Benzothiazolium salts as reagents for the deoxygenative perfluoroalkylthiolation of alcohols
A series of 2-(perfluoroalkylthio)benzothiazolium (BT-SRF) salts have been synthesized that serve as convenient sources of hitherto underexplored perfluoroalkylthiolate anions. An investigation of their reactivity in a deoxygenative nucleophilic substitution reaction led to the development of an unprecedented process that provides pentafluoroethyl and heptafluoropropyl thioethers directly from readily available alcohols.
1993 ◽
Vol 115
(13)
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pp. 5879-5880
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2013 ◽
Vol 448
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pp. 74-80
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2014 ◽
Vol 79
(23)
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pp. 11744-11749
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1970 ◽
pp. 738
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2006 ◽
Vol 20
(14)
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pp. 2209-2214
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