Sterically Unprotected Nucleophilic Boron Cluster Reagents
Keyword(s):
Herein, we demonstrate that the bench stable <i>closo</i>-hexaborate cluster anion can engage in a nucleophilic substitution reaction with a wide array of organic and main group electrophiles. The resulting molecules containing B‒C bonds can be further converted to tricoordinate boron species widely used in organic synthesis.<br>
2013 ◽
Vol 312
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pp. 433-437
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1993 ◽
Vol 115
(13)
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pp. 5879-5880
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2013 ◽
Vol 448
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pp. 74-80
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