scholarly journals Synthesis of Aromatic Rings Embedded in Polycyclic Scaffolds by Triyne Cycloaddition: Competition between Carbonylative and Non-Carbonylative Pathways

Molecules ◽  
2019 ◽  
Vol 24 (3) ◽  
pp. 595
Author(s):  
Laura Salacz ◽  
Nicolas Girard ◽  
Jean Suffert ◽  
Gaëlle Blond
Keyword(s):  
Aromatic Ring ◽  
Aromatic Rings ◽  
One Pot ◽  
Polycyclic Compounds ◽  
One Pot Synthesis ◽  
The One

Cycloadditions have emerged as some of the most useful reactions for the formation of polycyclic compounds. The carbonylative cycloaddition of triynes can lead to carbonylative and non-carbonylative competitive pathways, each leading to the formation of an aromatic ring. We report herein the one-pot synthesis of fully- and unsymmetrically-substituted tetracyclic 6,5,7,5-troponic and 6,5,6,5-benzenoid scaffolds using pre-organized triynes showing the competition between these two pathways.

An Overview of the One-pot Synthesis of Imidazolines

2020 ◽  
Vol 24 (20) ◽  
pp. 2341-2355
Author(s):  
Thaipparambil Aneeja ◽  
Sankaran Radhika ◽  
Mohan Neetha ◽  
Gopinathan Anilkumar
Keyword(s):  
Asymmetric Catalysis ◽  
Organic Compounds ◽  
Ring Opening ◽  
Ecological Impact ◽  
Chiral Auxiliary ◽  
One Pot ◽  
One Pot Synthesis ◽  
The One ◽  
Synthetic Intermediate ◽  
Heterocyclic Moiety

One-pot syntheses are a simple, efficient and easy methodology, which are widely used for the synthesis of organic compounds. Imidazoline is a valuable heterocyclic moiety used as a synthetic intermediate, chiral auxiliary, chiral catalyst and a ligand for asymmetric catalysis. Imidazole is a fundamental unit of biomolecules that can be easily prepared from imidazolines. The one-pot method is an impressive approach to synthesize organic compounds as it minimizes the reaction time, separation procedures, and ecological impact. Many significant one-pot methods such as N-bromosuccinimide mediated reaction, ring-opening of tetrahydrofuran, triflic anhydrate mediated reaction, etc. were reported for imidazoline synthesis. This review describes an overview of the one-pot synthesis of imidazolines and covers literature up to 2020.

Convenient One-Pot Synthesis of α-Selenonitriles, α-Selenoesters and Asymmetrical Selenides by a Sm/ZnCl2 system in DMF-H2O

2001 ◽  
Vol 2001 (4) ◽  
pp. 160-161 ◽  
Author(s):  
Hongyun Guo ◽  
Yunfa Zheng ◽  
Yongmin Zhang
Keyword(s):  
One Pot ◽  
One Pot Synthesis ◽  
Organic Halides ◽  
The One

α-Selenonitriles, α-selenoesters, and asymmetrical selenides can be readily obtained from the one-pot reaction of diselenides and active organic halides by a Sm/ZnCl2 system in DMF-H2O.

A New Strategy for the One Pot Synthesis of (Aryloxyimino)Ethylcoumarins Promoted by CuCl2

2012 ◽  
Vol 36 (1) ◽  
pp. 5-8 ◽  
Author(s):  
Gargi Pal ◽  
Pranabes Bhattacharyya ◽  
Arunima Medda ◽  
Asish R. Das
Keyword(s):  
One Pot ◽  
One Pot Synthesis ◽  
New Strategy ◽  
The One
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