scholarly journals Rare earth elements and yttrium in calcite and pyrite of the Orlovka gold deposit (the Southern Urals)

LITOSFERA ◽  
2017 ◽  
pp. 135-141 ◽  
Author(s):  
S. E. Znamensky ◽  
Author(s):  
A. V. Maslov

Information on the distribution of trace and rare-earth elements in the bottom sediments of estuarine zones of various river categories (large rivers, rivers draining water collections, composed of sedimentary or magmatic and metamorphic rocks, etc.) of silt and pelitic dimensions can be considered as the data, reflecting characteristic features of the suspention, transported to marine basins from various catchment provinces. In certain situations, the composition of the surface bottom sediments of the marine basin is determined by the suspension composition of any large river flowing into it (the Caspian Sea and the Volga River, the Laptev Sea and the Lena River, etc.). The similarity and difference in the rare-earth elements (REE) systematics of bottom sediments of estuarine zones and suspended particulate matter of rivers of various categories is quite well expressed in the pair diagrams (La/ Yb)N–(Eu/Sm)N, (La/Yb)N–Th, etc. A comparison of the features of the distribution of REE and Th in the Riphean clay rocks of the Southern Urals and in bottom sediments of the estuaries of various categories of recent rivers has been performed. It has been concluded that clay rocks forming a typical Riphean section are formed due to the erosion of mainly or predominantly sedimentary and/or metasedimentary complexes that existed during the PreRiphean or the Riphean in the east part of the East European platform and have not survived to date.


LITOSFERA ◽  
2020 ◽  
Vol 20 (4) ◽  
pp. 573-591
Author(s):  
S. G. Kovalev ◽  
S. V. Michurin ◽  
A. V. Maslov ◽  
A. A. Sharipova

Research subject. The object of the study is the Ulyuk-Bar gold deposit ore-bearing rocks, located in the Bashkir meganticlinorium (the Southern Urals). Methods. The article presents the first data on the distribution of rare earth elements (REE), platinum group elements (PGE) and Au, obtained by inductively coupled plasma mass spectrometry (ICP-MS) on “ELAN- 6100 DRC” and “Agilent 7700” with the use of the computer data processing program “TOTALQUANT”, which includes automatic accounting of isotopic and molecular overlays on the mass spectral analytical lines of the determined elements. The chemical composition of ore minerals (native gold, pyrite, pyrrhotite, gersdorfite, chalcopyrite, arsenopyrite, and galena) was determined using an REMMA-202M scanning electron microscope with an LZ-5 X-ray energy-dispersive spectrometer and detectors for secondary and reflected electrons. Results. As a result of the studies, the enrichment of heavy lanthanides from ore-bearing rocks of the Ulyuk-Bar deposit in comparison with the sandstones and shales of the Bolshoi Inzer Formation outside of the ore field was established. It is shown that the noble-metal geochemical specialization of ore-bearing sediments of the Bolshoi Inzer Formation of the Ulyuk-Bar deposit is similar in a number of parameters to rocks of the Mashak Formation of the Shatak complex, formed under the influence of Middle Riphean magmatism on sedimentary rocks of the upper layers of the earth’s crust. Based on the calculation of the age of the minerals thorium and uranium, according to the isotopic studies of Rb-Sr (996 ± 26 Ma) and K-Ar (676–706 Ma) methods and galena by the Pb-Pb method (950 Ma), it was established that mineralization was formed in two stages. The first of which is associated with tectono-thermal activation at the border of the Middle and Late Riphean, and the second was realized about 600 Ma ago. Conclusions. It is concluded that the REE-EPG-Au taxonomy of ore-bearing deposits of the Ulyuk-Bar deposit is due to the polychrony and polygenicity of ore formation processes associated with the Middle Riphean plume magmatism, manifested over a vast territory, and the Late Vendian dynamothermal collisional metamorphism.


2014 ◽  
Vol 88 (s2) ◽  
pp. 1118-1119 ◽  
Author(s):  
Peirong LI ◽  
Baocheng PANG ◽  
Baohua WANG ◽  
Yuanqiang LI ◽  
Yequan ZHOU ◽  
...  

LITOSFERA ◽  
2020 ◽  
Vol 19 (6) ◽  
pp. 919-944
Author(s):  
S. A. Dub ◽  
N. V. Cherednichenko ◽  
D. V. Kiseleva ◽  
N. P. Gorbunova ◽  
T. Ya. Gulyaeva ◽  
...  

