A Novel Nickel/Iron-Layered Double Hydroxide for Supercapacitors

2014 ◽  
Vol 665 ◽  
pp. 115-118 ◽  
Author(s):  
Zhe Kang ◽  
Ting Xiao ◽  
Xin Yu Tan ◽  
Peng Xiang ◽  
Li Hua Jiang

A facile one-step method of growing nickel/iron layered double hydroxide (Ni/Fe-LDH) films with nanosheet structures on Ti sheet is presented and the electrochemical performance is investigated. Cyclic voltammogram of Ni/Fe-LDH electrode shows a pair of well-defined redox peaks at-0.4~-1.4 V, which is quite different with the previous reports on LDHs used for supercapacitors. This result implies the Ni/Fe-LDH may be an alternative for the cathode of the asymmetric supercapacitors.

CrystEngComm ◽  
2018 ◽  
Vol 20 (46) ◽  
pp. 7428-7434 ◽  
Author(s):  
Chuan Jing ◽  
Xiaoli Liu ◽  
Xiaoying Liu ◽  
Debin Jiang ◽  
Biqin Dong ◽  
...  

Hierarchical three-dimensional (3D) porous structures of nickel–cobalt layered double hydroxide (LDH) are grown on diatomite biotemplate via one-step hydrothermal method.


RSC Advances ◽  
2015 ◽  
Vol 5 (66) ◽  
pp. 53726-53735 ◽  
Author(s):  
M. Hajibeygi ◽  
M. Shabanian ◽  
H. Moghanian ◽  
H. A. Khonakdar ◽  
L. Häußler

New exfoliated poly(amide–imide)/Zn–Al layered double hydroxide (LDH) nanocomposites were synthesized by solution intercalation using synthesized organo-modified LDH (OLDH) as nanofiller obtained by one-step method.


2022 ◽  
Author(s):  
Wenke Shao ◽  
Qiufan Wang ◽  
Can Huang ◽  
Daohong Zhang

Delicate design of nanostructures consisting of multiple components is an important strategy for energy storage materials. In this work, cobalt-doped nickel-iron layered double hydroxide (Fe-Ni3Co2 LDH) assembling from one-dimensional (1D)...


2021 ◽  
Author(s):  
Zihao Liu ◽  
Shifeng Li ◽  
Fangfang Wang ◽  
Mingxia Li ◽  
Yonghong Ni

FeNi-layered double hydroxide (LDH) is thought to be an excellent electrocatalyst for oxygen evolution reaction (OER), but it always shows extremely poor electrocatalytic activity toward hydrogen evolution reaction (HER) in...


ChemInform ◽  
2004 ◽  
Vol 35 (51) ◽  
Author(s):  
Alexey V. Lukashin ◽  
Andrei A. Eliseev ◽  
Natalya G. Zhuravleva ◽  
Alexey A. Vertegel ◽  
Yuri D. Tretyakov ◽  
...  

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Panlong Zhai ◽  
Mingyue Xia ◽  
Yunzhen Wu ◽  
Guanghui Zhang ◽  
Junfeng Gao ◽  
...  

AbstractRational design of single atom catalyst is critical for efficient sustainable energy conversion. However, the atomic-level control of active sites is essential for electrocatalytic materials in alkaline electrolyte. Moreover, well-defined surface structures lead to in-depth understanding of catalytic mechanisms. Herein, we report a single-atomic-site ruthenium stabilized on defective nickel-iron layered double hydroxide nanosheets (Ru1/D-NiFe LDH). Under precise regulation of local coordination environments of catalytically active sites and the existence of the defects, Ru1/D-NiFe LDH delivers an ultralow overpotential of 18 mV at 10 mA cm−2 for hydrogen evolution reaction, surpassing the commercial Pt/C catalyst. Density functional theory calculations reveal that Ru1/D-NiFe LDH optimizes the adsorption energies of intermediates for hydrogen evolution reaction and promotes the O–O coupling at a Ru–O active site for oxygen evolution reaction. The Ru1/D-NiFe LDH as an ideal model reveals superior water splitting performance with potential for the development of promising water-alkali electrocatalysts.


2015 ◽  
Vol 3 (31) ◽  
pp. 16348-16353 ◽  
Author(s):  
Na Han ◽  
Feipeng Zhao ◽  
Yanguang Li

Incorporation of molybdate ions into a NiFe-LDH structure leads to the formation of ultrathin nanosheets with enhanced OER performance.


2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
D. Scarpellini ◽  
C. Leonardi ◽  
A. Mattoccia ◽  
L. Di Giamberardino ◽  
P. G. Medaglia ◽  
...  

We have grown nanostructured films of Zn/Al Layered Double Hydroxide (LDH) on different substrates by combining the deposition of an aluminum micropatterned thin layer with a successive one-step room-temperature wet-chemistry process. The resulting LDH film is made of lamellar-like nanoplatelets mainly oriented perpendicular to the substrate. Since the aluminum layer acts as both reactant and seed for the synthesis of the LDH, the growth can be easily confined with submicrometric-level resolution (about ±0.5 μm) by prepatterning the aluminum layer with conventional photolithographic techniques. Moreover, we demonstrate real-time monitoring of the LDH growth process by simply measuring the resistance of the residual aluminum film. If the aluminum layer is thinner than 250 nm, the morphology of LDH nanoplatelets is less regular and their final thickness linearly depends on the initial amount of aluminum. This peculiarity allows accurately controlling the LDH nanoplatelet thickness (with uncertainty of about ±10%) by varying the thickness of the predeposited aluminum film. Since the proposed growth procedure is fully compatible with MEMS/CMOS technology, our results may be useful for the fabrication of micro-/nanodevices.


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