One pot Suzuki coupling - Wittig olefination reactions

2004 ◽  
Vol 2004 (11) ◽  
pp. 723-727 ◽  
Author(s):  
Thies Thiemann ◽  
Masataka Watanabe ◽  
Yasuko Tanaka ◽  
Shuntaro Mataka
ChemInform ◽  
2005 ◽  
Vol 36 (27) ◽  
Author(s):  
Thies Thiemann ◽  
Masataka Watanabe ◽  
Yasuko Tanaka ◽  
Shuntaro Mataka

Polymers ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1247
Author(s):  
Ryan Duty ◽  
Christopher E. Hobbs

This communication describes our recent efforts to utilize Wittig olefination reactions for the post-polymerization modification of polynorbornene derivatives prepared through ring opening metathesis polymerization (ROMP). Polymerizing α-bromo ester-containing norbornenes provides polymers that can undergo facile substitution with triphenylphosphine. The resulting polymeric phosphonium salt is then deprotonated to form an ylide that undergoes reaction with various aryl aldehydes in a one-pot fashion to yield the respective cinnamates. These materials can undergo further modification through photo-induced [2 + 2] cycloaddition cross-linking reactions.


2005 ◽  
Vol 60 (12) ◽  
pp. 1299-1307 ◽  
Author(s):  
Kyoko Yamamoto ◽  
Masataka Watanabe ◽  
Kyoko Ideta ◽  
Shuntaro Mataka ◽  
Thies Thiemann

Bromoarene carbaldehydes and bromoheteroarene carbaldehydes underwent a one-pot Suzuki cross coupling and Wittig olefination in aqueous medium to give compounds with extended π-systems.


2006 ◽  
Vol 4 (3) ◽  
pp. 375-402 ◽  
Author(s):  
Masataka Watanabe ◽  
Taisuke Matsumoto ◽  
Shuntaro Mataka ◽  
Thies Thiemann

Abstract17-Thienyl-and 17-benzo[b]thienyl-3-hydroxyestra-1,3,5(10),16-tetraenes were synthesized by either sequential or one-pot Suzuki cross-coupling and Wittig olefination reactions. At 160 °C, heteroaryl substituted steroids were observed to undergo thermal intramolecular cyclization to produce E-ring heteroareno-annelated estranes.


2006 ◽  
Vol 36 (24) ◽  
pp. 3809-3820 ◽  
Author(s):  
Masanori Miura ◽  
Takanori Koike ◽  
Tsukasa Ishihara ◽  
Fukushi Hirayama ◽  
Shuichi Sakamoto ◽  
...  

ChemInform ◽  
2016 ◽  
Vol 47 (32) ◽  
Author(s):  
Hongxiang Wu ◽  
Baiping Xu ◽  
Yue Li ◽  
Fengying Hong ◽  
Dezhao Zhu ◽  
...  

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