scholarly journals Mechanochemically-Assisted Synthesis of Lead-Free Piezoelectric CaZrO3-Modified (K,Na,Li)(Nb,Ta)O3-Solid Solution

Ceramics ◽  
2018 ◽  
Vol 1 (2) ◽  
pp. 304-318 ◽  
Author(s):  
Kristian Radan ◽  
Brigita Kmet ◽  
Silvo Drnovšek ◽  
Uroš Prah ◽  
Tadej Rojac ◽  
...  
Keyword(s):  
Thermal Analysis ◽  
Solid State ◽  
Processing Time ◽  
Piezoelectric Properties ◽  
Mechanochemical Activation ◽  
Solid State Synthesis ◽  
Lead Free ◽  
Compositional Homogeneity ◽  
Lower Temperature ◽  
Conventional Solid State Synthesis

Lead-free piezoelectric 0.95(Na0.49K0.49Li0.02)(Nb0.8Ta0.2)O3–0.05CaZrO3 with 2 wt % MnO2 addition was prepared using mechanochemically-assisted solid-state synthesis. Upon mechanochemical activation of the mixture of reagents partial amorphization occurs which contributes to a significantly lower temperature of completion of the solid-state reaction, ~600 °C as opposed to ~700 °C for the conventional solid-state synthesis as determined by thermal analysis. The ceramic specimens prepared by the mechanochemically-assisted route exhibit improved compositional homogeneity and slightly enhanced piezoelectric properties, achieved in a considerably shorter processing time compared to the conventional solid-state synthesis route, which was studied as a reference.

Structural and Electrical Properties of (1-x)Pb (Zry Ti1-y)O3-xSm(Fe3+0.5, Nb5+0.5)O3 Ceramics Prepared by Conventional Solid State Synthesis and Sintered at Low Temperature

2014 ◽  
Vol 87 ◽  
pp. 12-17
Author(s):  
Fares Kahoul ◽  
Louanes Hamzioui ◽  
Ahmed Boutarfaia
Keyword(s):  
Solid State ◽  
Electrical Properties ◽  
Piezoelectric Properties ◽  
Piezoelectric Materials ◽  
Promising Candidate ◽  
Solid State Method ◽  
Conventional Solid State Method ◽  
Structural And Electrical Properties ◽  
Conventional Solid State Synthesis ◽  
Stable Solid Solution

The phase structure, microstructure and electrical properties of (1-x)Pb (ZryTi1-y)O3-xSm(Fe3+0.5,Nb5+0.5)O3(PZT–SFN) (with x = 2 %, 41%≤ y ≤57 %) piezoelectric ceramics were prepared by the conventional solid state method, and effects of SFN and the Zr/Ti ratio content on the piezoelectric properties of PZT ceramics were mainly investigated. A stable solid solution has been formed between PZT and SFN, and a morphotropic phase boundary of PZT–SFN ceramics is identified in the range of 51% ≤ y ≤55 %. The Curie temperature of PZT–SFN ceramics decreases with increasing at Zr/Ti ratio content. A higher εrvalue and a lower tanδ value are demonstrated for the PZT–SFN ceramics with y = 53 %. The PZT–SFN ceramics with y = 53 % has an enhanced electrical behavior of kp~ 61.2 %, Qm~ 104, εr~ 566, tanδ ~ 2.02 % and TC~ 370OC. As a result, PZT–SFN ceramics are promising candidate materials for the field of lead piezoelectric materials and piezoelectric device.

