New detrital zircon U-Pb ages and Lu-Hf isotopic data from metasedimentary rocks along the western boundary of the composite Avalon terrane in the southeastern New England Appalachians

ABSTRACT West Avalonia is a composite terrane that rifted from the supercontinent Gondwana in the Ordovician and accreted to Laurentia during the latest Silurian to Devonian Acadian orogeny. The nature and extent of West Avalonia are well constrained in Nova Scotia, New Brunswick, and Newfoundland, Canada, by U-Pb detrital zircon data and/ or isotope geochemistry of (meta)sedimentary and igneous rocks. The southeastern New England Avalon terrane in eastern Massachusetts, Connecticut, and Rhode Island has generally been interpreted as an along-strike continuance of West Avalonia in Canada, but the ages and origins of metasedimentary units along the western boundary of the Avalon terrane in Massachusetts and Connecticut remain poorly constrained. In this study, new detrital zircon U-Pb and Lu-Hf laser-ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) data from three samples of metasedimentary units along the western boundary of the southeastern New England Avalon terrane in Connecticut and Massachusetts were compared with existing data to test whether these metasedimentary units can be correlated along strike. The data were also compared with existing detrital zircon U-Pb and εHf data in New England and Canada in order to constrain the extent and provenance of West Avalonia. The maximum depositional age of two of the three detrital zircon samples analyzed in this study, based on the youngest single grain in each sample (600 ± 28 Ma, n = 1; 617 ± 28 Ma, n = 1) and consistency with existing analyses elsewhere in the southeastern New England Avalon terrane, is Ediacaran, while that of the third sample is Tonian (959 ± 40 Ma, n = 4). Detrital zircon analyses of all three samples from this study showed similar substantial Mesoproterozoic and lesser Paleoproterozoic and Archean populations. Other existing detrital zircon U-Pb data from quartzites in the southeastern New England Avalon terrane show similar Tonian populations with or without Ediacaran grains or populations. Most published detrital zircon U-Pb data from (meta)sedimentary rocks in West Avalonia in Canada yielded Ediacaran youngest detrital zircon age populations, except for a quartzite unit within the Gamble Brook Formation in the Cobequid Highlands of Nova Scotia, which showed a Tonian maximum depositional age, and otherwise a nearly identical detrital zircon signature with rocks from the southeastern New England Avalon terrane. All samples compiled from the southeastern New England Avalon terrane and West Avalonia in Canada show main age populations between ca. 2.0 Ga and ca. 1.0 Ga, with major peaks at ca. 1.95, ca. 1.50, ca. 1.20, and ca. 1.00 Ga, and minor ca. 3.1–3.0 Ga and ca. 2.8–2.6 Ga populations. The εHf(t) values from the three samples yielded similar results to those from West Avalonia in Canada, suggesting that both regions were derived from the same cratonic sources. The εHf(t) values of all West Avalonian samples overlap with both Amazonia and Baltica, suggesting that there is a mixed signature between cratonic sources, possibly as a result of previous collision and transfer of basement fragments between these cratons during the formation of supercontinent Rodinia, or during subsequent arc collisions.

Structure, variability, and dynamics of the West Greenland Boundary Current System

The ventilation of intermediate waters in the Labrador Sea has important implications for the strength of the Atlantic Meridional Overturning Circulation. Boundary current-interior interactions regulate the exchange of properties between the slope and the basin, which in turn regulates the magnitude of interior convection and the export of ventilated waters from the subpolar gyre. This thesis characterizes theWest Greenland Boundary Current System near Cape Farewell across a range of spatio-temporal scales. The boundary current system is composed of three velocity cores: (1) the West Greenland Coastal Current (WGCC), transporting Greenland and Arctic meltwaters on the shelf; (2) the West Greenland Current (WGC), which advects warm, saline Atlantic-origin water at depth, meltwaters at the surface, and newly-ventilated Labrador Sea Water (LSW); and (3) the Deep Western Boundary Current, which carries dense overflow waters ventilated in the Nordic Seas. The seasonal presence of the LSW and Atlantic-origin water are dictated by air-sea buoyancy forcing, while the seasonality of the WGCC is governed by remote wind forcing and the propagation of coastally trapped waves from East Greenland. Using mooring data and hydrographic surveys, we demonstrate mid-depth intensified cyclones generated at Denmark Strait are found offshore of the WGC and enhance the overflow water transport at synoptic timescales. Using mooring, hydrographic, and satellite data, we demonstrate that the WGC undergoes extensive meandering due to baroclinic instability that is enhanced in winter due to LSW formation adjacent to the current. This leads to the production of small-scale, anticyclonic eddies that can account for the entirety of wintertime heat loss within the Labrador Sea. The meanders are shown to trigger the formation of Irminger Rings downstream. Using mooring, hydrographic, atmospheric, and Lagrangian data, and a mixing model, we find that strong atmospheric storms known as forward tip jets cause upwelling at the shelfbreak that triggers offshore export of freshwater. This freshwater flux can explain the observed lack of ventilation in the eastern Labrador Sea. Together, this thesis documents previously unobserved interannual, seasonal, and synoptic-scale variability and dynamics within the West Greenland boundary current system that must be accounted for in future modeling.

