scholarly journals Potassium Sulfate: A New Candidate to Explore Non-Photochemical Laser-Induced Nucleation Mechanisms

Crystals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1571
Author(s):  
Mélody Briard ◽  
Clément Brandel ◽  
Sandrine Morin-Grognet ◽  
Gérard Coquerel ◽  
Valérie Dupray

In this paper, we report a study on the nucleation behavior of potassium sulfate (K2SO4) from aqueous solutions under the influence of unfocused nanosecond laser pulses. The objective is to contribute to the general understanding of the Non-Photochemical Laser-Induced Nucleation (NPLIN) mechanism. First, the influence of several parameters such as supersaturation as well as laser parameters (pulse energy, number of pulses, and laser polarization) on induction time, probability of nucleation and mean number of crystals in comparison with spontaneous nucleation was investigated. Then, we examined the influence of gas composition (i.e., degassing and gas bubbling (CO2 and N2)) of the supersaturated solutions on the NPLIN kinetics, showing no correlation between gas content (or nature) on the crystallization behavior. Our study questions the role of impurities within the solution regarding the mechanism of laser-induced nucleation.

RSC Advances ◽  
2016 ◽  
Vol 6 (91) ◽  
pp. 87897-87904 ◽  
Author(s):  
Pramod Sharma ◽  
Soumitra Das ◽  
Rajesh K. Vatsa

Interaction of tetrahydrofuran clusters with nanosecond laser pulses has been investigated at 532 and 1064 nm, using a time-of-flight mass spectrometer and home-built electron analyzer setup.


2006 ◽  
Vol 89 (14) ◽  
pp. 141907 ◽  
Author(s):  
Danny Perez ◽  
Laurent J. Lewis ◽  
Patrick Lorazo ◽  
Michel Meunier

2011 ◽  
Vol 257 (24) ◽  
pp. 10876-10882 ◽  
Author(s):  
Nadezhda M. Bulgakova ◽  
Anton B. Evtushenko ◽  
Yuri G. Shukhov ◽  
Sergey I. Kudryashov ◽  
Alexander V. Bulgakov

2010 ◽  
Vol 97-101 ◽  
pp. 3803-3806
Author(s):  
Yong Xiang Hu ◽  
Heng Zhang ◽  
Zheng Qiang Yao

Laser interference micro-structuring is a relatively efficient and cost-effective technique for fabricating periodical micro-nano-structuring surfaces. The direct fabrication of sub-micron sized dot array on silicon was performed by four interfering nanosecond laser beams with a diffractive beam splitter. The mechanism to form the dot array was analyzed and it was found that the obtained conical dot array had a negative shape of the interference pattern of four laser beams. A second-order peak between two first-order peaks also occurred due to the liquid-solid expansion.


Sign in / Sign up

Export Citation Format

Share Document