scholarly journals Crystallographic and Seismic Anisotropies of Calcite at Different Depths: A Study Using Quantitative Texture Analysis by Neutron Diffraction

Minerals ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 26 ◽  
Author(s):  
Michele Zucali ◽  
Daniel Chateigner ◽  
and Bachir Ouladdiaf

Eight samples of limestones and marbles were studied by neutron diffraction to collect quantitative texture (i.e., crystallographic preferred orientations or CPO) of calcite deforming at different depths in the crust. We studied the different Texture patterns developed in shear zones at different depth and their influence on seismic anisotropies. Samples were collected in the French and Italian Alps, Apennines, and Paleozoic Sardinian basement. They are characterized by isotropic to highly anisotropic (e.g., mylonite shear zone) fabrics. Mylonite limestones occur as shear zone horizons within the Cenozoic Southern Domain in Alpine thrust-and-fold belts (Italy), the Briançonnais domain of the Western Alps (Italy-France border), the Sardinian Paleozoic back-thrusts, or in the Austroalpine intermediate units. The analyzed marbles were collected in the Carrara Marble, in the Austroalpine Units in the Central (Mortirolo) and Western Alps (Valpelline). The temperature and depth of development of fabrics vary from <100 ∘ C, to 800 ∘ C and depth from <10 km to about 30 km, corresponding from upper to lower crust conditions. Quantitative Texture Analysis shows different types of patterns for calcite: random to strongly textured. Textured types may be further separated in orthorhombic and monoclinic (Types A and B), based on the angle defined with the mesoscopic fabrics. Seismic anisotropies were calculated by homogenizing the single-crystal elastic tensor, using the Orientation Distribution Function calculated by Quantitative Texture Analysis. The resulting P- and S-wave anisotropies show a wide variability due to the textural types, temperature and pressure conditions, and dip of the shear planes.

Author(s):  
Michele Zucali ◽  
Daniel Chateigner ◽  
Bachir Ouladdiaf

Eight samples of limestones and marbles were studied by neutron diffraction to collect 2 Quantitative Texture (i.e., Crystallographic Preferred Orientations or CPO) of calcite deforming at 3 different depths in the crust. We studied the different Texture patterns developed in shear zones at 4 different depth and their influence on seismic anisotropies. Samples were collected in the French and 5 Italian Alps, Apennines, and Paleozoic Sardinian basement. They are characterized by isotropic to 6 highly anisotropic (e.g., mylonite shear zone) fabrics. Mylonite limestones occur as shear zone horizons 7 within the Cenozoic Southern Domain in Alpine thrust-and-fold belts (Italy), the Briançonnais domain 8 of the Western Alps (Italy-France border), the Sardinian Paleozoic back-thrusts or in the Austroalpine 9 intermediate units. The analyzed marbles were collected in the Carrara Marble, in the Austroalpine Units 10 in the Central (Mortirolo) and Western Alps (Valpelline). The temperature and depth of development of fabrics vary from &lt; 100◦C, to 800◦C and depth from &lt;10 km to about 30 km, corresponding from upper 12 to lower crust conditions. Quantitative Texture Analysis shows different types of patterns for calcite: 13 random to strongly textured. Textured types may be further separated in orthorhombic and monoclinic 14 (Types A and B), based on the angle defined with the mesoscopic fabrics. Seismic anisotropies were 15 calculated by homogenizing the single crystal elastic tensor, using the Orientation Distribution Function 16 calculated by the Quantitative Texture Analysis. The resulting P- and S-waves anisotropies show a wide 17 variability due to the textural types, temperature and pressure conditions, and dip of the shear planes.


Author(s):  
Michele Zucali ◽  
Daniel Chateigner ◽  
Bachir Ouladdiaf

Eight samples of limestones and marbles were studied by neutron diffraction to collect Quantitative Texture (i.e. Crystallographic Preferred Orientations or CPO) of calcite deforming at different depths in the crustal profile. We studied the different CPO patterns developed in shear zones at different depth and their influence on seismic anisotropies. Samples were collected in the French and Italian Alps, Apennines and Paleozoic Sardinian basement. They are characterized by different mesoscopic fabrics, from isotropic to highly anisotropic (e.g. mylonite shear zone). Mylonite limestones occur as shear zone horizons within the Cenozoic Southern Domain in Alpine thrust-and-fold belts (Italy), the Brian&ccedil;onnais domain of the Western Alps (Italy-France border), the Sardinian Paleozoic back-thrusts or in the Austroalpine Upper units. The analyzed marbles were collected in the Carrara Marble, in the Austroalpine Units in the Central (Mortirolo) and Western Alps (Valpelline). The temperature and depth of development of the fabrics vary from shallow, &lt; 100&deg;C, to more than 800&deg;C at depth of about 30 km. Quantitative Texture Analysis shows different types of patterns for calcite CPO, from random (Type A) to strongly textured (Type B); Type B may be further separated in orthorhombic and monoclinic, based on the angle defined with the mesoscopic fabrics, namely the shear plane. Seismic anisotropies were calculated by homogenizing the single crystal elastic tensor, using the Orientation Distribution Function calculated by the Quantitative Texture Analysis. The resulting P- and S-waves anisotropies show a wide variability due to the textural types, depth within the crustal profile, and dip of the shear planes.