New age constraints on magmatism and metamorphism in the Morin terrane (Grenville Province, Quebec)

The Morin terrane is an allochthonous crustal block in the southwestern Grenville Province with a relatively poorly-constrained metamorphic history. In this part of the Grenville Province, some terranes were part of the ductile middle crust during the 1.09–1.02 Ga collision of Laurentia with the Amazon craton (the Ottawan phase of the Grenvillian orogeny), while other terranes were part of the orogen’s superstructure. New U-Pb geochronology suggests that the Morin terrane experienced granulite-facies metamorphism during the accretionary Shawinigan orogeny (1.19–1.14 Ga) and again during the Ottawan. Seven zircon samples from the 1.15 Ga Morin anorthosite suite were dated to confirm earlier age determinations, and Ottawan metamorphic rims (1.08–1.07 Ga) were observed in two samples. U-Pb dating of titanite in nine marble samples surrounding the Morin anorthosite suite yielded mixed ages spanning between the Shawinigan and Ottawan metamorphisms (n=7), and predominantly Ottawan ages (n=2). Our results show that Ottawan zircon growth and resetting of titanite ages is spatially heterogeneous in the Morin terrane. Ages with a predominantly Ottawan signature are recognized in the Morin shear zone, which deforms the eastern lobe of the anorthosite, in an overprinted skarn zone on the western side of the massif, and in the Labelle shear zone that marks its western boundary. In the rest of the Morin terrane titanite with Shawinigan ages appear to have been only partially reset during the Ottawan. Further work is needed to better understand the relationship between the character of Ottawan metamorphism and resetting in different parts of the Morin terrane.

Shelf Transport Pathways Adjacent to the East Australian Current Reveal Sources of Productivity for Coastal Reefs

The region where the East Australian Current (EAC) separates from the coast is dynamic and the shelf circulation is impacted by the interplay of the western boundary current and its eddy field with the coastal ocean. This interaction can drive upwelling, retention or export. Hence understanding the connection between offshore waters and the inner shelf is needed as it influences the productivity potential of valuable coastal rocky reefs. Near urban centres, artificial reefs enhance fishing opportunities in coastal waters, however these reefs are located without consideration of the productivity potential of adjacent waters. Here we identify three dominant modes of mesoscale circulation in the EAC separation region (~31.5−34.5°S); the ‘EAC mode’ which dominates the flow in the poleward direction, and two eddy modes, the ‘EAC eddy mode’ and the ‘Eddy dipole mode’, which are determined by the configuration of a cyclonic and anticyclonic eddy and the relationship with the separated EAC jet. We use a Lagrangian approach to reveal the transport pathways across the shelf to understand the impact of the mesoscale circulation modes and to explore the productivity potential of the coastal waters. We investigate the origin (position and depth) of the water that arrives at the inner-mid shelf over a 21-day period (the plankton productivity timescale). We show that the proportion of water that is upwelled from below the euphotic zone varies spatially, and with each mesoscale circulation mode. Additionally, shelf transport timescales and pathways are also impacted by the mesoscale circulation. The highest proportion of upwelling (70%) occurs upstream of 32.5°S, associated with the EAC jet separation, with vertical displacements of 70–120 m. From 33 to 33.5°S, water comes from offshore above the euphotic layer, and shelf transport timescales are longest. The region of highest retention over the inner shelf is immediately downstream of the EAC separation region. The position of the EAC jet and the location of the cyclonic eddy determines the variability in shelf-ocean interactions and the productivity of shelf waters. These results are useful for understanding productivity of temperate rocky reefs in general and specifically for fisheries enhancements along an increasingly urbanised coast.

