An Efficient Transition-Metal-Chloride/Sodium-Nitrite/TEMPO Catalytic System for Aerobic Oxidative Aromatisation of Hantzsch 1,4-Dihydropyridines

2013 ◽  
Vol 37 (7) ◽  
pp. 409-412 ◽  
Author(s):  
Bin-Hui Lou ◽  
Shu-Bin Chen ◽  
Jian Wang ◽  
Ying Chen ◽  
Jing-Hua Li
Keyword(s):  
Transition Metal ◽  
Catalytic System ◽  
Sodium Nitrite ◽  
Metal Chloride ◽  
Transition Metal Chloride

Synthesis of a series of M(ii) (M = Mn, Fe, Co) chloride complexes with both inter- and intra-ligand hydrogen bonding interactions

2021 ◽  
Vol 50 (35) ◽  
pp. 12088-12092
Author(s):  
Clare A. Leahy ◽  
Michael J. Drummond ◽  
Josh Vura-Weis ◽  
Alison R. Fout
Keyword(s):  
Hydrogen Bonding ◽  
Transition Metal ◽  
Intramolecular Hydrogen Bonding ◽  
Metal Chloride ◽  
Chloride Complexes ◽  
Hydrogen Bonding Interactions ◽  
Transition Metal Chloride ◽  
Hydrogen Bonding Networks ◽  
Intramolecular Hydrogen

Hydrogen bonding networks are vital for metallo-enzymes to function; however, modeling these systems is non-trivial. The development of 1st-row transition metal chloride complexes with intramolecular hydrogen-bonding interactions are detailed herein.

Investigation on the effect of transition metal chloride on anthracite combustion

Fuel ◽  
2020 ◽  
Vol 264 ◽  
pp. 116796 ◽  
Author(s):  
Bo Tan ◽  
Hongyi Wei ◽  
Bin Xu ◽  
Hongru Zhao ◽  
Zhuangzhuang Shao
Keyword(s):  
Transition Metal ◽  
Metal Chloride ◽  
Transition Metal Chloride

Chlorocuprate(II) and Chlorocobaltate(II) Salts of the Aminodiphenyl-phosphonitrileaminodiphenylphosphonium Ion

1972 ◽  
Vol 50 (1) ◽  
pp. 75-82 ◽  
Author(s):  
R. M. Clipsham ◽  
M. A. Whitehead
Keyword(s):  
Electronic Structure ◽  
Transition Metal ◽  
Metal Chloride ◽  
Quaternary Amine ◽  
Ring Compounds ◽  
General Series ◽  
Cobalt Compounds ◽  
Transition Metal Chloride ◽  
New Compounds ◽  
Chloride Salts

Two new compounds [NH2(C6H5)2PNP(C6H5)2NH2]2[CoCl4] and [NH2(C6H5)2PNP(C6H5)2NH2][CoCl4]CH2Cl2 have been isolated, and characterized by spectrometry, as examples of the general series of quaternary amine transition metal chloride salts. Three other compounds containing the same cations, with empirical formulae, CuP2N3C25H32OCl3 (1), CuP2N3C24H28Cl3 (2), and Cu3P4N6C50H64O2Cl8 (3) have been isolated and studied by spectrometry. The formulae [NH2(C6H5)2PNP(C6H5)2NH2]2[Cu2Cl6] and [NH2(C6H5)2PNP(C6H5)2NH2]2[Cu2Cl6]. 2CH3OH are proposed for (2) and (1) by comparison with the cobalt compounds, and interpretation of the electronic structure. These compounds were produced during attempts to synthesize mixed ring compounds of (PN) and (SN) units.

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