Mechanical and Thermal Evaluation of Diatomite Doped Fly Ash Based Geopolymers

In this work, the properties of alkali silicate geopolymer type materials and diatomite as additive to fly coal ash was investigated using thermic coal plant’s fly ash in alkaline solution. The reacted products of alumino-silicate geopolymers using fly ash plus diatomite were pseudo-amorphous aluminosilicate gel and calcite and their mechanical and thermal properties were evaluated by the addition of diatomite. The compressive strength of this geopolymer is similar to that of the Portland cement mortar of PC20 (± 20 %) when cured for 28 days while the density and thermal properties are much lower that indicates the insulator properties. Alkaline solution was produced by NaOH in different concentrations to determine the least alkaline solution molarity in the range of 1 M, 3 M and 5 M. The characterization of geopolymers were done by using XRD for phase analysis, SEM for surface and morphological evaluation, compression tests for mechanical properties and transient plane source thermal analysis for thermal insulation properties. The results showed that, 1 M of NaOH alkaline solution and 10wt% diatomite addition can provide enough strength of 18 MPa which is a good candidate for constructional materials. The thermal conductivity coefficient of 10 wt.% diatomite added geopolymer was evaluated as 0.0018 W/m×K which can also be a good candidate for insulator materials to be used in green lateral wall production.

Use of Natural Pyrophyllite as Cement Substitution in Ultra Performance Polypropylene Fiber Concrete

The present work investigates the use of an alumino-silicate material, the pyrophyllite as cement substitution, synthetic polypropylene fibers and binder to create an unusual ultra-performance fiber concrete; new composite, which offers a wide field of possible use in construction industry. Effect of pyrophyllite on the physical-mechanical properties is analyzed. One reference fiber concrete without pyrophyllite and three fiber concretes containing 10%, 20%, 30% of pyrophyllite were elaborated. Results show that the pyrophyllite affects the characteristics of the concrete. Indeed, in the hardened state, the density of fiber concrete decreased with pyrophyllite rate increasing. Moreover, the use of pyrophyllite slows down the hardening process of concrete, consequently producing at early ages, compressive, flexural and tensile strengths and elastic modulus of concretes approaching without exceeding those of the reference fiber concrete. The fiber concretes are also considered to be of good quality. It seems that the rate of 10 % of pyrophyllite generates the best physical-mechanical performances that approach those of the reference fiber concrete. The use of pyrophyllite as a cement substitution is beneficial since it can help to decrease the production of cement; the amount of CO2 released and protects the environment.