1993 ◽  
Vol 21 (2-3) ◽  
pp. 71-78
Author(s):  
H.-G. Brokmeier

This paper describes the application of neutron diffraction to investigate the texture of a zinc layer 8 μm in thickness. In a nondestructive way both the texture of the zinc layer as well as the texture of the steel substrate were studied. Therefore, pole figures of iron ((110), (200) and (211)) and of zinc ((0002), (101¯0), (101¯1); and (101¯3)/(112¯0)) were measured; additionally the orientation distribution function of iron and zinc were calculated.


2021 ◽  
Author(s):  
Stéphane Schwartz ◽  
Ahmed Nouibat ◽  
Yann Rolland ◽  
Thierry Dumont ◽  
Anne Paul ◽  
...  

&lt;p&gt;The recent S-wave velocity tomography undertaken at the scale of the Alps by Nouibat et al. (2021) allows a reappraisal of the deep structure of this mountain belt. These geophysical data highlight the role of crustal geometry in the strain field development observed in the Western Alps. The geophysical imagery shows a standard crustal thickness in the foreland, with slow velocities (&lt;3.6 km.s&lt;sup&gt;-1&lt;/sup&gt;) in the lower crust. The occurrence of a sharp Moho offset of 5-12 km is detected beneath the External Crystalline Massifs (ECMs). The ECMs do not show any significant crustal thickening in their frontal parts (&lt;35 km), except for the Pelvoux ECM (35-40 km). Beneath the internal zones, east of the Penninic Frontal Thrust, the crustal geometry is more complex with the presence of an European continental slab subducting locally deeper than 80 km beneath the Adria plate. This slab is overlain by a high-pressure metamorphic orogenic prism. The lower part, corresponding to the Ivrea gravimetry anomaly, shows seismic signatures of serpentinized mantle (Vs between 3.8 and 4.3 km.s&lt;sup&gt;-1&lt;/sup&gt;) whose upper limit is located at 10 km depth below the Dora Maira internal crystalline massif. This new crustal-scale image can be compared to the current deformation pattern, which appears highly partitioned at the scale of the Alpine arc. The internal zones show a transtensional deformation regime, whose activity is distributed along two major seismic lineaments (the &amp;#8216;Piemontais&amp;#8217; and &amp;#8216;Brian&amp;#231;onnais&amp;#8217; ones). The Alpine European foreland shows a transpressional deformation that is more diffuse and associated with vertical displacements in the ECMs. Beneath the Po plain, the seismic activity is deeper (&gt;40 km), and correlates with a transpressional deformation which is localized along sub-vertical lineaments. The deformation of the orogenic prism appears controlled by a deeper and rigid mantle indenter split in two units by a major subvertical serpentinized structure. The upper unit, which indents horizontally and vertically the crustal orogenic prism, is located between 20 and 45 km depth. The lower unit corresponds to the western boundary of the Adria mantle that pinches directly the European slab. The surface observations and geochronological data suggest that the Moho offstets are superposed on European crustal-scale faults trend inherited from the Variscan orogeny, following the East-Variscan strike-slip system. This structural anisotropy was reactivated during the Alpine orogeny as shear zones in a mainly transpressional regime since about 25-30 Ma, as documented by Ar-Ar data on syn-kinematic mica and U-Pb on monazite. The comparison of current seismicity with the kinematics of exhumed shear zones suggests a continuity of this regime since 25-30 Ma, in response to the Adria plate anticlockwise rotation.&lt;/p&gt;


2001 ◽  
Vol 34 (4) ◽  
pp. 442-453 ◽  
Author(s):  
H.-R. Wenk ◽  
L. Cont ◽  
Y. Xie ◽  
L. Lutterotti ◽  
L. Ratschbacher ◽  
...  