Na/K RATIOS DEPENDENCE OF PIEZOELECTRIC AND FERROELECTRIC PROPERTIES IN (K1-xNax)NbO3 LEAD-FREE CERAMICS

2011 ◽  
Vol 01 (04) ◽  
pp. 471-478 ◽  
Author(s):  
HONGLIANG DU ◽  
SHAOBO QU ◽  
ZHUO XU ◽  
XIAOYONG WEI ◽  
WANCHENG ZHOU ◽  
...  
Keyword(s):  
Solid State ◽  
Phase Boundary ◽  
Morphotropic Phase Boundary ◽  
Piezoelectric Properties ◽  
Ferroelectric Properties ◽  
Lead Free ◽  
Obvious Effect ◽  
Lead Free Ceramics ◽  
Solid State Sintering

In order to clarify the Na/K ratios dependence of piezoelectric properties, ( K 1-x Na x) NbO 3 ceramics were prepared by conventional solid-state sintering at x = 0.4–0.6 with a smaller compositional interval (0.02 mol). The results demonstrate that the Na/K ratios have obvious effect on piezoelectric and ferroelectric properties of ( K 1-x Na x) NbO 3 ceramics. Piezoelectric and ferroelectric properties show the maximum (d33 = 147 pC/N, kp = 0.40, and Pr = 24 μC/cm2) at x = 0.54, which is not consistent with conventional viewpoint. The reasons should be attributed to the existence of a phase boundary at x = 0.54 mol, which is similar to the morphotropic phase boundary in Pb(Zr,Ti)O3 ceramics.

Synthesis of Three Layer NaxCoO2 (x=0.3, 0.5, 0.6, 0.75, 1.0) and Superconductivity in Three Layer Na0.3CoO2•1.3H2O

2004 ◽  
Vol 848 ◽  
Author(s):  
M.L. Foo ◽  
T. Klimczuk ◽  
L. Li ◽  
N.P. Ong ◽  
R.J. Cava ◽  
...  
Keyword(s):  
Solid State ◽  
Cobalt Oxide ◽  
Room Temperature ◽  
Solid State Synthesis ◽  
Stacking Sequence ◽  
Sodium Cobalt Oxide ◽  
Conventional Solid State Synthesis

ABSTRACTThe synthesis of three layer sodium cobalt oxide, NaxCoO2 (x=0.3, 0.5, 0.6, 0.75 and 1.0) is reported. For x=0.6, 0.75, and 1.0, conventional solid-state synthesis was employed. x=0.3 and 0.5 were obtained via oxidative deintercalation of sodium at room temperature. x=0.3 can be hydrated to Na0.3CoO2•1.3H2O which is superconducting with a Tc of 4.3 K. Although having the same chemical stiochiometry as the previously reported two layer superconductor, it has a different stacking sequence of CoO2 layers making it structurally distinct. Crystals of three layer NaCoO2 show triangular morphology compared to hexagonal morphology for two layer Na0.7CoO2.

scholarly journals Large electro-strain signal of the BNT–BT–KNN lead-free piezoelectric ceramics with CuO doping

2019 ◽  
Vol 09 (03) ◽  
pp. 1950022 ◽  
Author(s):  
Zhi-Hao Zhao ◽  
Rui-Fang Ge ◽  
Yejing Dai
Keyword(s):  
Transition Temperature ◽  
Solid State ◽  
Room Temperature ◽  
Ferroelectric Phase ◽  
Piezoelectric Properties ◽  
The Other ◽  
Lead Free ◽  
State Process ◽  
Relaxor State ◽  
Strain Signal

This paper investigates a system of 0.93[Formula: see text][Formula: see text]TiO3–0.06BaTiO3–0.01[Formula: see text][Formula: see text]NbO3–[Formula: see text]CuO (BNT–BT–KNN–[Formula: see text]CuO, [Formula: see text][Formula: see text]mol.%) ceramics, which were fabricated by the conventional solid-state process through the granulation of vacuum freeze drier. The results show that the CuO doping made a significant enhancement on the piezoelectric properties of the BNT–BT–KNN ceramics. With the doping of CuO, the transition temperature between ferroelectric phase and ergodic relaxor state is reduced to near room temperature, resulting in pinched [Formula: see text]–[Formula: see text] loops and “sprout” shape [Formula: see text]–[Formula: see text] curves. For the composition with [Formula: see text], a high unipolar strain of 0.39% under 5[Formula: see text]kV/mm contributes a large [Formula: see text][Formula: see text]pm/V at room temperature, which is competitive with the other BNT-based ceramics.

