scholarly journals The Effects of Nanosized-Palm Oil Fuel Ash on Early Age Hydration of Hardened Cement Paste: The Microstructure Studies

Author(s):  
Mohd Azrul Andul Rajak ◽  
Zaiton Abdul Majid ◽  
Mohammad Ismail

Integration of cement-based products with nanosized-palm oil fuel ash as supplementary cementing material (SCM) amend its hydration’s degree at early age phase and the microstructural groundworks are relevant to explain the findings. Hence, the present work investigates the microstructure properties of the hardened cement paste (HCP) incorporating nPOFA to study on the effect of nPOFA in cement hydration at an early age phase. An Ordinary Portland Cement (OPC) paste as a set of HCP blended with microsized-palm oil fuel ash (mPOFA) (10-30%) and nPOFA (10-60%) were prepared and cured for 28 days. The microstructural examination of OPC, mPOFA and nPOFA cement pastes at 28 days curing age via Thermogravimetric (TG) analysis, X-Ray diffraction (XRD) analysis, morphology study and Fourier transform infrared (FTIR) spectroscopy analysis. In TG analysis, the relative weight loss of calcium hydroxide (CH) of nPOFA pastes is lower than OPC and mPOFA. Based on the CH peaks at 2?= 18.1°and 34.0° in the diffractogram, it shows that nPOFA pastes give the low CH peaks compare to OPC and mPOFA pastes. In addition, the nPOFA pastes form the dense and compact microstructure of HCP compare to other pastes. Observations from FTIR analysis, nPOFA pastes display a high frequency of Si-O band due to the high rate of pozzolanic reaction. Overall, the findings confirmed the contribution of nPOFA in accelerating the rate of cement hydration and pozzolanic reaction as it reduced the amount of CH in the cementitious matrix.

2011 ◽  
Vol 25 (11) ◽  
pp. 4287-4293 ◽  
Author(s):  
Chai Jaturapitakkul ◽  
Jatuphon Tangpagasit ◽  
Sawang Songmue ◽  
Kraiwood Kiattikomol

2020 ◽  
Vol 17 (2) ◽  
pp. 1032-1036
Author(s):  
Nur Nadhira Abdul Rasid ◽  
Abdul Rahman Mohd. Sam ◽  
Azman Mohamed ◽  
Nor Hasanah Abdul Shukor Lim ◽  
Zaiton Abdul Majid ◽  
...  

Blended concrete has later strength development with long maturity strength development. An accelerator is thus needed to enhance the early strength development of concrete. This paper shows the combination of ground palm oil fuel ash and eggshell powder that was designed for later and early strength development, respectively. Two types of eggshell powder were utilised in concrete: uncarbonised eggshell powder and decarbonised eggshell powder. The study was initiated with compression test for concrete curing at age 1, 3, 7, and 28 days followed by rapid evaluation test of setting time to investigate the preliminary performance between materials. The results revealed decarbonised eggshell powder as a high accelerator that can improve the early age of concrete strength development. Meanwhile, despite showing the best performance, uncarbonised eggshell powder is a very low accelerator thus not fit the purpose. In conclusion, the combination of ground palm oil fuel ash (rich with silica oxide) and decarbonised eggshell powder (rich with calcium oxide) provided dual function, where ground palm oil fuel ash and decarbonised eggshell powder took later and early strength development, respectively. The combination between silica oxide and calcium oxide in cementitious materials has potential to be utilised to enhance the early age of a blended concrete strength development.


2018 ◽  
Vol 7 (5) ◽  
pp. 271-295 ◽  
Author(s):  
Ali Mohamed Ali Aboshia ◽  
Riza Atiq Rahmat ◽  
Muhammad Fauzi Mohd Zain ◽  
Amiruddin Ismail

2021 ◽  
Vol 1200 (1) ◽  
pp. 012001
Author(s):  
A S Nurfarhanna ◽  
A Suraya Hani ◽  
O Mohamad Hairi ◽  
J Zalipah ◽  
AH Noor Azlina ◽  
...  

Abstract Railway’s concrete sleepers demand high consumption of cement which generates higher energy assumption and carbon emission. Meanwhile, in Malaysia, around 100 tonnes of palm oil fuel ash (POFA) were disposed of in the landfill, which endangering environmental health. However, this POFA have pozzolanic properties that can be employed as cementitious material. Therefore, this study aimed to produce a sustainable concrete sleeper by using POFA as a cement replacement material focusing on the compressive strength and water absorption performance. Concrete samples with a strength grade of 55MPa and w/c of 0.35 were prepared with three design mixes containing 0% (control), 20%(POFA20), and 40%(POFA40) of POFA. For the compressive strength test, a compression machine was used. Meanwhile, the water absorption was measured at atmospheric pressure. Both tests were conducted at 7 and 28 days of curing age. The results show that as the curing age increases, their water absorption and compressive strength improves, indicating a pozzolanic reaction. In terms of POFA content, the water absorption increases by 14% and 54% for POFA20 and POFA40, respectively. Meanwhile, the compressive strength reduced by 39% for POFA20 and 67% for POFA40. Since POFA20 meets the standards, it is however applicable in slab tracks.


2018 ◽  
Vol 9 (3) ◽  
pp. 71
Author(s):  
Khairunisa Muthusamy ◽  
Muhammad Azreen Ibrahim ◽  
Nor Hazurina Othman ◽  
Ahmed Mokhtar Albshir Budiea ◽  
Saffuan Wan Ahmad

The prosperous palm oil industry continues to generate increasing amount of palm oil fuel ash which disposed as environmental polluting waste. Thus, research was conducted to investigate the effect of ground palm oil fuel ash as partial fine aggregate replacement towards properties of sand cement brick. Series of mixes were prepared with 0%, 5%, 10%, 15%, 20% and 25% ground palm oil fuel ash partially substituting the river sand. Two types of curing methods were applied namely water and air curing. The bricks were subjected to compressive strength, flexural strength and water absorption test at 28 days. The results show that utilization of 15% ground palm oil fuel ash as fine aggregate replacement increases the brick strength. The pozzolanic reaction and filler effect of the finely ground ash makes the concrete internal structure denser resulting in strength enhancement. The use of ground palm oil fuel ash in brick production would reduce amount of palm oil waste disposed, save the use of land for dumping purpose and decrease quantity of river sand mined.


2011 ◽  
Vol 25 (11) ◽  
pp. 4095-4104 ◽  
Author(s):  
Wunchock Kroehong ◽  
Theerawat Sinsiri ◽  
Chai Jaturapitakkul ◽  
Prinya Chindaprasirt

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