scholarly journals Two-Dimensional Metal Organic Framework Nanosheets as Bifunctional Catalyst for Electrochemical and Photoelectrochemical Water Oxidation

2020 ◽  
Vol 8 ◽  
Author(s):  
Chang Liu ◽  
Xiaochen Shen ◽  
Grayson Johnson ◽  
Yulu Zhang ◽  
Changlin Zhang ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Metal Organic Framework ◽  
Bifunctional Catalyst ◽  
Two Dimensional ◽  
Metal Organic ◽  
Photoelectrochemical Water Oxidation ◽  
Organic Framework

A Cobalt‐Based Metal–Organic Framework as Cocatalyst on BiVO 4 Photoanode for Enhanced Photoelectrochemical Water Oxidation

ChemSusChem ◽  
2018 ◽  
Vol 11 (16) ◽  
pp. 2710-2716 ◽  
Author(s):  
Wang Zhang ◽  
Rui Li ◽  
Xin Zhao ◽  
Zhong Chen ◽  
Adrian Wing‐Keung Law ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Photoelectrochemical Water Oxidation ◽  
Organic Framework

Synthesis and Structure of a Clathrated Two-Dimensional Metal-Organic Framework: [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2·H2O (L = Bis(1-pyrazinylethylidene)hydrazine)

2008 ◽  
Vol 73 (1) ◽  
pp. 24-31
Author(s):  
Dayu Wu ◽  
Genhua Wu ◽  
Wei Huang ◽  
Zhuqing Wang
Keyword(s):  
Metal Organic Framework ◽  
Channel Structure ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Guest Molecules ◽  
X Ray ◽  
Square Planar ◽  
Metal Organic ◽  
Aqueous Meoh ◽  
Organic Framework

The compound [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2 was obtained by the reaction of Cd(ClO4)2, bis(1-pyrazinylethylidene)hydrazine (L) and 4,4'-bipyridine in aqueous MeOH. Single-crystal X-ray diffraction has revealed its two-dimensional metal-organic framework. The 2-D layers superpose on each other, giving a channel structure. The square planar grids consist of two pairs of shared edges with Cd(II) ion and a 4,4'-bipyridine molecule each vertex and side, respectively. The square cavity has a dimension of 11.817 × 11.781 Å. Two guest molecules of bis(1-pyrazinylethylidene)hydrazine are clathrated in every hydrophobic host cavity, being further stabilized by π-π stacking and hydrogen bonding. The results suggest that the hydrazine molecules present in the network serve as structure-directing templates in the formation of crystal structures.

Sign in / Sign up

Export Citation Format

Share Document