Effect of biomass-based carbon capture on the sustainability and economics of pulp and paper production in the Nordic mills

Bioenergy with carbon capture and storage (BECCS) is one of the key negative emission technologies (NETs). Large-scale implementation of BECCS has been criticized of the associated increase in land use. The existing large Nordic pulp and paper production units enable BECCS deployment without additional land use, as they currently release large amounts of bio-based carbon dioxide (CO2). The application of BECCS in pulp mills has been found technically feasible in earlier studies. This study explores key factors that affect the propensity to invest in BECCS in different types of existing European pulp and paper mills. The results give fresh understanding on the effects of BECCS on the market price of pulp and paper products and the required level of incentives. Based on statistical data, the marginal carbon dioxide credit (€ per ton CO2) to make BECCS profitable was derived. The results show that the required level of credit greatly depends on the mill type and details and that the feasibility of BECCS does not clearly correlate with the economic performance or the measured efficiency of the mill. The most promising mill type, a market kraft pulp mill, would find BECCS profitable with a credit in the range of 62–70 €/tCO2 and a credit of 80 €/tCO2 would decrease pulp production costs by 15 €/tproduct on average if 50% of CO2 emissions was captured. The EU Emission Trading System (ETS) is the main policy instrument to achieve the climate targets related to fossil energy use, but does not yet contemplate bio-based emissions.

Quantifying the Life Cycle Greenhouse Gas Emissions of a Mechanized Shelterwood Harvest Producing Both Sawtimber and Woodchips

Forests are used to mitigate anthropogenic greenhouse gas (GHG) emissions through carbon offset programs, and forest management is generally accepted as “carbon neutral”. However, forest harvesting operations depend heavily on fossil fuels, so it would be remiss to broadly paint all forms of management as carbon neutral without empirical verification of this claim. Biomass feedstock, as a means to supplant fossil fuel consumption, has received the bulk of investigative efforts, as the carbon benefit of biomass is one of the most contentious among wood products, because it does not create long-term carbon storage. A life cycle assessment (LCA) was conducted on a winter shelterwood harvest occurring in the Adirondacks of upstate New York. Primary data were collected daily throughout the operation and used to model the impact attributed to producing clean chips and logs for delivery to a pulp mill and sawmill, respectively. This harvest produced 4894 Mg of clean chips and 527 Mg of sawtimber. We calculated that 39.77 and 25.16 kg of carbon dioxide equivalent were emitted per Mg of clean chips and sawtimber, respectively, with a total observed flow of GHG into the atmosphere between 206 and 210 thousand kilograms. The results contribute to our understanding of the global warming potential of implementing a forest harvest to produce raw materials for medium- and long-term carbon storage products such as paper and dimensional hardwood lumber.

Assessing the Economic Viability of the Mechanized Removal of Understory Beech during a Shelterwood Harvest

Beech bark disease is a pathogenic complex that has been spreading throughout the American beech’s range since the 1800s. A litany of negative consequences have manifested from the infestation of this disease, many of which deteriorate the ecological functions of forestland. This case study sought to analyze the cost structure for removing a recalcitrant beech understory via mechanized shelterwood harvesting. High-resolution data regarding the day-to-day operation of harvesting equipment was collected using daily production journals. Interviews were conducted with the logging company owner and maintenance supervisor to gather additional information required to calculate machine costs, overhead, job specific costs, and trucking costs. The yield from this harvest was 527 metric tonnes of sawtimber and 4,893 tonnes of clean chips. The total harvesting cost equated to $4,651/ha, with the cost attributed to removing beech at $204/ha. Despite the additional cost of beech removal, the logger generated a total profit of $5,965 and a return on investment of 7.5%, allowing us to conclude that mechanized harvesting can be a viable beech removal strategy given the forest stocking and market conditions that are in place. Study Implications This study breaks down the various costs associated with cutting, skidding, landing, and transporting wood products from a mechanized harvesting operation designed to remediate the effects of beech bark disease. The beech remediation harvest was economically viable for both the landowner and the logger because the timber sale included some valuable hardwood sawtimber, and the harvest system was capable of generating clean chips for a pulp mill with the low-grade hardwood. Furthermore, the landowner’s willingness to accept lower sawtimber stumpage revenues allowed the logger to make a profit and return-on-investment on the job. Had the timber sale been limited to only hardwood pulpwood or fuel chips, the operation would not have been economically viable without the landowner paying for the operation, which, based on our analysis, would be approximately $200/ha.

