Piezoelectric Properties and Depolarization Temperatures of (Bi1/2Na1/2)TiO3-(Bi1/2K1/2)TiO3-BaTiO3 Lead-Free Piezoelectric Ceramics

2006 ◽  
Vol 320 ◽  
pp. 23-26 ◽  
Author(s):  
Yuji Hiruma ◽  
Kazushige Yoshii ◽  
Rintaro Aoyagi ◽  
Hajime Nagata ◽  
Tadashi Takenaka
Keyword(s):  
Electromechanical Coupling ◽  
Piezoelectric Properties ◽  
Sodium Titanate ◽  
Piezoelectric Ceramics ◽  
Lead Free ◽  
Bismuth Sodium Titanate ◽  
Depolarization Temperature ◽  
Potassium Titanate ◽  
Coupling Factors ◽  
Dielectric And Piezoelectric Properties

The piezoelectric properties of a solid solution based on the three components of bismuth sodium titanate, (Bi1/2Na1/2)TiO3 (BNT), bismuth potassium titanate, (Bi1/2K1/2)TiO3 (BKT), and barium titanate, BaTiO3 (BT), that is, x(Bi1/2Na1/2)TiO3-y(Bi1/2K1/2)TiO3-zBaTiO3 [BNBKy:z(x); x+y+z=1] are investigated. Fine piezoelectric properties in lead-free piezoelectric ceramics were obtained near the MPB composition, and the highest electromechanical coupling factors, k33 and kp, and piezoelectric constant, d33, were 0.58 and 0.36 for BNBK2:1(0.89) and 181 pC/N for BNBK2:1(0.88), respectively. In this study, we also measured the depolarization temperature, Td, from the temperature dependence of dielectric and piezoelectric properties.

Morphotropic Phase Boundary Study of the BNT-BKT Lead-Free Piezoelectric Ceramics

2008 ◽  
Vol 368-372 ◽  
pp. 1908-1910 ◽  
Author(s):  
Wei Zhao ◽  
He Ping Zhou ◽  
Yong Ke Yan ◽  
Dan Liu
Keyword(s):  
Phase Boundary ◽  
Morphotropic Phase Boundary ◽  
Composition Range ◽  
Piezoelectric Properties ◽  
Rhombohedral Phase ◽  
Sodium Titanate ◽  
Xrd Analysis ◽  
Lead Free ◽  
Bismuth Sodium Titanate ◽  
Potassium Titanate

A lead-free piezoelectric ceramic binary system based on bismuth sodium titanate (Bi0.5Na0.5)TiO3 (BNT)-bismuth potassium titanate (Bi0.5K0.5)TiO3 (BKT) was synthesized by conventional mixed-oxide technique. The XRD analysis showed that the rhombohedral-tetragonal morphotropic phase boundary (MPB) of the Bi0.5 (Na1-xKx)0.5 TiO3 system was in the composition range of x = 0.16 ~ 0.20. In addition, the piezoelectric properties of this system were also investigated. It was indicated that the piezoelectric properties are better with the compositions near the rhombohedral phase within the MPB than the compositions near the tetragonal phase.

Preparation and Properties of Bi0.5Na0.5TiO3-Ba (Hf,Ti)TiO3 Lead-Free Piezoelectric Ceramics

2007 ◽  
Vol 334-335 ◽  
pp. 957-960
Author(s):  
Hu Yong Tian ◽  
Wan Ping Chen ◽  
D.Y. Wang ◽  
Y. Wang ◽  
J.T. Zeng ◽  
...  
Keyword(s):  
Piezoelectric Coefficient ◽  
Sodium Titanate ◽  
Piezoelectric Ceramics ◽  
Lead Free ◽  
Synthesis Process ◽  
Bismuth Sodium Titanate ◽  
Promising Candidate ◽  
Device Applications ◽  
The Relationship ◽  
Bismuth Sodium