Research subject. 14 samples of limestone and one sample of carbonate-siliciclastic rock from siliciclastic-carbonate deposits of the Upper Riphean Uk Formation (the Southern Urals) were studied.Methods. Mineral and chemical composition of the samples were determined; the main tool for detecting the concentrations of trace elements was the ICPMS method. X-ray diffraction analysis was carried out using a Shimadzu XRD-7000 diffractometer, the content of major (rock-forming) oxides in bulk samples was established by X-ray fluorescence spectrometry on the SRM-35 and Shimadzu XRF 1800 spectrometers. Microelement composition of bulk samples and acidic leachates obtained with using acetic (10%), nitric (36%) and hydrochloric (17%) acids was determined on a Perkin Elmer ELAN 9000 spectrometer.Results. The distribution of lithophile, rare-earth and a number of other elements (Sr, Ni, U) both in bulk samples and in acidic leachates was analyzed. The main carrier phases of these elements were revealed.Conclusions. 1. The use of any listed acids leads to the non-carbonate component entering the solution, including contamination of the “carbonate” leachates by lithophile elements. In particular, a transition Rb, Zr, Li, Th, Ti, Sc to leachates was noted. This process is most active in nitric and hydrochloric acids, less intensive in acetic acid. 2. Among the carriers of rare earth elements (REE) in the studied rocks are clays (1), accessory minerals (2), including phosphate-bearing grains, secondary carbonate phases represented by dolomite and, possibly (3), finely disseminated iron and manganese (oxy)hydroxides (4). It is assumed that the REE pattern in limestones is determined by the content of the epigenetic dolomite. The contribution of lanthanides bound in the sedimentary calcite crystal lattice in the total REE pattern is rather large only in relatively “pure” limestones. However, the use of acids with such concentrations did not allow to obtain a leachate, which the REE pattern with high probability corresponds to the distribution of REE in the Uk time seawater. But acetic acid is more effective for achieving this goal than the others. 3. In addition to Sr, sedimentary calcite also contains Ni and U.


2020 ◽  
pp. 22-31
Author(s):  
S. A. Milyaev ◽  
G. G. Samosorov ◽  
S. V. Yablokova ◽  
L. V. Shatilova ◽  
N. N. Pozdnyakova

The features of impurity element distribution in native gold of two ore formation gold deposit types are con- sidered. A typomorphic set of elements for gold-polysulfide-quartz and gold-quartz low-sulfide mineralization was determined. Geochemical indicators for estimating ore formation types of native gold are offered. The differences in gold composition due to metallogenic specialization of regions are established. Data on the distribution of rare-earth elements in native gold are obtained, which allows to predict igneous rocks composition during gold-polysulfide-quartz deposit formation.


Author(s):  
V. N. Ogorodnikov ◽  
◽  
Yu. A. Polenov ◽  
V. V. Babenko ◽  
A. N. Savichev ◽  
...  

Minerals ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 338
Author(s):  
Jiasheng Wang ◽  
Jinyang Chang ◽  
Chao Li ◽  
Zhenchun Han ◽  
Tao Wang ◽  
...  

The Zhesang gold deposit of southeastern Yunnan is an important component of the Dian-Qian-Gui (Yunnan, Guizhou, and Guangxi) “Golden Triangle”, which hosts a multitude of Carlin-like gold deposits (CLGDs). Calcite is one of the most common gangue minerals in Zhesang. The calcites that have been found in the mining area are classified as ore-stage and post-ore calcites. The ore-stage calcite exhibits a clear paragenetic relationship with gold-bearing arsenopyrite and with an alteration halo that has been cut by the post-ore calcite. To elucidate the origin of the ore-forming fluids of the Zhesang gold deposit and to investigate the possibility of utilizing calcite geochemistry as prospecting indicators, the rare earth elements (REEs), Y, Fe, Mn and Mg contents, and C-O isotopic compositions of calcites from Zhesang have been analyzed. The ore-stage calcite is enriched in middle rare earth elements (MREEs) relative to light rare earth elements (LREEs) and heavy rare earth elements (HREEs) (MREE/LREE = 1.11–1.61, MREE/HREE = 6.12–8.22), whereas post-ore calcite exhibits an enrichment in LREE (LREE/HREE = 4.39–14.93, MREE/LREE = 0.35–0.71). The ore-stage and post-ore calcites were both formed by hydrothermal fluids; however, these hydrothermal fluids may have different sources. The Fe contents of the ore-stage calcite are significantly higher than those of post-ore calcite (4690–6300 μg/g versus 2030–2730 μg/g). Ore-stage calcite also has significantly lower δ18OV-SMOW values than post-ore calcite (11.03–12.49‰ versus 16.48–17.14‰). These calcites with an MREE/LREE ratio greater than 0.92, MREE/HREE ratio greater than 5.69, Fe content greater than 3827 μg/g, and δ18OV-SMOW value less than 14.40‰ represent ore-stage calcites and are important prospecting guidelines. According to the REE, C-O isotopic characteristics of the calcites and the previous findings, it is inferred that the ore-forming fluids of the Zhesang gold deposit were a mixture of crustal fluid by meteoric water leaching wall rocks and a small amount of basic magmatic fluid. The formation of post-ore calcite might be derived from meteoric water and marine carbonates interaction. The ore-forming fluids of the Zhesang gold deposit may be associated with the intrusion of diabase that outcrops in the mining area, and that the basic magmatic activities of the Indosinian period also provided some of the ore-forming materials and heat for gold mineralization.


Sign in / Sign up

Export Citation Format

Share Document