Durable Biopolymer Films From Lignin-Carbohydrate Complex Derived From a Pulp Mill Side Stream

Valorization of side streams offers novel types of raw materials to complement or replace synthetic and food-based alternatives in materials science, increasing profitability and decreasing the environmental impacts of biorefineries. Lignocellulose biomass contains lignin and carbohydrates that are covalently linked into lignin-carbohydrate complexes (LCCs). In biomass fractionation processes, these complexes are conventionally considered as waste, which hinders the biomass fractionation process, and they may solubilize into aqueous effluents. This study presents how LCCs, derived from pulp mill effluent, can be turned into valuable biopolymers for industrial polymer film applications. Free-standing composite films containing hydroxyethyl cellulose (HEC) and LCCs with varying molar mass, charge density and lignin/hemicellulose ratio were prepared to study the effect of LCC amount on mechanical properties and oxygen permeability. Increasing the LCC content increased the yield point and Young’s modulus of the films. Breaking strain measurements revealed a non-linear correlation with the LCC concentration for the samples with higher lignin than hemicellulose content. The addition of LCC enhanced oxygen barrier properties of HEC films significantly even at high relative humidity. The present research demonstrates how a currently underutilized fraction of the biorefinery side stream has the potential to be valorized as a biopolymer in industrial applications, for example as a barrier film for paper and board packaging.

Industrial Ecology and Knots Solid Waste of a Pulp Mill

Os rejeitos de nós são inevitáveis durante a conversão da madeira em polpa dentro do digestor contínuo no processo kraft. No estágio de cozimento ocorre impregnação parcial e consequentemente perda de fibras, assim como danos ambientais. Este trabalho analisa a viabilidade da mistura dos nós com cavacos virgens na alimentação do digestor, aumentando a vida útil do aterro industrial, provendo ganho econômico e ambiental, com base nos princípios da ecologia industrial e produção mais limpa. O sistema de reuso proporcionou um ganho de 781.87 quilogramas por hora de fibras, demonstrando a viabilidade para o reuso dos nós.

The economics of forest bioeconomy: new results

We examine the emerging forest bioeconomy as an integrated multi-product industrial ecosystem, where the traditional pulp mills allocate the use of side streams to independent biochemical companies manufacturing bioproducts in the vicinity of the pulp mills. Biochemical companies benefit from the proximity by receiving wood-based side streams at lower costs and pulp mills from having a new source of revenue from selling side streams. We focus on the economic interaction between the pulp mill and the biochemical company, and study the impacts on the use of wood and profits under perfect and imperfect competition. We demonstrate that the new industrial ecosystem uses more wood than traditional pulp mills, but, depending on the side stream, it may promote cascading use of wood-based side streams.

Refining of crude sulfate turpentine obtained from a kraft pulp mill: A pilot scale treatment

Crude sulfate turpentine (CST), a by-product of the kraft process, has commercial value that depends on the removal of sulfur compounds. The current study investigates desulfurization of CST using basic process steps for a paper mill at a pilot scale treatment. In another aspect, the sulfurous compounds in CST were removed by passing to the aqueous phase with terpin hydrate production, followed by α-terpineol conversion with citric acid catalysis. The goal was to design an environmentally friendly, low-cost, zero waste process and thereby refine the CST or byproducts to a quality that can produce chemical raw materials. Refining processes included hypochlorite oxidation, air oxidation, washing with water, and distillation. The sulfur content was decreased to 170, 106, and 29 ppm from respectively by 1260 ppm initial sulphur content of CST. The chlorine amount, due to treatment with hypochlorite oxidation, did not decrease with refining processes, even in distilled fraction. By obtaining α-terpineol from terpin hydrate, the sulfur compounds were completely removed. According to the GS-MS analysis results, distilled sulfate turpentine (DST) as the final product of the refining process of the CST sample increased the ratio with pinenes. On the other hand, with two reaction steps by obtaining terpin hydrate from CST and then α-terpineol, pinenes were converted to α-terpineol.