Hydrochemical Characteristics of Earthquake-Related Thermal Springs along the Weixi–Qiaohou Fault, Southeast Tibet Plateau

The Weixi–Qiaohou Fault (WQF) is considered an important zone of the western boundary of the Sichuan–Yunnan block, and its seismicity has attracted much attention after a series of moderate–strong earthquakes, especially the Yangbi Ms6.4 earthquake that occurred on 21 May 2021. In the present research, we investigate major and trace elements, as well as hydrogen and oxygen isotopes, of 10 hot springs sites located along the WQF, which are recharged by infiltrated precipitation from 1.9 to 3.1 km. The hydrochemical types of most analyzed geothermal waters are HCO3SO4-Na, SO4Cl-NaCa, and SO4-Ca, proving that they are composed of immature water and thus are characterized by weak water–rock reactions. The heat storage temperature range was from 44.1 °C to 101.1 °C; the circulation depth was estimated to range between 1.4 and 4.3 km. The results of annual data analysis showed that Na+, Cl−, and SO42− in hot springs decreased by 11.20% to 23.80% north of the Yangbi Ms5.1 earthquake, which occurred on 27 March 2017, but increased by 5.0% to 28.45% to the south; this might be correlated with the difference in seismicity within the fault zone. The results of continuous measurements of NJ (H1) and EYXX (H2) showed irregular variation anomalies 20 days before the Yangbi Ms6.4 earthquake. In addition, Cl− concentration is more sensitive to near-field seismicity with respect to Na+ and SO42−. We finally obtained a conceptual model on the origin of groundwater and the hydrogeochemical cycling process in the WQF. The results suggest that anomalies in the water chemistry of hot spring water can be used as a valid indicator of earthquake precursors.

Spatial distribution of turbulent diapycnal mixing along the Mindanao current inferred from rapid-sampling Argo floats

The Mindanao Current (MC) bridges the North Pacific low-latitude western boundary current system region and the Indonesian Seas by supplying the North Pacific waters to the Indonesian Throughflow. Although the previous study speculated that the diapycnal mixing along the MC might be strong on the basis of the water mass analysis of the gridded climatologic dataset, the real spatial distribution of diapycnal mixing along the MC has remained to be clarified. We tackle this question here by applying a finescale parameterization to temperature and salinity profiles obtained using two rapid-sampling profiling Argo floats that drifted along the MC. The western boundary (WB) region close to the Mindanao Islands and the Sangihe Strait are the two mixing hotspots along the MC, with energy dissipation rate ε and diapycnal diffusivity Kρ enhanced up to ~ 10–6 W kg−1 and ~ 10–3 m2 s−1, respectively. Except for the above two mixing hotspots, the turbulent mixing along the MC is mostly weak, with ε and Kρ to be 10–11–10–9 W kg−1 and 10–6–10–5 m2 s−1, respectively. Strong mixing in the Sangihe Strait can be basically attributed to the existence of internal tides, whereas strong mixing in the WB region suggests the existence of internal lee waves. We also find that water mass transformation along the MC mainly occurs in the Sangihe Strait where the water masses are subjected to strong turbulent mixing during a long residence time.

Reduction in meridional heat export contributes to recent Indian Ocean warming

Since 2000, the Indian Ocean has warmed more rapidly than the Atlantic or Pacific. Air-sea fluxes alone cannot explain the rapid Indian Ocean warming, which has so far been linked to an increase in temperature transport into the basin through the Indonesian Throughflow (ITF). Here, we investigate the role that the heat transport out of the basin at 36°S plays in the warming. Adding the heat transport out of the basin to the ITF temperature transport into the basin, we calculate the decadal mean Indian Ocean heat budget over the 2010s. We find that heat convergence increased within the Indian Ocean over 2000-2019. The heat convergence over the 2010s is the same order as the warming rate, and thus the net air-sea fluxes are near zero. This is a significant change from previous analyses using trans-basin hydrographic sections from 1987, 2002, and 2009, which all found divergences of heat. A two year time series shows that seasonal aliasing is not responsible for the decadal change. The anomalous ocean heat convergence over the 2010s compared to previous estimates is due to changes in ocean currents at both the southern boundary (33%) and the ITF (67%). We hypothesize that the changes at the southern boundary are linked to an observed broadening of the Agulhas Current, implying that temperature and velocity data at the western boundary are crucial to constrain heat budget changes.

Supplemental Material: New detrital zircon U-Pb ages and Lu-Hf isotopic data from metasedimentary rocks along the western boundary of the composite Avalon terrane in the southeastern New England Appalachians

U-Pb LA-ICP-MS detrital zircon data for three samples collected along the western boundary of the Avalon terrane in southeastern New England

Supplemental Material: New detrital zircon U-Pb ages and Lu-Hf isotopic data from metasedimentary rocks along the western boundary of the composite Avalon terrane in the southeastern New England Appalachians

U-Pb LA-ICP-MS detrital zircon data for three samples collected along the western boundary of the Avalon terrane in southeastern New England

Supplemental Material: New detrital zircon U-Pb ages and Lu-Hf isotopic data from metasedimentary rocks along the western boundary of the composite Avalon terrane in the southeastern New England Appalachians

U-Pb LA-ICP-MS detrital zircon data for three samples collected along the western boundary of the Avalon terrane in southeastern New England