A Study of Molecular Interaction in Binary Mixtures of 1-Propanol with N,N-Dimethylformamide at Different Temperatures

2013 ◽  
Vol 665 ◽  
pp. 317-325 ◽  
Author(s):  
A.N. Prajapati ◽  
Vipinchandra A. Rana ◽  
A.D. Vyas ◽  
Deepak H. Gadani
Keyword(s):  
Dielectric Constant ◽  
Binary Mixtures ◽  
Molecular Species ◽  
Molecular Interaction ◽  
Optical Dielectric Constant ◽  
Different Temperatures ◽  
Optical Dielectric ◽  
Correlation Parameters ◽  
Lcr Meter ◽  
Bruggeman Parameter

The static dielectric constant (ε0) and optical dielectric constant (ε = n2) of binary mixtures of 1-Propanol (1-PrOH) with N,N-Dimethylformamide (DMF) of different concentrations, prepared by volume fractions (0.0, 0.1, . 1.0) are measured at 2 MHz using precision LCR meter and Abbes refractometer respectively at different temperatures. The excess dielectric constant (ε0)E, Kirkwood correlation parameters (geff, gF), Bruggeman parameter (fB) are evaluated. The variations of these parameters with concentration and temperature are discussed in terms of molecular interaction between the molecular species of constituting components in these mixtures.

Dielectric Studies of Binary Mixtures of 1-Propanol and Fluorobenzene

2013 ◽  
Vol 209 ◽  
pp. 203-206 ◽  
Author(s):  
Ashvin N. Prajapati ◽  
Vipinchandra A. Rana ◽  
A.D. Vyas ◽  
S.P. Bhatanagar ◽  
D.H. Gadani
Keyword(s):  
Dielectric Constant ◽  
Binary Mixtures ◽  
Complex Permittivity ◽  
High Frequency ◽  
Low Frequency ◽  
Microwave Frequency ◽  
Static Dielectric Constant ◽  
Frequency Range ◽  
Optical Dielectric Constant ◽  
Optical Dielectric

Complex permittivity spectra of 1-Propanol (1-PrOH), Fluorobenzene (FB) and their binary mixtures are obtained in radio and microwave frequency range using Vector network analyzer (VNA) operating in the frequency range 0.3 MHz to 3.0 GHz and standard microwave benches operated at 9.1 GHz and 19.61 GHz. Static dielectric constant (ε0) and high frequency limiting dielectric constant (ε∞1) for binary mixtures of 1-PrOH and FB are obtained by extrapolating the complex permittivity data towards low frequency side and high frequency side on complex plane plots. Optical dielectric constant (ε∞ = n2) for binary mixtures are measured using Abbe's refractometer. Excess static dielectric constant (ε0)E, Kirkwood correlation parameters (g, geff and gf) and Bruggeman factor (fB) are determined from the values of static dielectric constant (ε0) and optical dielectric constant (ε∞). These parameters have been discussed to explore the molecular interaction between the molecular species.

Energy gap and optical dielectric constant of Pb1−Cd Se films

1987 ◽  
Vol 27 (6) ◽  
pp. 389-397 ◽  
Author(s):  
M. Baleva ◽  
M. Maksimov ◽  
M. Sendova
Keyword(s):  
Dielectric Constant ◽  
Energy Gap ◽  
Optical Dielectric Constant ◽  
Optical Dielectric

Optical and dielectric properties of lead perovskite and iodoplumbate complexes: an ab initio study

2020 ◽  
Vol 22 (33) ◽  
pp. 18423-18434
Author(s):  
Malladi Srikanth ◽  
Mailde S. Ozório ◽  
Juarez L. F. Da Silva
Keyword(s):  
Density Functional Theory ◽  
Dielectric Constant ◽  
Dielectric Properties ◽  
Ab Initio ◽  
Density Functional ◽  
Ab Initio Study ◽  
Functional Theory ◽  
Optical Dielectric Constant ◽  
Energetic Stability ◽  
Optical Dielectric

Optical and dielectric properties, and energetic stability orders of black phase of perovskites and yellow phase of iodoplumbates have been studied using density functional theory; where the optical dielectric constant varies with the polymorphic phase and nature of cation.

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