Low Temperature Selective Catalytic Reduction of NO on CeO2-Fe3O4/TiO2,CeO2 /TiO2 Catalysts Prepared by Coprecipitation Method

2014 ◽  
Vol 960-961 ◽  
pp. 234-239 ◽  
Author(s):  
Wen Long Zhen ◽  
Rui Tang Guo ◽  
Wei Guo Pan

CeO2-Fe3O4/TiO2and CeO2/TiO2catalysts were prepared by coprecipitation method, and their activities for selective catalytic reduction of NO with NH3were investigated. As can be seen from the experimental results, the CeO2-Fe3O4/TiO2catalyst prepared showed the best SCR activity and SO2resistance. Based on the characterization results of BET, XRD, NH3-TPD and XPS the excellent performance of CeO2-Fe3O4/TiO2catalyst should be resulted from its large surface area, high NH3adsorption capacity and high concentration of surface chemisorbed oxygen.

2016 ◽  
Vol 697 ◽  
pp. 275-278 ◽  
Author(s):  
Yu Xin Deng ◽  
Xin Chen ◽  
Rong Shao ◽  
Li Ming Hu ◽  
Jie Tang ◽  
...  

A systematic investigation of the effect of WO3 loading over V2O5/TiO2 catalysts was carried out for the selective catalytic reduction of NO by NH3. The characteristics were examined use BET surface area , X-ray diffractometry (XRD) , Temperature programmed desorption (TPD) of NH3 . It was fund that the WO3 species could interact with the TiO2 anatase phase to exhibits a high activity. With increasing WO3 content ,the activity of V-W/TiO2 for the selective catalytic reduction of NO by NH3 was improved at low temperatures in the range of 3~7%. The results showed that the adding of WO3 to V2O5/TiO2 could result in exposing acid sites of catalysts doped WO3 at low temperature. Furthermore, especially the catalytic activity of VW7Ti showed higher than 80% at 180 °C. However, the catalytic BET surface area and the mass of acid sites not play a leading role for improving low-temperature activity of VWTi in this paper.


2013 ◽  
Vol 864-867 ◽  
pp. 353-356 ◽  
Author(s):  
Ye Jiang ◽  
Yan Yan ◽  
Shan Bo Huang ◽  
Xiu Xia Zhang ◽  
Xin Wei Wang ◽  
...  

A Ce-Zr-Ti composite oxide catalyst was prepared by the sol-gel method and its NH3-SCR activities were investigated. The Ce-Zr-Ti oxide catalyst exhibited high activity and 92.7-98.8% NO conversion was obtained in the temperature range 250-450 °C at the high gas hourly space velocity of 50,000 h-1. In comparison with Ce-Ti oxide catalyst, the Ce-Zr-Ti oxide catalyst showed strong resistance to H2O and SO2. The excellent performance of the Ce-Zr-Ti oxide catalyst might be attributed to the large surface area and strong interaction among the three elements of Ce, Zr and Ti.


2012 ◽  
Vol 27 (5) ◽  
pp. 495-500 ◽  
Author(s):  
Da-Wang WU ◽  
Qiu-Lin ZHANG ◽  
Tao LIN ◽  
Mao-Chu GONG ◽  
Yao-Qiang CHEN

2022 ◽  
Author(s):  
Zhitao Han ◽  
Huan Du ◽  
Duo Xu ◽  
Yu Gao ◽  
Shaolong Yang ◽  
...  

FeMn/SnxTiO2 catalysts were synthesized by introducing Sn as an additive to modify TiO2 supports, and the Sn doping could improve the SO2 tolerance and low-temperature SCR activity significantly.


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