Study on the Photoelectric Properties of CdSe/MS Composite Film and its Potential Application in Biosensor Field

2012 ◽  
Vol 560-561 ◽  
pp. 688-693
Author(s):  
Ping Wang ◽  
Li Hua Cheng ◽  
Ru Jin Zhou
Keyword(s):  
Hydrogen Peroxide ◽  
Horseradish Peroxidase ◽  
Mesoporous Silica ◽  
Composite Film ◽  
Potential Application ◽  
Cdse Nanocrystals ◽  
Composite Particles ◽  
Response Signal ◽  
Uv Illumination ◽  
Photoelectric Properties

CdSe nanocrystals were prepared within a template of mesoporous silica (MS) spheres via chemical reaction. The photocurrent of CdSe/MS composite under UV illumination was distinctly higher than that in the dark. The horseradish peroxidase (HRP) was immobilized on the surface of the composite particles. The HRP/CdSe/MS composite film toward the reduction of hydrogen peroxide (H2O2) had stronger response signal under UV illumination than that in the dark. The electrons photo-generated from CdSe and the electrons provided by electrode can occur simultaneously to catalyze the reduction of H2O2. The holes photo-generated by CdSe are trapped at the interface between CdSe and pore walls of MS film. The results show that CdSe/MS composite film has good photoelectric properties and potential application on immobilization of horseradish peroxidase for hydrogen peroxide monitoring.

scholarly journals Monitoring the heme iron state in horseradish peroxidase to detect ultratrace amounts of hydrogen peroxide in alcohols

RSC Advances ◽  
2021 ◽  
Vol 11 (17) ◽  
pp. 9901-9910
Author(s):  
Raheleh Ravanfar ◽  
Alireza Abbaspourrad
Keyword(s):  
Hydrogen Peroxide ◽  
Horseradish Peroxidase ◽  
Oxidative Damage ◽  
Heme Iron ◽  
Aqueous Systems ◽  
Iron State ◽  
Low Concentrations

Despite the importance of hydrogen peroxide (H2O2) in initiating oxidative damage and its connection to various diseases, the detection of low concentrations of H2O2 (<10 μM) is still limited using current methods, particularly in non-aqueous systems.

scholarly journals The Reaction of Ferrous Horseradish Peroxidase with Hydrogen Peroxide

1970 ◽  
Vol 245 (9) ◽  
pp. 2409-2413
Author(s):  
Robert W. Noble ◽  
Quentin H. Gibson
Keyword(s):  
Hydrogen Peroxide ◽  
Horseradish Peroxidase

scholarly journals Fluorescent Derivatization of Aromatic Carboxylic Acids with Horseradish Peroxidase in the Presence of Excess Hydrogen Peroxide

2015 ◽  
Vol 31 (1) ◽  
pp. 37-44
Author(s):  
Junichi ODO ◽  
Masahiko INOGUCHI ◽  
Hiroyuki AOKI ◽  
Yuto SOGAWA ◽  
Masahiro NISHIMURA
Keyword(s):  
Hydrogen Peroxide ◽  
Horseradish Peroxidase ◽  
Carboxylic Acids ◽  
Aromatic Carboxylic Acids ◽  
Excess Hydrogen

scholarly journals Detection of a Tryptophan Radical as an Intermediate Species in the Reaction of Horseradish Peroxidase Mutant (Phe-221 → Trp) and Hydrogen Peroxide

1998 ◽  
Vol 273 (24) ◽  
pp. 14753-14760 ◽  
Author(s):  
Atsushi Morimoto ◽  
Motomasa Tanaka ◽  
Satoshi Takahashi ◽  
Koichiro Ishimori ◽  
Hiroshi Hori ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Horseradish Peroxidase ◽  
Intermediate Species
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