scholarly journals Bifunctional g-C3N4/WO3 Thin Films for Photocatalytic Water Purification

Water ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 2439 ◽  
Author(s):  
Maria Antoniadou ◽  
Michalis K. Arfanis ◽  
Islam Ibrahim ◽  
Polycarpos Falaras

A bifunctional thin film photocatalyst consisting of graphitic carbon nitride on tungsten trioxide (g-C3N4/WO3) is introduced for the improvement of photocatalytic activity concerning hexavalent chromium reduction and methylene blue dye removal in water, compared to the bare, widely used WO3 semiconductor. A bilayered structure was formed, which is important for the enhancement of the charge carriers’ separation. The characterization of morphological, structural, optoelectronic, and vibrational properties of the photocatalysts permitted a better understanding of their photocatalytic activity for both dye degradation and Cr+6 elimination in water and the analysis of the photocatalytic kinetics permitted the determination of the corresponding pseudo-first-order reaction constants (k). Trapping experiments performed under UV illumination revealed that the main active species for the photocatalytic reduction of Cr+6 ions are electrons, whereas in the case of methylene blue azo-dye (MB) oxidation, the activation of the corresponding photocatalytic degradation comes via both holes and superoxide radicals.

2020 ◽  
Vol 276 ◽  
pp. 128173 ◽  
Author(s):  
K. Bhuvaneswari ◽  
Ba-Son Nguyen ◽  
Van-Huy Nguyen ◽  
Vu-Quynh Nguyen ◽  
Quang-Hung Nguyen ◽  
...  

2019 ◽  
Vol 18 (6) ◽  
pp. 1503-1511 ◽  
Author(s):  
Prashant V. Pimpliskar ◽  
Shrinivas C. Motekar ◽  
Govind G. Umarji ◽  
Wonyoung Lee ◽  
Sudhir S. Arbuj

The photocatalytic activity of ZnO nanorods towards methylene blue dye degradation was enhanced by loading 0.5, 1, 5, and 10 mol% silver nanoparticles on the ZnO.


2022 ◽  
pp. 131637
Author(s):  
Devaraj Bharathi ◽  
Thiruvengadam Nandagopal Jaya Ganesh ◽  
Ranjithkumar Rajamani ◽  
Soumya Pandit ◽  
Deepak Kumar ◽  
...  

RSC Advances ◽  
2019 ◽  
Vol 9 (27) ◽  
pp. 15381-15391 ◽  
Author(s):  
Devina Rattan Paul ◽  
Rishabh Sharma ◽  
S. P. Nehra ◽  
Anshu Sharma

The appropriate synthesis temperature and optimized photodegradation reaction conditions result in an appreciable enhancement of the photocatalytic activity of urea derived innate g-C3N4 towards MB dye degradation.


2016 ◽  
Author(s):  
Deuk Yong Lee ◽  
Siwon Son ◽  
Min-Seok Jeon ◽  
Myung-Hyun Lee ◽  
Bae-Yeon Kim

2021 ◽  
Author(s):  
Alireza Esmaeilzadeh ◽  
Felora Heshmatpour

Abstract In this study, Sr-Ce-TiO2/HAp as a novel and efficient nanocomposite was synthesized and characterized by Fourier transform infrared spectroscopy (FTIR), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), scanning electron microscopy (SEM), and surface area determination of porous using the Brunauer–Emmett–Teller (BET) method and degradation of methylene blue under visible radiation was investigated. Evaluations showed that doped with metal cations and the presence of hydroxyapatite reduced energy gap, increased surface area, increased adsorption and decreased electron-hole recombination. The results also showed that more than 92% of methylene blue was removed within 100 min. The pseudo-first order reaction synthetic was obtained.


2019 ◽  
Vol 233 (8) ◽  
pp. 1161-1181 ◽  
Author(s):  
Shifa Wang ◽  
Huajing Gao ◽  
Leiming Fang ◽  
Yong Wei ◽  
Yanwu Li ◽  
...  

Abstract Hexagonal BaAl2O4 catalyst has been prepared using a gamma-ray irradiation assisted polyacrylamide gel method. The catalysts synthesized at different calcining temperatures were analyzed to insight into their effects on the structural, crystalline, surface morphology, color, optical, fluorescence and photocatalytic properties of the hexagonal BaAl2O4 catalyst. Increasing the calcining temperature has obvious influences on the crystallinity, color, optical properties and the formation of the hexagonal BaAl2O4 catalyst. The optical energy gap (Eg) value of the hexagonal BaAl2O4 catalyst increases with the increasing of calcining temperature. TEM image of the pure hexagonal BaAl2O4 catalyst shows a morphology of flake structure and aggregation. Raman spectroscopy of the pure hexagonal BaAl2O4 catalyst exhibits four luminescent background peaks at 400, 415, 428 and 445 nm mainly due to the oxygen vacancies (VO), Ba vacancies (VBa) and some color centers exists in the BaAl2O4 sample. A comparison of photocatalytic activity among samples for degradation of methylene blue (MB) dye indicates that the pure hexagonal BaAl2O4 catalyst exhibits highest photocatalytic activity under the irradiation of both visible and ultraviolet light. Based on the fluorescence experiment, electrochemical and active species tests, the high photocatalytic activity of the pure hexagonal BaAl2O4 catalyst to be related to hole (h+) and hydroxyl radical (⋅OH) and also to the defects in the sample.


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