Low-Frequency Dielectric Dispersion and Impedance Spectroscopy of lead-free (Na$_{0.5}$Bi$_{0.5}$)TiO$_3$(NBT) Ferroelectric Ceramics

2009 ◽  
Vol 55 (2(1)) ◽  
pp. 879-883 ◽  
Author(s):  
Jin Soo Kim ◽  
Byung Chun Choi ◽  
Jung Hyun Jeong ◽  
Su Tae Chung ◽  
Sang-Bock Cho ◽  
...  
Keyword(s):  
Impedance Spectroscopy ◽  
Low Frequency ◽  
Dielectric Dispersion ◽  
Lead Free ◽  
Ferroelectric Ceramics

A study of low frequency dielectric dispersion of lead-free 0.94(Na0.50Bi0.50)Ti0.95V0.05O3-0.06BaTiO3 ceramics

2019 ◽  
Author(s):  
Anita Verma ◽  
Arun Kumar Yadav ◽  
Nasima Khatun ◽  
Sunil Kumar ◽  
Somaditya Sen
Keyword(s):  
Low Frequency ◽  
Dielectric Dispersion ◽  
Lead Free

DIELECTRIC RESPONSE AND IMPEDANCE SPECTROSCOPY OF (Na0.5Bi0.5)0.95Ba0.05Zr0.04Ti0.96O3 FERROELECTRIC CERAMIC

2012 ◽  
Vol 02 (03) ◽  
pp. 1250019
Author(s):  
B. TILAK
Keyword(s):  
Transition Temperature ◽  
Impedance Spectroscopy ◽  
Dielectric Response ◽  
Ferroelectric Ceramic ◽  
Lead Free ◽  
Ferroelectric Ceramics ◽  
Dielectric Susceptibility ◽  
Relaxation Processes ◽  
Average Grain Size ◽  
Wide Range

A new lead-free ferroelectric relaxor ceramic was prepared by conventional solid-state synthesis by modifying A-site and B-site in (Na0.5Bi0.5)TiO3 system, i.e., (Na0.5Bi0.5)0.95Ba0.05Zr0.04Ti0.96O3 (0.05BNBZT). X-ray diffraction studies reveal a single phase rhombohedral structure. Crystallite size and strain analysis has been done by Debye–Scherrer and Williamson–Hall technique. The tolerance factor is 0.81, indicating a stable Perovskite structure of the material. Scanning electron micrograph of the material shows a distribution of grains, average grain size is 1.41 μm. Dielectric response of (Na0.5Bi0.5)0.95Ba0.05 Zr0.04Ti0.96O3 , ferroelectric ceramic has been studied as a function of frequency over a wide range of temperatures. The studied ceramic exhibited maximum frequency dispersion in both real and imaginary part of dielectric susceptibility at and around the dielectric transition temperature (Tm). The frequency dependence of transition temperature, Tm (temperature of the maximum of dielectric constant) was studied in terms of Vogel–Fulcher relation. The dielectric relaxation of (Na0.5Bi0.5)0.95Ba0.05Zr0.04Ti0.96O3 ceramic was studied at different temperatures using the complex impedance (Z*) and electrical modulus (M*) formalism. Impedance measurements were made on over a wide range of temperatures (300–600°C) and frequencies (45 Hz–5 MHz) which show the presence of both grain and grain boundary effects in the material. The Impedance spectroscopy is shown to be an efficient method capable of detecting the contributions of the resistances of grain boundaries (at higher temperature), in addition to granular contribution (at all temperatures), which influences the device properties of a material. The electric modulus (M*) formalism used in the analysis enabled us to distinguish and separate the relaxation processes. Conductivity studies in the material obey the Jonscher's power law in frequency (45 Hz–5 MHz) and temperature (30–600°C). These results give evidence that the lead-free ferroelectric ceramics is extensively may be used for device and electronic applications, when compared with lead-based materials.

Influence of Nb2O5 doping to energy-storage properties of (Na0.5Bi0.5)0.705Ba0.045Sr0.25TiO3 lead-free ferroelectric ceramics

2021 ◽  
Vol 573 (1) ◽  
pp. 246-255
Author(s):  
Ruifang Wu ◽  
Linlin Liang ◽  
Ruijie Duan ◽  
Jinghao Zhao ◽  
Zekai Li ◽  
...  
Keyword(s):  
Energy Storage ◽  
Lead Free ◽  
Ferroelectric Ceramics ◽  
Energy Storage Properties ◽  
Storage Properties

MnO2-modified Lead-free NBT-based Relaxor Ferroelectric Ceramics with Improved Energy Storage Performances

2021 ◽  
Author(s):  
Ziqiong Ling ◽  
Jie Ding ◽  
Weijun Miao ◽  
Jinjun Liu ◽  
Jinghao Zhao ◽  
...  
Keyword(s):  
Energy Storage ◽  
Relaxor Ferroelectric ◽  
Lead Free ◽  
Ferroelectric Ceramics ◽  
Relaxor Ferroelectric Ceramics

scholarly journals Switching characteristics of MPB compositions of (Bi0.5Na0.5)TiO3–BaTiO3–(Bi0.5K0.5)TiO3 lead-free ferroelectric ceramics

2007 ◽  
Vol 55 (9) ◽  
pp. 3081-3087 ◽  
Author(s):  
J. Shieh ◽  
K.C. Wu ◽  
C.S. Chen
Keyword(s):  
Lead Free ◽  
Ferroelectric Ceramics ◽  
Switching Characteristics

scholarly journals Study of Influence of Electrode Geometry on Impedance Spectroscopy

2010 ◽  
Author(s):  
Riaz Ahmed ◽  
Kenneth Reifsnider
Keyword(s):  
Impedance Spectroscopy ◽  
High Frequency ◽  
Low Frequency ◽  
Effective Area ◽  
Ac Impedance ◽  
Local Geometry ◽  
Electrode Geometry ◽  
Electrode Area ◽  
Impedance Response ◽  
Working Electrode

Electrochemical Impedance Spectroscopy (EIS) is a powerful and proven tool for analyzing AC impedance response. A conventional three electrode EIS method was used to perform the investigation in the present study. Saturated potassium chloride solution was used as the electrolyte and three different material rods were used as working electrodes. Different configurations of electrode area were exposed to the electrolyte as an active area to investigate electrode geometry effects. Counter to working electrode distance was also altered while keeping the working electrode effective area constant to explore the AC response dependence on the variation of ion travel distance. Some controlled experiments were done to validate the experimental setup and to provide a control condition for comparison with experimental results. A frequency range of 100 mHz to 1 MHz was used for all experiments. In our analysis, we have found a noteworthy influence of electrode geometry on AC impedance response. For all electrodes, impedance decreases with the increase of effective area of the electrolyte. High frequency impedance is not as dependent on geometry as low frequency response. The observed phase shift angle drops in the high frequency region with increased working electrode area, whereas at low frequency the reverse is true. Resistance and capacitive reactance both decrease with an increase of area, but resistance response is more pronounce than reactance. For lower frequencies, small changes in working area produce very distinctive EIS variations. Electrode material as well as geometry was systematically varied in the present study. From these and other studies, we hope to develop a fundamental foundation for understanding specific changes in local geometry in fuel cell (and other) electrodes as a method of designing local morphology for specific performance.

Sign in / Sign up

Export Citation Format

Share Document