A variational procedure is developed for estimating the effective constitutive behaviour of polycrystalline materials undergoing high-temperature creep. The procedure is based on a new variational principle allowing the determination of the effective potential function of a given nonlinear polycrystal in terms of the corresponding potential for a linear comparison polycrystal with an identical geometric arrangements of its constituent single-crystal grains. As such, it constitutes an extension, to locally anisotropic behaviour, of the variational procedure developed by Ponte Castañeda (1991) for nonlinear heterogeneous media with locally isotropic behaviour. By way of an example, the procedure is applied to the determination of bounds of the Hashin-Shtrikman type for the effective potentials of statistically isotropic nonlinear polycrystals. The bounds are computed for the special class of untextured FCC polycrystals with isotropic pure power-law viscous behaviour, first considered by Hutchinson (1976), in the context of a calculation of the self-consistent type. The new bounds are found to be more restrictive than the corresponding classical Taylor-Bishop-Hill bounds, and also more restrictive, if only slightly so, than related bounds of the Hashin-Shtrikman type by Dendievel
et al
. (1991). The new procedure has the advantage over the self-consistent procedure of Hutchinson (1976) that it may be applied, without any essential complications, to aggregates of crystals with slip systems exhibiting different creep rules - with, for example, different power exponents - and to general loading conditions. However, the distinctive feature of the new variational procedure is that it may be used in conjunction with other types of known bounds and estimates for linear polycrystals to generate corresponding bounds and estimates for nonlinear polycrystals.