Orientation distributions of garnet and omphacite in eclogite from the ultra-high pressure Dabie Shan belt in east-central China were determined from neutron diffraction data by the Rietveld method. Diffraction spectra were recorded in 16 sample orientations with seven detectors, with a kappa-geometry texture goniometer at the time-of-flight (TOF) neutron facility at the Intense Pulsed Neutron Source (IPNS). The textures of the two minerals were extracted simultaneously from 16 × 7 = 112 diffraction spectra, covering a large portion of the pole figure. The texture analysis was performed both with the Williams–Imhof–Matthies–Vinel (WIMV) method and the harmonic method, implemented in the program packageMAUD. The incomplete pole-figure coverage introduced artificial oscillations in the case of the harmonic method. The discrete WIMV method produced better results, which illustrate a more or less random orientation distribution for cubic garnet. Apparently elongated grains turned out to be layers of randomly oriented crystals. Monoclinic omphacite displays a sharp texture, with [001] parallel to the lineation direction. The texture data obtained by neutron diffraction were verified with EBSP (electron backscatter pattern) measurements.


2021 ◽  
Author(s):  
Jeremie Malecki ◽  
Juan Gómez Barreiro ◽  
Manuela Durán Oreja ◽  
José Ramón Martínez Catalán ◽  
Magdalena Tettamanti ◽  
...  

&lt;p&gt;The NW Iberian Massif represents a segment of the Variscan Belt, where several allochthonous complexes crop out: : Cabo Ortegal, Ordenes and Malpica-Tuy, in Spain, and Bragan&amp;#231;a and Morais in Portugal. These allochthonous complexes comprise allochthonous units, overthrusting parautochthonous and autochthonous units. The suture zone of the Variscan orogeny in the NW Iberia preserves the testimony of the collisional dynamics between Gondwana and Laurussia during the Carboniferous. The stacking of allochthonous units into an accretion wedge, and their subsequent incorporation by thrusts into the continental margin of Gondwana, resulted in polyphasic tectonothermal evolution. Different units record valuable information about the deformation mechanisms, rheological behaviour and the configuration of plates during the Palaeozoic.&lt;/p&gt;&lt;p&gt;The kinematic and deformational evolution of major tectonic boundaries of the Variscan Allochthonous units, as well as their mutual relationship in Iberia is critical, in order to constrain their regional meaning and correlation with similar units along the European Variscan Belt. In shear-zones, plastic deformation of polycrystalline aggregates result into microstructural and textural fingerprints that need to be interpreted. Quantitative analyses of fabrics has been crucial in untangling complex tectonothermal evolutions. In this case neutron diffraction experiments have been conducted in transmission mode in the Institute Laue-Langevin (ILL) (France), to characterize mylonites from the basal shear zone of the Lower Allochthon in Morais Complex. Two different experimental sets have been tested in D1B and D20 beamlines, comparing textural standards and new vanadium sample holders in order to optimize the procedure. Diffraction data were refined with Rietveld software MAUD to obtain quantitative texture information and orientation distribution functions (ODF) for main phases. Afterward, pole figures of relevant planes were interpreted in terms of slip-system activity to understand deformation conditions. Overall, microstructural data and fabric analysis points to a top-to-the SE shearing with a pure-shear component in the mylonitic flow.&lt;/p&gt;&lt;p&gt;&lt;strong&gt;Keywords&lt;/strong&gt;: Shear zones, texture analysis, neutron diffraction, Rietveld method, Variscan orogeny, Morais complex.&lt;/p&gt;


2020 ◽  
Vol 113 (1) ◽  
Author(s):  
Stefano Ghignone ◽  
Gianni Balestro ◽  
Marco Gattiglio ◽  
Alessandro Borghi

Abstract In the Western Alps, different shear zones acting at different depths have been investigated for explaining multistage exhumation of (U)HP units, and several exhumation models have been proposed for explaining present-day stacking of different tectonometamorphic units. This study aims to reconstruct the tectonic evolution of the Susa Shear Zone (SSZ), a polyphasic first-order shear zone, outcropping in the Susa Valley. The SSZ consists of a thick mylonitic zone, along which units characterized by different Alpine metamorphic P–T peaks are coupled. In the study area, the footwall of the SSZ mostly consists of oceanic units (i.e., Internal Piedmont Zone), which record eclogitic conditions, whereas the hanging wall consists of oceanic units (i.e., External Piedmont Zone), which record blueschist-facies conditions. These tectonic units were deformed during subduction- and exhumation-related Alpine history, throughout four main regional deformation phases (from D1 to D4), and were coupled along the SSZ, wherein two shearing events have been distinguished (T1 and T2). T1 occurred during early exhumation and was characterized by “apparent reverse” Top-to-E kinematics, whereas T2 occurred during late exhumation and was characterized by Top-to-W kinematics. Detailed fieldwork and structural analysis allowed us to describe the main features of the different deformation stages and define the deformation relative timing. As final result, we propose a four-step geodynamic model, focused on the different stages developed along the SSZ, from pre-T1 to syn-T2, showing the geometrical relationships between the tectonic units involved in the exhumation. The model aims at explaining the role of the SSZ in the axial sector of the Western Alps.


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