Dielectric, Piezoelectric and Ferroelectric Properties of (1-x)K0.5Na0.5NbO3–xBiGaO3 Lead-Free Ceramics

2013 ◽  
Vol 634-638 ◽  
pp. 2345-2348 ◽  
Author(s):  
Hong Mei Zhang ◽  
Shao Bo Qu ◽  
Jing Bo Zhao ◽  
Hong Liang Du
Keyword(s):  
Solid State ◽  
Electrical Properties ◽  
Piezoelectric Ceramic ◽  
Room Temperature ◽  
Piezoelectric Properties ◽  
Ferroelectric Properties ◽  
Lead Free ◽  
Practical Applications ◽  
Lead Free Ceramics ◽  
Solid State Sintering

(1-X)K0.5Na0.5NbO3–xBiGaO3[(1-X)KNN-Xbg] Lead-Free Ceramics with Different Additive of Bigao3 Were Synthesized by Conventional Solid-State Sintering Technique. Dielectric, Piezoelectric and Ferroelectric Properties of (1-X)KNN-Xbg Lead-Free Ceramics Were Studied. it Is Found that the Piezoelectric Properties Was Improved due to the Additive Bigao3，The Ceramics X=0.01 near Room Temperature Exhibit Excellent Electrical Properties D33=152pC/N, TC=372 °C. these Results Indicate that Bigao3 Adjusted K0.5Na0.5NbO3-Based Ceramics Materials Are Promising Lead-Free Piezoelectric Ceramic Candidates for Practical Applications.

Kinetic Study of Conventional Solid-State Synthesis of BaTiO3 by in situ HT-XRD

1998 ◽  
Vol 278-281 ◽  
pp. 379-383 ◽  
Author(s):  
Federica Bondioli ◽  
A. Bonamartini Corradi ◽  
Anna Maria Ferrari ◽  
Tiziano Manfredini ◽  
Gian Carlo Pellacani
Keyword(s):  
Solid State ◽  
Kinetic Study ◽  
Solid State Synthesis ◽  
Conventional Solid State Synthesis

Effects of Mn-Doping on the Piezoelectric and Ferroelectric Properties of (Na0.8K0.2)0.5Bi0.5TiO3 Ceramics

2008 ◽  
Vol 368-372 ◽  
pp. 69-71 ◽  
Author(s):  
Xiang Ping Jiang ◽  
Long Zhu Li ◽  
Fu Lan Jiang ◽  
Yan Yan Zheng ◽  
Li Hua Liu
Keyword(s):  
Solid State ◽  
Dielectric Loss ◽  
Grain Growth ◽  
Remnant Polarization ◽  
Piezoelectric Properties ◽  
Ferroelectric Properties ◽  
Mechanical Quality Factor ◽  
Lead Free ◽  
Mn Doping ◽  
Mechanical Quality

Lead-free piezoelectric ceramics of (Na0.8K0.2)0.5Bi0.5TiO3+x wt.% Mn (abbreviated as NBKT-x% Mn, x=0~0.5) were synthesized by solid-state reaction. The grain growth of the ceramics was restrained by Mn-doping at a certain extent. The mechanical quality factor Qm increases and the dielectric loss tanδ decreases with the increase of Mn-doping. Best piezoelectric properties were obtained for the composition of NKBT-0.2%Mn: d33=158 pC·N-1, tanδ=2.9% at 1 kHz, Qm=110 and kp=30%. The P-E loops show that remnant polarization Pr and coercive field Ec decrease slightly with the amount of the Mn2+ increasing up to 0.2wt.% and then increase as the content of Mn2+ increases further. NKBT-0.5wt. % Mn exhibits strong ferroelectricity with remnant polarization Pr = 38μC/cm2.

Sign in / Sign up

Export Citation Format

Share Document