scholarly journals Aerobic synthesis of N-sulfonylamidines mediated by N-heterocyclic carbene copper(I) catalysts

2020 ◽  
Vol 16 ◽  
pp. 482-491
Author(s):  
Faïma Lazreg ◽  
Marie Vasseur ◽  
Alexandra M Z Slawin ◽  
Catherine S J Cazin

A new catalytic strategy for the one-pot synthesis of N-sulfonylamidines is described. The cationic copper(I) complexes were found to be highly active and efficient under mild conditions in air and in the absence of solvent. A copper acetylide is proposed as key intermediate in this transformation.

2018 ◽  
Vol 2018 (13) ◽  
pp. 1581-1588 ◽  
Author(s):  
Xue-Ting Bai ◽  
Qian-Qian Zhang ◽  
Shuai Zhang ◽  
Dan-Yun Chen ◽  
Ji-Ya Fu ◽  
...  

Synlett ◽  
2017 ◽  
Vol 29 (04) ◽  
pp. 477-482 ◽  
Author(s):  
Dibakar Deka ◽  
Subarna Kalita

A metal- and catalyst-free reductive alkylation protocol for the one-pot synthesis of 5-monoalkylbarbiturates from barbituric acids and aldehydes using the in situ generated chemoselective reducing agent 2-phenyl-2,3-dihydrobenzo[d]thiazole from 2-aminothiophenol and benzaldehyde is described. The notable advantages of the protocol are operational simplicity, mild reaction conditions, high yield, short reaction time, and simple workup and purification process which make it highly attractive.


2016 ◽  
Vol 6 (14) ◽  
pp. 5473-5482 ◽  
Author(s):  
Meenakshisundaram Sankar ◽  
Qian He ◽  
Simon Dawson ◽  
Ewa Nowicka ◽  
Li Lu ◽  
...  

All-in-one: supported nanoalloys as efficient heterogeneous catalysts for the one-pot synthesis of imines and secondary amines directly from nitrobenzene and benzylic alcohols using a hydrogen auto transfer strategy.


Synthesis ◽  
2017 ◽  
Vol 49 (23) ◽  
pp. 5143-5148 ◽  
Author(s):  
Ramesh Katla ◽  
Rakhi Chowrasia ◽  
Caren da Silva ◽  
Aline de Oliveira ◽  
Beatriz dos Santos ◽  
...  

[Ce(l-Pro)2]2 (Oxa) was used as a recyclable heterogeneous catalyst under mild conditions for the preparation of 2-aryl-2,3-dihydroquinazolin-4(1H)-one derivatives. The one-pot protocol proceeds in ethanol using anthranilamide with several aldehydes at 50–55 °C. The catalyst can be recycled and reused three cycles without significant loss of catalytic activity.


2008 ◽  
pp. 2677 ◽  
Author(s):  
Hongyang Liu ◽  
Ding Ma ◽  
Ross A. Blackley ◽  
Wuzong Zhou ◽  
Xinhe Bao

Sign in / Sign up

Export Citation Format

Share Document