scholarly journals Ablation and surface modification of polymers with ultraviolet laser radiation.

1995 ◽  
Vol 8 (3) ◽  
pp. 495-503 ◽  
Author(s):  
Sylvain LAZARE ◽  
Weiping GUAN ◽  
David DRILHOLE ◽  
Matthias BOLLE ◽  
John LOPEZ
1991 ◽  
Vol 236 ◽  
Author(s):  
Peter R. Herman ◽  
Boyi Chen ◽  
David J. Moore ◽  
Mark Canaga-Retnam

AbstractExcimer lasers sources of 193nm and 157 nm wavelength were used to obtain new photoablation etching rates for several materials of interest to the microelectronics industry. The harder 157nm radiation provided lower ablation rates and smaller threshold fluences for Polyimide and Polymethyl Methacrylate (PMMA) than with 193nm. For normally robust materials like quartz and Teflon (PTFE), the 157nm laser produced clean and smooth ablation sites with low threshold fluences of 620mJ/cm2 and 68mJ/cm2, respectively, features impossible to obtain with conventional excimer lasers at longer wavelengths. The data should help define new micromachining applications of these two materials for the electronic, optical or medical industry. Results are also reported for GaAs and InP based materials which are found to undergo moderate etch rates of 30-80nm/pulse at fluences of ∼3J/cm2, but suffer thermal damage and material segregation due to surface melting.


2020 ◽  
Vol 41 (6) ◽  
pp. 549-553
Author(s):  
A. V. Sidashov ◽  
A. T. Kozakov ◽  
V. I. Kolesnikov ◽  
D. S. Manturov ◽  
S. I. Yaresko

2019 ◽  
Vol 4 (18) ◽  
pp. 5235-5239
Author(s):  
Guanhua Yang ◽  
Haiming Wu ◽  
Anthony M. S. Pembere ◽  
Zhixun Luo

1998 ◽  
Vol 73 (6) ◽  
pp. 847-849 ◽  
Author(s):  
K. Piglmayer ◽  
E. Arenholz ◽  
C. Ortwein ◽  
N. Arnold ◽  
D. Bäuerle

1985 ◽  
Vol 2 (6) ◽  
pp. 925 ◽  
Author(s):  
D. B. Geohegan ◽  
A. W. McCown ◽  
J. G. Eden

1986 ◽  
Vol 75 ◽  
Author(s):  
Philip J. Hargis

AbstractUltraviolet laser radiation at 248 nm and 266 nm was used to ablate low density (0.04 to 0.14 g/cm3) microcellular polystyrene and TPX foams at laser fluences between 0.1 and 1000 J/cm2, The dependence of the etch rate on laser fluence and foam density is consistent with a linear absorption mechanism for the initial stages of polystyrene ablation. Studies of the morphology and chemical composition of the ablated foams as a function of laser fluence and foam density show that the degree of melting increases at the higher foam densities. Blackbody and radical specie contributions to optical emission from the ablated foam were readily resolved for correlation with laser fluence, foam density, absorption spectra, and etch depth. Temperatures in excess of 3000 °K are calculated from emission spectra observed during the ablation of polystyrene foams. From this data we conclude that chemical and thermal changes in the ablated foam are influenced by the absorption spectrum as well as the density of the foam.


2014 ◽  
Vol 1683 ◽  
Author(s):  
Yang Wei Koh ◽  
Kenneth Westerman ◽  
Sergei Manzhos

ABSTRACTWe present a computational density functional theory study of UF6 adsorption on ideal as well as hydrogenated and fluorinated graphene. We show that (i) the isotopic splitting in the vibrational spectrum of UF6 observed in vacuum is largely preserved in the adsorbed molecules. The existence of several adsorption configurations with competing Eads leads to overlaps in the vibrational spectra of isotopomers, but isotopomer-unique modes exist on all three surfaces. (ii) The adsorption energy of UF6 is of the order of 1.2 eV on ideal graphene, 1 eV on graphane, and 0.1 eV on fluorographene, i.e. the adsorption strength is moderate and can be controlled by surface modification. (i) and (ii) mean that it may be possible to cause desorption of a selected isotopomer by laser radiation, leading to isotopic separation between the surface and the gas.


1989 ◽  
Vol 107 (5) ◽  
pp. 647-649
Author(s):  
A. L. Vladimirtseva ◽  
A. P. Ettinger ◽  
E. Ya. Gatkin ◽  
Yu. V. Golubenko

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