Raman Spectra of Luminescent Graphene Oxide (GO)-Phosphor Hybrid Nanoscrolls

The graphene oxides were synthesized form graphite by ultrasonic dispersion in water, N-methylpyrrolidone (NMP), N,N-dimethyl-formamide (DMF), acetone and dimethylbenzene, and the polyurethane acrylates containing the reactive NCO (PACN) were prepared. Then the polyurethane acrylates modified graphene oxide synthesized by ultrasonic dispersion in N-methylpyrrolidone (NMP), N,N-dimethyl-formamide (DMF), acetone were prepared by NCO of PACN reacting with the hydroxyl groups of the graphene oxides. The polyurethane acrylates modified graphene oxide was characterized by Fourier transform infrared spectrometer (FTIR), scanning electron microscope (SEM) and Raman spectra. The FTIR spectra showed that the NCO of PACN reacted with the hydroxyl groups of graphene oxide synthesized by ultrasonic dispersion. The measurement of SEM and Raman spectra showed that the polyurethane acrylates modification didn't change the structure and surface morphology of graphene oxide.

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Characteristics of Raman spectra for graphene oxide from ab initio simulations

The Journal of Chemical Physics ◽

10.1063/1.3658859 ◽

2011 ◽

Vol 135 (18) ◽

pp. 184503 ◽

Cited By ~ 22

Author(s):

Lu Wang ◽

Jijun Zhao ◽

Yi-Yang Sun ◽

Shengbai B. Zhang

Keyword(s):

Graphene Oxide ◽

Ab Initio ◽

Raman Spectra ◽

Ab Initio Simulations

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Exploration of the Cs Trapping Phenomenon by Combining Graphene Oxide with α-K6P2W18O62 as Nanocomposite

Materials ◽

10.3390/ma14195577 ◽

2021 ◽

Vol 14 (19) ◽

pp. 5577

Author(s):

Bangun Satrio Nugroho ◽

Akane Kato ◽

Chie Kowa ◽

Tomoya Nakashima ◽

Atsushi Wada ◽

...

Keyword(s):

Graphene Oxide ◽

Raman Spectra ◽

Quantitative Data ◽

Aggregation Process ◽

Pxrd Pattern ◽

Adsorption Performance ◽

Black Spots ◽

Sem Imaging ◽

The Difference ◽

Hybrid Carbon

A graphene oxide-based α-K6P2W18O62 (Dawson-type polyoxometalate) nanocomposite was formed by using two types of graphene oxide (GO) samples with different C/O compositions. Herein, based on the interaction of GO, polyoxometalates (POMs), and their nanocomposites with the Cs cation, quantitative data have been provided to explicate the morphology and Cs adsorption character. The morphology of the GO-POM nanocomposites was characterized by using TEM and SEM imaging. These results show that the POM particle successfully interacted above the surface of GO. The imaging also captured many small black spots on the surface of the nanocomposite after Cs adsorption. Furthermore, ICP-AES, the PXRD pattern, IR spectra, and Raman spectra all emphasized that the Cs adsorption occurred. The adsorption occurred by an aggregation process. Furthermore, the difference in the C/O ratio in each GO sample indicated that the ratio has significantly influenced the character of the GO-POM nanocomposite for the Cs adsorption. It was shown that the oxidized zone (sp2/sp3 hybrid carbon) of each nanocomposite sample was enlarged by forming the nanocomposite compared to the corresponding original GO sample. The Cs adsorption performance was also influenced after forming a composite. The present study also exhibited the fact that the sharp and intense diffractions in the PXRD were significantly reduced after the Cs adsorption. The result highlights that the interlayer distance was changed after Cs adsorption in all nanocomposite samples. This has a good correlation with the Raman spectra in which the second-order peaks changed after Cs adsorption.

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