Selective oxidation of primary and secondary alcohols with chromium trioxide in ionic liquid

2005 ◽  
Vol 2005 (12) ◽  
pp. 753-754 ◽  
Author(s):  
Yun-Fa Zheng ◽  
Xing-Fen Du ◽  
Wei-Liang Bao
Keyword(s):  
Ionic Liquid ◽  
Selective Oxidation ◽  
Chromium Trioxide ◽  
Secondary Alcohols

Application of Dess-Martin oxidation in total synthesis of natural products

2020 ◽  
Vol 17 ◽  
Author(s):  
Majid M. Heravi ◽  
Tayebe Momeni ◽  
Vahideh Zadsirjan ◽  
Leila Mohammadi
Keyword(s):  
Natural Products ◽  
Total Synthesis ◽  
Selective Oxidation ◽  
Secondary Alcohols ◽  
Aldehydes And Ketones

: Dess–Martin periodinane (DMP), is a commercially available chemical, frequently being utilized as a mild oxidative agent for the selective oxidation of primary and secondary alcohols to their corresponding aldehydes and ketones, respectively. DMP shows several merits over other common oxidative agent such as chromium- and DMSO-based oxidants, thus it is habitually employed in the total synthesis of natural products. In this review, we try to underscore the applications of DMP as an effective oxidant in an appropriate step (steps) in the multistep total synthesis of natural products.

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