The TiC-Cu composites with different mass fraction were prepared by powder metallurgy method. The effect of ball milling time and sintering temperature on the morphology, relative density and electrical conductivity of TiC/Cu composites has been investigated. As-milled sintered compacts were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD) and conductivity measurements. The results demonstrate that under laboratory conditions with the milling time increasing grains are remarkable refined. Mechanical milling can bring about changes of lattice parameters, the grain size first decrease and then increase as milling time increasing. Relative density showed strong dependency on the milling time. The effect of the grain being refined by ball milling is helpless to improve electrical conductivity of composites. For the composites with TiC content<50wt.%, as milling time prolonging the electric conductivity decreases while for the 50%TiC-Cu the conductivity are not be impacted.