scholarly journals Sensitivity Analysis of the Climate Effect of Using Pyrochar Biofuel for Heat and Electricity Generation

Processes ◽  
2021 ◽  
Vol 9 (10) ◽  
pp. 1744
Author(s):  
Johanna Högosta ◽  
Ali Mohammadi

This study aims to quantify the climate change impact of pyrochar production from pulp and paper mill sludge and the subsequent utilisation in combined heat and power (CHP) plants for co-generation of heat and electricity using the environmental life cycle assessment (E-LCA) method. In the Pyrochar Scenario, in which the sludge is pyrolyzed into pyrochar, the authors have assumed that pyrochar would replace coal. In the Reference Scenario, sludge is incinerated with a subsequent low rate of energy recovery. A comprehensive sensitivity analysis was performed to determine the conditions in which the sludge pyrochar would offer the greatest climate-effect benefits. The parameters selected for the said analysis are the form of pyrochar (pellet or powder), fuels replaced by it in the CHP plant (solid waste and peat vis-à-vis coal), and the utilisation of the pyrochar fuel in another European country (Germany and Spain vis-à-vis Sweden). The results of this E-LCA clearly show that using pyrochar as a biofuel in CHP plants delivered a considerable reduction in greenhouse gas (GHG) emissions (−1.87 tonne CO2-eq per 2.8 tonne dry sludge). Contribution analysis reveals that the process accounting for the biggest share of the reduction is the pyrochar combustion (a negative contribution of 76%), which results in a displacement of coal-based fuels. The authors conclude that the utilisation of pyrochar in firing units would provide the highest reduction in GHG emissions, while recommending a comprehensive economic analysis in addition to climate effect assessment, before making a decision regarding the introduction of sludge pyrochar to the energy sector.

2019 ◽  
Vol 23 (5) ◽  
pp. 1039-1051 ◽  
Author(s):  
Ali Mohammadi ◽  
Maria Sandberg ◽  
G. Venkatesh ◽  
Samieh Eskandari ◽  
Tommy Dalgaard ◽  
...  

2008 ◽  
Vol 43 (2-3) ◽  
pp. 161-171 ◽  
Author(s):  
Pierre Martel ◽  
Tibor Kovacs ◽  
Virginie Bérubé

Abstract Pulp and paper mill effluents have been reported to cause changes in reproductive indicators of fish in laboratory and field studies. These changes include reduced egg production and gonad size, and altered hormone levels and expression of secondary sex characteristics. We examined the performance of biotreatment plants for their potential in abating effects of pulp and paper mill effluents on fish reproduction under laboratory conditions. A bleached kraft mill effluent (BKME) treated in an aerated lagoon and a thermomechanical pulp mill effluent (TMPE) treated by aerobic sludge in a sequential batch reactor were selected for study. Mature fathead minnows (Pimephales promelas) were exposed to effluents before and after biotreatment under continuous renewal conditions for 21 days. Egg production was monitored daily, while morphometric parameters (length, weight, gonad size), secondary sexual characteristics, and steroid hormone and vitellogenin levels were measured at the end of the effluent exposure. The effluent from both mills before biotreatment impaired the reproductive capacity of minnows (egg production) at concentrations of 10 and 20% vol/vol, but not at 2% vol/vol. Exposure to biotreated effluents from both mills at concentrations of 2, 10, 20, and 40% vol/vol caused no significant differences in overall reproductive capacity of minnows as compared with controls. These results indicate that biotreatment can significantly improve the quality of a BKME and an effluent from a TMP mill with respect to the reproductive capacity of fish as determined in laboratory tests.


1988 ◽  
Vol 23 (4) ◽  
pp. 568-577
Author(s):  
Harold S. Bailey

Abstract The water quality of the upper 110 kilometres of the St. Croix River is considered to be pristine. A major industrial discharge renders the lower 14 kilometres of the river a water quality limited segment. Prior to 1970 the Georgia-Pacific Pulp and Paper Mill at Woodland, Maine, discharged untreated effluent directly into the river causing dissolved oxygen concentrations to drop well below 5 mg/L, the objective chosen in the interest of restoring endemic fish populations. Since 1972, the Mill has installed primary and secondary treatment, regulated river discharge rate and effluent composition which has greatly improved the summer dissolved oxygen regime. By 1980, dissolved oxygen concentrations were generally above 5.0 mg/L and restocking the river with Atlantic Salmon (Salmo salar) was initiated.


1992 ◽  
Vol 25 (2) ◽  
pp. 57-64
Author(s):  
C. G. Jardine

As part of the Remedial Action Plan (RAP) programs for the St. Lawrence and Spanish Rivers in Ontario, Canada, tainting evaluations were conducted using members of the Public Advisory Committees (PACs) and the RAP teams. Triangle test sensory evaluations were conducted on caged rainbow trout (Salmo gairdneri) exposed insitu upstream and downstream of the pulp and paper mill diffuser outfalls In the St. Lawrence River only, evaluations were conducted on indigenous yellow perch (Perca flavescens) caught upstream and downstream of the mill discharge . In both locations, the odour of the flesh from the caged trout exposed above the diffuser outfall was not judged significantly different from caged trout exposed downstream of the discharge. However, the indigenous perch caught downstream of the mill in the St. Lawrence River were judged by the panelists to have a significantly more objectionable odour than those caught upstream of the discharge. While the effluent tainting potential appears to have been eliminated in the Spanish River, further studies are required to determine the source and magnitude of tainting concerns in the St. Lawrence River. The sensory test and results reported here provide useful tools for evaluating the tainting potential of pulp mill discharges and for assessing perceived consumer quality of the fish exposed to these effluents.


1988 ◽  
Vol 20 (2) ◽  
pp. 143-152 ◽  
Author(s):  
A. Langi ◽  
M. Priha

The mutagenic properties of pulp and paper mill effluents were studied in three mills: bleached kraft mill with aerated lagoon treatment (Mill 1), bleached kraft mill with activated sludge treatment (Mill 2) and mechanical pulp/paper mill (Mill 3). Both treated and untreated effluents, process streams and molecular fractions were tested for mutagenicity (Ames test. Salmonella typhimurium TA100 and SCE sister chromatid exchange test, Chinese hamster ovary cells). To verify the potential environmental effects the mutagenic activity of concentrated recipient lake water (Mill 2) was also studied. The Ames mutagenicity of the bleached kraft mill effluent (BKME) originated from the first chlorination filtrate, SCE mutagenicity also occurred in the alkali extraction stage filtrate (Mill 1). No Ames mutagenicity was detected in the paper mill effluent, but it was SCE mutagenic. Activated sludge treatment of BKME removed both Ames and SCE mutagenicity, but the aerated lagoon treated BKME was still SCE mutagenic. No mutagenic activity was detected in the recipient water concentrates.


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