The Synthesis and Ion-Exchange Property of Inorganic Material Mg2Mn0.5Ti0.5O4

2012 ◽  
Vol 511 ◽  
pp. 109-112
Author(s):  
Jin He Jiang

Magnesium-manganese-titanium oxide (Mg2Mn0.5Ti0.5O4) was prepared by a coprecipitation/thermal crystallization method. The results showed that the Li+ extraction/insertion be progressed mainly by an ion-exchange mechanism. The acid treatments of Mg2Mn0.5Ti0.5O4 caused Mg2+ extractions of more than 73%, while the dissolutions of Mn4+ and Ti4+ were less than 13%. The experimental results have proved that the acid-treated sample has a capacity of exchange 12.6mmol•g-1 for Li+ in the solution.

2012 ◽  
Vol 511 ◽  
pp. 105-108
Author(s):  
Jin He Jiang

Mg1.5Mn0.5Ti0.75O4 was prepared by a coprecipitation/thermal crystallization method. The extraction/insertion reaction with this material was investigation by X-ray, saturation capacity of exchange, and Kd measurement. The acid treatments of Mg1.5Mn0.5Ti0.75O4 caused Mg2+ extractions of more than 72%, while the dissolutions of Mn4+ and Ti4+ were less than 8.2%. The results showed that the Li+ extraction/insertion be progressed mainly by an ion-exchange mechanism. The acid treated samples had an ion exchange capacity of 10.6mmol/g for Li+.


2012 ◽  
Vol 424-425 ◽  
pp. 789-792
Author(s):  
Heng Li

Compound [LiZnPO4], a spinel-type metal compound, was prepared by a solid state reaction crystallization method. The experimental results showed that the Li+extraction/insertion be progressed mainly by an ion-exchange mechanism. The acid treated samples had an ion exchange capacity of 4.1 mmol/g for Li+.


2012 ◽  
Vol 511 ◽  
pp. 113-116
Author(s):  
Jin He Jiang

The MgMn0.25Ti0.75O3 was synthesized by a coprecipitation/thermal crystallization method. The extraction/insertion reaction with this material was investigation by X-ray, saturation capacity of exchange, and Kd measurement. The acid treatments of MgMn0.25Ti0.75O3 caused Mg2+ extractions of more than 74%, while the dissolutions of Mn4+ and Ti4+ were less than 8.2%. The experimental results have proved that the acid-treated sample has a capacity of exchange 9.5mmol•g-1 for Li+ in the solution.


2012 ◽  
Vol 457-458 ◽  
pp. 26-29
Author(s):  
Heng Li

Lithium-titanium oxide(Li2.5Ti1.375O4) was prepared by a solid state reaction crystallization method. The results showed that the Li+ extraction/insertion be progressed mainly by an ion-exchange mechanism. The acid treated samples had an ion exchange capacity of 8.1mmol/g for Li+.


2012 ◽  
Vol 485 ◽  
pp. 457-460
Author(s):  
Heng Li

Spinel-type metal oxides, magnesium-manganese- titanium oxide (MgMn0.25Ti0.75O3), was prepared by a coprecipitation/thermal crystallization method. The extraction/insertion reaction with this material was investigation by X-ray, saturation capacity of exchange, and Kd measurement. The acid treatments of MgMn0.25Ti0.75O3 caused Mg2+ extractions of more than 81%, while the dissolutions of Mn4+ and Ti4+ were less than 15%. The experimental results have proved that the acid-treated sample has a capacity of exchange 7.1mmol•g-1 for Li+ in the solution.


2012 ◽  
Vol 549 ◽  
pp. 466-469 ◽  
Author(s):  
Jin He Jiang

LiMn0.25TiO3was prepared by a solid state reaction crystallization method. The results showed that the Li+ extraction/insertion be progressed mainly by an ion-exchange mechanism. The acid treated samples had an ion exchange capacity of in 0.1mol /L HNO3 solution is 4.3mmol/g for Li+. It had a memorial ion-sieve property for Li+.


2012 ◽  
Vol 457-458 ◽  
pp. 206-209
Author(s):  
Heng Li

Compound [Li1.4Zn0.8PO4], a spinel-type metal compound, was prepared by a solid state reaction crystallization method. The results showed that the Li+ extraction/insertion be progressed mainly by an ion-exchange mechanism. The acid treated samples had an ion exchange capacity of 6.2 mmol/g for Li+.


2013 ◽  
Vol 842 ◽  
pp. 255-258
Author(s):  
Jin He Jiang

LiMn0.75Ti0.5O3 was prepared by a solid state reaction crystallization method. The acid treatments of LiMn0.75Ti0.5O3 caused Li2+ extractions of more than 75%, while the dissolutions of Mn4+ and Ti4+ were less than 13%. The experimental results have proved that the acid-treated sample has a capacity of exchange 4.1mmol·g-1 for Li+ in the solution.


2012 ◽  
Vol 554-556 ◽  
pp. 860-863
Author(s):  
Jin He Jiang

Compound [Li2MnO3], a spinel-type metal compound, was prepared by a solid state reaction crystallization method. The results showed that the Li+ extraction/insertion be progressed mainly by an ion-exchange mechanism. Results of column test indicated, that the exchange capacity obtained from tests for Li+ in 0.1mol/L HNO3 solution is 7.0 mmol•g-1.It had a memorial ion-sieve property for Li+


2012 ◽  
Vol 430-432 ◽  
pp. 32-35
Author(s):  
Heng Li

Inverse spinel-type metal oxides, magnesium-manganese-titanium oxide(MgMn0.5Ti0.5O3), was prepared by a coprecipitation/thermal crystallization method. The extraction/insertion reaction with this material was investigation by X-ray, saturation capacity of exchange, and Kd measurement. The acid treatments of MgMn0.5Ti0.5O3 caused Mg2+ extractions of more than 82%, while the dissolutions of Mn4+ and Ti4+ were less than 15%.The experimental results have proved that the acid-treated sample has a capacity of exchange 7.6 mmol•g-1 for Li+ in the solution.


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