THERMAL SHOCK RESISTANCE OF La2(Zr0.7Ce0.3)2O7 THERMAL BARRIER COATING PREPARED BY ATMOSPHERIC PLASMA SPRAYING

2012 ◽  
Vol 48 (8) ◽  
pp. 965 ◽  
Author(s):  
Jianying XIANG ◽  
Shuhai CHEN ◽  
Jihua HUANG ◽  
Xingke ZHAO ◽  
Hua ZHANG
Coatings ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1186
Author(s):  
Lihua Gao ◽  
Fang Jia ◽  
Xiaoliang Lu

As one of the promising thermal barrier coating (TBC) candidates, stoichiometric (La0.8Gd0.2)2Ce2O7 (LGC) coatings were prepared by atmospheric plasma spraying (APS), using (La0.8Gd0.2)2Ce2.5O8 as a spray powder and optimized spray parameters. It was found that spray distance and spray power both play an important role in the phase composition and microstructure of the coating. The LGC coating exhibited lower thermal conductivities than that of La2Ce2O7 (LC) coating, which is ~0.67 W/m·K at 1200 °C. Double-ceramic-layer (DCL) optimum (La0.8Gd0.2)2Ce2O7/YSZ (LGC/YSZ) thermal barrier coating was prepared and its thermal shock behavior was investigated. The LGC/YSZ DCL TBCs had better thermal shock resistance ability than that of LC/YSZ TBCs, which was around 109 cycles at 1100 °C. However, the failure mode was similar to that of LC/YSZ DCL TBCs, which was still layer-by-layer spallation in the top ceramic layer due to the sintering of the ceramic coating.


2019 ◽  
Vol 14 (11) ◽  
pp. 1597-1605
Author(s):  
Yang Lyu ◽  
Xuan Shao ◽  
Wen-Xue Wang ◽  
Hui Tang

In this paper, nano-CeO2–Y2O3 co-stabilized ZrO2 ceramic powders (CYSZ) were firstly prepared by co-precipitation method, and CYSZ powder was spray-granulated, followed by thermal plasma spraying of nano-CYSZ thermal barrier coating on 35Cr2Ni4 MoA alloy matrix. After XRD and SEM analysis, the five CYSZ ceramic coatings (CeO2 content 0, 1, 5, 10, 15 mol%) prepared were tetragonal phase structures before and after the thermal shock experiment, and the thickness of CYSZ ceramic coating was about 200 μm. Adding appropriate amount of nano CeO2 promoted the formation of micro-cracks in the coating, released the coating stress, slowed down the thermal shock damage process, and prevented the transformation from t-ZrO2 to m-ZrO2. The AFM morphology showed that the coating surface grains grow vertically after thermal shock cycle, which indicated that the entry of Ce4+ into ZrO2 lattice resulted in lattice distortion and made the grains more stable. When the content of CeO2 is 1 mol%, the thermal shock resistance excellent is 84 times. Therefore, the addition of CeO2 can effectively improve the thermal shock resistance performance of CYSZ thermal barrier coating, meeting the requirements of high temperature working conditions of aeroengine and hot-end components.


Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3865
Author(s):  
Muhammed Anaz Khan ◽  
Annakodi Vivek Anand ◽  
Muthukannan Duraiselvam ◽  
Koppula Srinivas Rao ◽  
Ramachandra Arvind Singh ◽  
...  

In this work, functionally graded lanthanum magnesium hexaluminate (LaMgAl11O19)/yttria-stabilised zirconia (YSZ) thermal barrier coating (FG-TBC), in as-sprayed and laser-glazed conditions, were investigated for their thermal shock resistance and thermal insulation properties. Results were compared with those of a dual-layered coating of LaMgAl11O19 and YSZ (DC-TBC). Thermal shock tests at 1100 °C revealed that the as-sprayed FG-TBC had improved thermal stability, i.e., higher cycle lifetime than the as-sprayed DC-TBC due to its gradient architecture, which minimised stress concentration across its thickness. In contrast, DC-TBC spalled at the interface due to the difference in the coefficient of thermal expansion between the LaMgAl11O19 and YSZ layers. Laser glazing improved cycle lifetimes of both the types of coatings. Microstructural changes, mainly the formation of segmentation cracks in the laser-glazed surfaces, provided strain tolerance during thermal cycles. Infrared rapid heating of the coatings up to 1000 °C showed that the laser-glazed FG-TBC had better thermal insulation capability, as interlamellar pores entrapped gas and constrained heat transfer across its thickness. From the investigation, it is inferred that (i) FG-TBC has better thermal shock resistance and thermal insulation capability than DC-TBC and (ii) laser glazing can significantly enhance the overall thermal performance of the coatings. Laser-glazed FG-TBC provides the best heat management, and has good potential for applications that require effective heat management, such as in gas turbines.


Sign in / Sign up

Export Citation Format

Share Document