scholarly journals Towards Highly Efficient TADF Yellow-Red OLEDs Fabricated by Solution Deposition Methods: Critical Influence of the Active Layer Morphology

Nanomaterials ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 101 ◽  
Author(s):  
Manish Kumar ◽  
Luiz Pereira

Organic light-emitting diodes (OLEDs) based on thermally activated delayed fluorescence emitters (TADF) in simple device structures fabricated by solution processing are strongly dependent on a suitable host molecular conformation and morphology. Herein, we report the fabrication of highly efficient yellow-red TADF-based OLEDs via solution processing in a simple, two-organic-layer device structure. The devices were fabricated at different weight concentrations of 5%, 8%, and 10% emitter in an n-/p-type mixed host matrix, and their characteristics were studied. The device performance was compared with different thickness parameters for both the emitting layer (EML) and the electron transport layer (ETL) in various solvents, including chlorobenzene, dichlorobenzene, and chloroform. By optimizing the mixed ratio of EML, yellow-red OLEDs of 2-[4 (diphenylamino)phenyl]-10,10-dioxide-9H-thioxanthen-9-one (TXO-TPA) emitter in an n-/p-type host matrix of poly(N-vinylcarbazole):1,3-Bis[2-(4-tert-butylphenyl)-1,3,4-oxadiazo-5-yl]benzene (PVK:OXD-7) as a blend for the active layer were fabricated. In the best results, the device exhibited a lower turn-on voltage at around 6 V, with an external quantum efficiency (EQE) of 18.44%, current efficiency of 36.71 cd/A, and power efficiency of 14.74 Lm/W for the 8% emitter concentration. The importance of solvent for improving the electrical properties, together with organic layer thickness and host effect for the charge carrier’s transport and device characteristics are also discussed.

2017 ◽  
Vol 8 (5) ◽  
pp. 1702235 ◽  
Author(s):  
Mahdi Malekshahi Byranvand ◽  
Taewan Kim ◽  
Seulki Song ◽  
Gyeongho Kang ◽  
Seung Un Ryu ◽  
...  

2020 ◽  
Vol 64 (4) ◽  
pp. 808-819
Author(s):  
Shenya Qu ◽  
Jiangsheng Yu ◽  
Jinru Cao ◽  
Xin Liu ◽  
Hongtao Wang ◽  
...  

2021 ◽  
Author(s):  
Irfan Qasim ◽  
Owais Ahmad ◽  
Asim Rashid ◽  
Tashfeen Zehra ◽  
Muhammad Imran Malik ◽  
...  

Abstract Solar energy is found to be low cost and abundant of all available energy resources and needs exploration of highly efficient devices for global energy requirements. We have investigated methyl ammonium tin halide (CH3NH3SnI3)-based perovskite solar cells (PSCs) for optimized device performance using solar capacitance simulator SCAPS-1D software. This study is a step forward towards availability of stable and non-toxic solar cells. We explored all necessary parameters such as metal work functions, thickness of absorber and buffer layers, charge carrier’s mobility and defect density for improved device performance. Calculations revealed that for the best efficiency of device the maximum thickness of the perovskite absorber layer must be 4.2 μm. Furthermore, optimized thickness values of (ZnO=0.01 μm) as electron transport layer (ETL), GaAs as hole transport layer (HTL=3.02 μm) and (CdS=10 nm) and buffer layer have provided power conversion efficiency (PCE) of 23.53%. Variation of open circuit voltage (Voc), Short circuit current (Jsc), Fill Factor (FF%) and quantum efficiency against thickness of all layers in FTO/ZnO/CdS/CH3NH3SnI3/GaAs/Au compositions have been critically explored and reported. Interface defects and defect density in different inserted layers have also been reported in this study as they can play a crucial for the device performance. Insertion of ZnO layer and CdS buffer layers have shown improved device performance and PCE. Current investigations may prove to be useful for designing and fabrication of climate friendly, non-toxic and highly efficient solar cells.


2020 ◽  
Vol 2 (6) ◽  
pp. 1545-1553
Author(s):  
Mangey Ram Nagar ◽  
Shahnawaz ◽  
Rohit Ashok Kumar Yadav ◽  
Jin-Ting Lin ◽  
Jwo-Huei Jou

2014 ◽  
Vol 6 (18) ◽  
pp. 15875-15880 ◽  
Author(s):  
Hong Il Kim ◽  
Thi Thu Trang Bui ◽  
Guan-Woo Kim ◽  
Gyeongho Kang ◽  
Won Suk Shin ◽  
...  

ChemSusChem ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2779-2785 ◽  
Author(s):  
Haoliang Cheng ◽  
Yaru Li ◽  
Meirong Zhang ◽  
Ke Zhao ◽  
Zhong‐Sheng Wang

Nanoscale ◽  
2019 ◽  
Vol 11 (45) ◽  
pp. 21917-21926 ◽  
Author(s):  
Zhichao Lin ◽  
Jingjing Yan ◽  
Qingbin Cai ◽  
Xiaoning Wen ◽  
Hongye Dong ◽  
...  

Co-modification of an electron transport layer (ETL) with metal oxides and organic molecules can optimize the structure of the ETL and improve the performance of perovskite solar cells (PSCs).


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