scholarly journals A Novel Iron Chloride Red-Ox Concentration Flow Cell Battery (ICFB) Concept; Power and Electrode Optimization

Energies ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 1109
Author(s):  
Robert Bock ◽  
Björn Kleinsteinberg ◽  
Bjørn Selnes-Volseth ◽  
Odne Stokke Burheim

For renewable energies to succeed in replacing fossil fuels, large-scale and affordable solutions are needed for short and long-term energy storage. A potentially inexpensive approach of storing large amounts of energy is through the use of a concentration flow cell that is based on cheap and abundant materials. Here, we propose to use aqueous iron chloride as a reacting solvent on carbon electrodes. We suggest to use it in a red-ox concentration flow cell with two compartments separated by a hydrocarbon-based membrane. In both compartments the red-ox couple of iron II and III reacts, oxidation at the anode and reduction at the cathode. When charging, a concentration difference between the two species grows. When discharging, this concentration difference between iron II and iron III is used to drive the reaction. In this respect it is a concentration driven flow cell redox battery using iron chloride in both solutions. Here, we investigate material combinations, power, and concentration relations.

2021 ◽  
Author(s):  
Karin Astrid Senta Edel ◽  
František Hrdlička ◽  
Václav Novotný

As part of the change towards a higher deployment of renewable energy sources, which naturally deliver energy intermittently, the need for energy storage systems is increasing. For compensation of disturbance in power production due to inter-day to seasonal weather changes, long-term energy storage is required. In the spectrum of storage systems, one out of a few geographically independent possibilities is the storage of electricity in heat, so-called Carnot-Batteries. This paper presents a Pumped Thermal Energy Storage (PTES) system based on a recuperated supercritical CO2 Brayton cycle. The modelled system provides a round-trip efficiency of 38.9%.


Energies ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 1070 ◽  
Author(s):  
Serguey Maximov ◽  
Gareth Harrison ◽  
Daniel Friedrich

Chile has abundant solar and wind resources and renewable generation is becoming competitive with fossil fuel generation. However, due to renewable resource variability their large-scale integration into the electricity grid is not trivial. This study evaluates the long-term impact of grid level energy storage, specifically Pumped Thermal Energy Storage (PTES), on the penetration of solar and wind energies and on CO2 emissions reduction in Chile. A cost based linear optimization model of the Chilean electricity system is developed and used to analyse and optimize different renewable generation, transmission and energy storage scenarios until 2050. For the base scenario of decommissioning ageing coal plants and no new coal and large hydro generation, the generation gap is filled by solar photovoltaic (PV), concentrated solar power (CSP) and flexible gas generation with the associated drop of 78% in the CO2 emission factor. The integration of on-grid 8h capacity storage increases the solar PV fraction which leads to a 6% reduction in operation and investment costs by 2050. However, this does not necessarily lead to further reductions in the long term emissions. Thus, it is crucial to consider all aspects of the energy system when planning the transition to a low carbon electricity system.


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