By inserting a layer of green CaSO4:Ce3+,Mn2+ or red LiLaO2:Eu3+ phosphor on the yellow YAG:Ce3+ phosphor layer, the phosphor structure configuration can be constructed. Then, to get the best color quality, the concentration of added phosphor LiLaO2:Eu3+ would be changed. The findings showed the rise of CRI and CQS along with the LiLaO2:Eu3+, which implies the influence of LiLaO2:Eu3+ to the growth of red light components within WLEDs packages. The greater the concentration of LiLaO2:Eu3+ is, the more the CRI and CQS increase. Meanwhile, the luminous flux gains from the green phosphor CaSO4:Ce3+,Mn2+. Nevertheless, the luminous flux and color quality would decrease if the concentrations of both red LiLaO2:Eu3+ and green CaSO4:Ce3+,Mn2+ phosphors reach a certain corresponding level. Centered on the Mie-scattering theory and the law of Lambert-Beer, this result is illustrated. The findings in this research are vital references for manufacturing WLEDs with higher white light performance.

Combination of wet fixation and drying treatments to improve dye fixation onto spray-dyed cotton fabric

The conventional dyeing process requires a substantial amount of auxiliaries and water, which leaches hazardous colored effluents to the environment. Herein, a newly developed sustainable spray dyeing system has been proposed for cotton fabric in the presence of reactive dyes, which has the potential to minimize the textile dyeing industries environmental impact in terms of water consumption and save significant energy. The results suggest that fresh dye solution can be mixed with an alkali solution before spray dyeing to avoid the reactive dye hydrolysis phenomenon. After that, drying at 60–100 °C, wet fixation treating for 1–6 min, and combined treatments (wet fixation + drying) were sequentially investigated and then dye fixation percentages were around 63–65%, 52–70%, and above 80%, respectively. Following this, fixation conditions were optimized using L16 orthogonal designs, including wet fixation time, temperature, dye concentration, and pH with four levels where the “larger-the-better” function was selected to maximize the dye fixation rate. Additionally, the color uniformity and wash and rubbing fastnesses were at an acceptable level when both treatments were applied. Finally, the dyes were hydrolyzed after wet fixation, and the hydrolysis percentages were enhanced after the drying process.

Analysis of the Visual Appearance of AISI 430 Ferritic Stainless Steel Flat Sheets Manufactured by Cool Rolling and Bright Annealing

This article reports on the relation between the surface topography and the optical reflectance, both total and diffuse, of different samples of AISI 430 ferritic stainless steel. Gaussian filters with different cutoff wavelengths were applied to the height maps of the surface topography of the samples, to separate the different scales of surface roughness involved in optical scattering in the visible range of the spectrum. Significant anisotropy, related to the rolling process, was found in the topography. An effective roughness slope parameter was defined from the dependence of the ratio between the root mean square height and the autocorrelation length on the cutoff wavelength. This roughness slope demonstrated an exceptionally good linear relationship with CIE 1931 luminance, which was calculated from the diffuse reflection spectra. The color uniformity of the samples was analyzed based on their CIE L*a*b* coordinates under daylight and LED illumination. The results confirmed the strong influence of manufacturing process on the surface characteristics of AISI 430 ferritic stainless steel sheet products with a bright finish.