Synthesis of Gadolinium Zirconate by Coprecipitaiton and Its Properties for TBC Application

2007 ◽  
Vol 280-283 ◽  
pp. 1501-1502 ◽  
Author(s):  
Cai-Lin Wang ◽  
Wei Pan ◽  
Qiu Xu ◽  
C.J. Jiang ◽  
Kazutaka Mori ◽  
...  
Keyword(s):  
Gas Turbines ◽  
Ceramic Materials ◽  
Yttria Stabilized Zirconia ◽  
Thermal Barrier ◽  
Stabilized Zirconia ◽  
Barrier Coatings ◽  
Gadolinium Zirconate ◽  
Long Term Stability ◽  
Sintering Behaviour

The increase of the efficiency for gas turbines leads to the increasing combustion-chambertemperatures. Rapid degradation of the conventional yttria-stabilized zirconia coatings does not fulfill therequirements at these temperatures for a reliable thermal barrier coatings (TBCs) due to the phasetransformation of zirconia and the sintering behaviour. Therefore, it is very important to develop novel ceramic materials for TBCs with low thermal conductivity and long-term stability at high temperatures.In this paper, the developments of potential novel ceramic materials for TBCs with low thermalconductivity are reviewed.

Novel Low Thermal Conductivity Ceramic Materials for Thermal Barrier Coatings

2007 ◽  
Vol 280-283 ◽  
pp. 1497-1500 ◽  
Author(s):  
Wei Pan ◽  
Qiang Xu ◽  
Long Hao Qi ◽  
Jing Dong Wang ◽  
He Zhuo Miao ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Thermal Barrier Coatings ◽  
Gas Turbines ◽  
Ceramic Materials ◽  
Thermal Barrier ◽  
Barrier Coatings ◽  
Low Thermal Conductivity ◽  
Long Term Stability ◽  
Sintering Behaviour

The increase of the efficiency for gas turbines leads to the increasing combustion-chambertemperatures. Rapid degradation of the conventional yttria-stabilized zirconia coatings does not fulfill therequirements at these temperatures for a reliable thermal barrier coatings (TBCs) due to the phasetransformation of zirconia and the sintering behaviour. Therefore, it is very important to develop novelceramic materials for TBCs with low thermal conductivity and long-term stability at high temperatures.In this paper, the developments of potential novel ceramic materials for TBCs with low thermalconductivity are reviewed.

scholarly journals A Comparative Study on the Synthesis and Properties of Yttria Stabilized Zirconia (YSZ) and Lanthana Doped YSZ Plasma Sprayed Thermal Barrier Coatings

2013 ◽  
Author(s):  
S. T. Aruna ◽  
N. Balaji ◽  
B. Arul Paligan
Keyword(s):  
Thermal Conductivity ◽  
Thermal Barrier Coatings ◽  
Gas Turbines ◽  
Operating Temperature ◽  
Yttria Stabilized Zirconia ◽  
Thermal Barrier ◽  
Spray Parameters ◽  
Stabilized Zirconia ◽  
Barrier Coatings ◽  
Plasma Sprayed

Ceramic thermal barrier coatings (TBCs) have been used for decades to extend the life of combustors and high temperature turbine stationary and rotating components to increase the operating temperature and in turn the performance of gas turbines or diesel engines can be increased. At present, thermal barrier coatings (TBCs) of Y2O3 partially stabilized ZrO2 (YSZ) films are widely used. In recent years ceramic compositions useful in thermal barrier coatings having reduced thermal conductivity are being explored to further increasing the operating temperature of gas turbines and improve the engine efficiency. In the present study, a comparison of the properties of state-of-the art 8wt% yttria stabilized zirconia (YSZ) and lanthana doped YSZ plasma sprayed coatings is presented. Plasma sprayable powders were prepared in the laboratory by a single step precipitation method and characterized. Both the powders had good flowability. These powders were plasma sprayed at identical critical plasma spray parameters. The coatings were characterized for phase, microstructure and thermal conductivity. Both the powders and coatings exhibited tetragonal form of zirconia and no traces of lanthana were observed. Both the coatings exhibited similar porosity levels. Microstructure of the coatings revealed porous coating with good adhesion of the bondcoat with the topcoat. Plasma sprayed 8wt% YSZ and lanthana doped YSZ exhibited thermal conductivity values of 0.88 and 0.67 W m−1 K−1 respectively which is lower than that reported in literature. This study shows that lanthana doping in YSZ helps in lowering the thermal conductivity and hence this coating may be a potential candidate for TBC application.

Time-Dependent Behavior and Fracture of Functionally Graded Thermal Barrier Coatings under Thermal Shock

2005 ◽  
Vol 492-493 ◽  
pp. 379-384 ◽  
Author(s):  
Klod Kokini ◽  
Sudarshan V. Rangaraj
Keyword(s):  
Thermal Shock ◽  
Thermal Barrier Coatings ◽  
Functionally Graded ◽  
Yttria Stabilized Zirconia ◽  
Time Dependent ◽  
Thermal Barrier ◽  
Stabilized Zirconia ◽  
Barrier Coatings ◽  
Dependent Behavior ◽  
Bond Coat Alloy

The thermal fracture and its dependence on time-dependent behavior in functionally graded yttria stabilized zirconia - NiCoCrAlY bond coat alloy thermal barrier coatings was studied. The response of three coating architectures of similar thermal resistance to laser thermal shock tests was considered, experimentally and computationally.

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