Lead-free piezoelectric ceramics based on bismuth sodium titanate (BNT) -barium hafnate titanate (BHT) were prepared by a two-step synthesis process. The final BNT-BHT ceramics sintered at 1180oC for 2 h in air showed a perovskite structure with high density. The morphotropic phase boundaries (MPB) were found in BNT based piezoelectric ceramics with 8~10 wt% BHT in composites. In the case of Bi0.5Na0.5TiO3-0.08BaHf0.05Ti0.95O3 ceramics, a maximum piezoelectric coefficient d33 of 122.6 pC/N was obtained. The remnant polarization (Pr) and coercive field (Ec) were measured and the relationship between ferroelectricity and the BHT fraction in the compounds was investigated. The BNT-BHT ceramics were expected to be a new and promising candidate for lead-free piezoelectric device applications.

Dielectric and Piezoelectric Properties of Lead Free (1-x-y)Na1/2Bi1/2TiO3-xBaTiO3-yBiFeO3 Piezoelectric Ceramics

2011 ◽  
Vol 492 ◽  
pp. 194-197 ◽  
Author(s):  
Yue Fang Wang ◽  
Xiu Jie Yi ◽  
Wei Pan ◽  
Guo Zhong Zang ◽  
Juan Du
Keyword(s):  
Electrical Properties ◽  
Dielectric Loss ◽  
Phase Structure ◽  
Perovskite Structure ◽  
Piezoelectric Properties ◽  
Piezoelectric Ceramics ◽  
Lead Free ◽  
Compositional Dependence ◽  
Pure Perovskite Structure ◽  
Dielectric And Piezoelectric Properties

Lead-free (1-x-y)Na1/2Bi1/2TiO3-xBaTiO3-yBiFeO3 ceramics were synthesized by ordinary sintering technique. The compositional dependence of phase structure and electrical properties of the ceramics was systematically investigated. All samples possessed pure perovskite structure. The dielectric and piezoelectric properties of ceramics were investigated with the amount of different BiFeO3 substitutions. The addition of BiFeO3 can not only decrease Ec and Pr but also lead to a significant degradation of the dielectric loss tanδ.

Influence of the powder grain size on dielectric and piezoelectric properties of lead-free KxNa1-xNbO3 piezoelectric ceramics

2019 ◽  
Vol 539 (1) ◽  
pp. 89-92
Author(s):  
S. Grigorevich Ponomarev ◽  
V. Pavlovich Tarasovskii ◽  
A. Vladimirovich Reznichenko ◽  
A. Aleksandrovich Vasin
Keyword(s):  
Grain Size ◽  
Piezoelectric Properties ◽  
Piezoelectric Ceramics ◽  
Lead Free ◽  
Dielectric And Piezoelectric Properties

Investigation on Electrical Properties of CaCu3Ti4O12-Modified (Na,Bi)TiO3-BaTiO3 Lead Free Piezoceramics

2014 ◽  
Vol 887-888 ◽  
pp. 289-293
Author(s):  
Jing Chang Zhao ◽  
Zhen Lai Zhou
Keyword(s):  
Electrical Properties ◽  
Electromechanical Coupling ◽  
Piezoelectric Properties ◽  
Piezoelectric Ceramics ◽  
Electromechanical Coupling Factor ◽  
Coupling Factor ◽  
Mechanical Quality Factor ◽  
Lead Free ◽  
Lead Free Ceramics ◽  
Structure Morphology

(Na,Bi)TiO3-BaTiO3lead free piezoelectric ceramics were fabricated with modification of CaCu3Ti4O12additives. The phase structure, morphology, dielectric and piezoelectric properties of prepared samples were investigated, respectively. It was found that CaCu3Ti4O12additives evidently improve the polarization properties of (Na,Bi)TiO3-BaTiO3lead free ceramics and the obtained samples exhibit an excellent piezoelectric properties (electromechanical coupling factorKp=31%, mechanical quality factorQm=151 and piezoelectric constantd33=160pC/N). According to results, the effect of CaCu3Ti4O12additives on electrical properties of (Na,Bi)TiO3-BaTiO3lead free piezoelectric ceramics is discussed.

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