scholarly journals Efficient Hydrophobic Modification of Old Newspaper and Its Application in Paper Fiber Reinforced Composites

Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 842 ◽  
Author(s):  
Weiwei Zhang ◽  
Jin Gu ◽  
Dengyun Tu ◽  
Litao Guan ◽  
Chuanshuang Hu

Paper fibers have gained broad attention in natural fiber reinforced composites in recent years. The specific problem in preparing paper fiber reinforced composites is that paper fibers easily become flocculent after pulverization, which increases difficulties during melt-compounding with polymer matrix and results in non-uniform dispersion of paper fibers in the matrix. In this study, old newspaper (ONP) was treated with a low dosage of gaseous methyltrichlorosilane (MTCS) to solve the flocculation. The modified ONP fibers were characterized by Scanning Electron Microscope (SEM), Fourier Transform Infrared Spectroscopy (FTIR), and Thermogravimetric Analysis (TG). Then the modified ONP fibers and high-density polyethylene (HDPE) were extruded and pelletized to prepare ONP/HDPE composites via injection molding. Maleic anhydride-grafted polyethylene (MAPE) was added to enhance the interfacial bonding performance with the ultimate purpose of improving the mechanical strength of the composites. The mechanical properties such as tensile, flexural, and impact strength and the water absorption properties of the composite were tested. The results showed that the formation of hydrogen bonding between ONP fibers was effectively prevented after MTCS treatment due to the reduction of exposed –OH groups at the fiber surface. Excessive dosage of MTCS led to severe fiber degradation and dramatically reduced the aspect ratio of ONP fibers. Composites prepared with ONP fibers modified with 4% (v/w) MTCS showed the best mechanical properties due to reduced polarity between the fibers and the matrix, and the relatively long aspect ratio of treated ONP fibers. The composite with or without MAPE showed satisfactory water resistance properties. MTCS was proven to be a cheap and efficient way to pretreat old newspaper for preparing paper fiber reinforced composites.

Author(s):  
Vijay Kumar Mahakur ◽  
Sumit Bhowmik ◽  
Promod Kumar Patowari

Nowadays, the utilization of natural fiber reinforced composite has increased frequently. These natural fibers have significant features like low cost, renewable, and, more importantly, biodegradable in nature, making them to be utilized for various industrial sectors. However, the massive demand for natural fiber reinforced composites (NFRC), forces them to be machined and operated, which is required for countless areas in multiple industries like automotive, marine, aerospace and constructions. But before obtaining the final shape of any specimen, this specimen should come across numerous machining processes to get the desired shape and structure. Therefore, the present review paper focused on the various aspects during conventional and unconventional machining of the NFRC. It covers the work by exploring the influence of all input variables on the outcome produced after machining the NFRC. Various methodologies and tools are also discussed in this article for reducing the machining defects. The machining of the NFRC is found as a challenging task due to insufficient interlocking between the matrix and fibers, and minimum knowledge in machining characteristics and appropriate input parameters. Thus, this review is trying to assist the readers to grasp a basic understanding and information during the machining of the NFRC in every aspect.


2019 ◽  
Vol 23 ◽  
pp. 6-30
Author(s):  
Volkan Uğraşkan ◽  
Abdullah Toraman ◽  
A. Binnaz Hazar Yoruç

In early composite materials, the use of petroleum based fibers such as glass and carbon fibers, aramid etc. was common. In order to reduce the dependency on petroleum based sources and environmental pollution, researchers have focused on the search for alternative sources. Natural fibers are abundant, recyclable and biodegradable plant derived materials. Besides, thanks to good physical, thermal and mechanical properties, natural fibers become promising alternative for composites. This review includes information about natural fiber reinforced composites’ components, manufacturing methods, mechanical properties and applications.


2019 ◽  
Vol 54 (8) ◽  
pp. 1031-1048 ◽  
Author(s):  
Yang Yang ◽  
Qi He ◽  
Hong-Liang Dai ◽  
Jian Pang ◽  
Liang Yang ◽  
...  

A micromechanical model for short fiber-reinforced composites (SFRCs) with functionally graded interphases and a systematic prediction scheme to determine the effective properties are presented. The matrix and the fibers are regarded to be linear elastic, isotropic, and homogeneous. Fibers are assumed to be ellipsoids coated perfectly by functionally graded interphases, which is supposed to be formed chemically or physically by the constituents near the interface. First, to analyze the grading interphase effect, layer-wise concept is followed to divide the functionally graded interphases into multi-homogeneous sub-layers. Next, to take the effect of functionally graded interphases into account, a combination of multi-inclusion method and Mori–Tanaka method is applied to predict effective elastic properties of this unidirectional SFRCs with respect to the content and aspect ratio of the inclusions. By employing coordinate transformation, spatially elastic moduli are obtained. Finally, Voigt homogenization scheme is used to obtain the overall, averaged, symmetrical elastic properties of the SFRCs. Numerical examples and analyses demonstrate the applicability of the proposed method and indicate the influences of graded interphase, orientation, and aspect ratio of inclusions as well as properties and contents of the constituents on the overall properties of SFRCs.


Nowadays, Natural Fiber Reinforced composites (NFCs) are emerging to be a good substitute for synthetic fiber reinforced composites as NFCs have many advantages such as low density, high specific strength, recyclability, low cost and good sound abatement quality etc. Among all types of NFCs, a vast study has been done on banana fiber and kenaf fiber reinforced composite. However, only limited work has been done on the banana fabric, kenaf fiber reinforced composite and the effect of their hybridization on mechanical properties. In this paper, an attempt has been made to study the mechanical properties of the banana fabric, kenaf fiber and hybrid banana fabric/kenaf fiber reinforced composites. Effect of alkali treatment on kenaf fiber reinforced composite is discussed in the paper. For the present work, plain-woven banana fabric and randomly oriented kenaf fiber are used as reinforcement while the epoxy resin is used as a matrix. samples are fabricated using hand lay-up and vacuum bagging method. Curing is done at ambient temperature (250C-300C) for 48h. Tensile, impact and hardness test has been performed on a specimen according to ASTM standards. Improvement in mechanical properties is observed after alkali (6% NaOH) treatment on kenaf fiber reinforced composite. Tensile testing behavior of randomly oriented kenaf fiber composite has been studied using Finite element method and results are compared with experimental investigations. This topic present big potential because it seeks to find solution for sustainable development with environmental concerns.


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