Study of Copolymerization Reaction N,N-Dialylaminocarbonic Acids with Vinyl Acetate

2021 ◽  
Vol 899 ◽  
pp. 355-360
Author(s):  
Madina B. Begieva ◽  
Olga V. Pshikova ◽  
Milana Kh. Begieva ◽  
Mukhamed T. Shaov ◽  
Yusuf A. Malkanduev
Keyword(s):  
Vinyl Acetate ◽  
Radical Copolymerization ◽  
Organic Medium ◽  
Statistical Nature ◽  
Copolymerization Reaction

The reaction of radical copolymerization of N, N-diallylaminocarboxylic acids with vinyl acetate in an aqueous and aqueous-organic medium (a mixture of methanol-water in a ratio of 70:30 mol.%) Obtained copolymers of a statistical nature. It was found that vinyl acetate under these conditions is more reactive than N, N-diallylaminocarboxylic acids. The kinetic laws of the reactions have been investigated and the structures of the copolymers have been established.

Free Radical Copolymerization of Ethylene with Vinyl Acetate under Mild Conditions

2017 ◽  
Vol 50 (9) ◽  
pp. 3516-3523 ◽  
Author(s):  
A. Zarrouki ◽  
E. Espinosa ◽  
C. Boisson ◽  
V. Monteil
Keyword(s):  
Free Radical ◽  
Vinyl Acetate ◽  
Radical Copolymerization ◽  
Free Radical Copolymerization ◽  
Mild Conditions

scholarly journals Features of radical copolymerization initiated by manganese triacetylacetonate

2021 ◽  
pp. 11-14
Author(s):  
N. A. Lavrov
Keyword(s):  
Vinyl Acetate ◽  
Radical Copolymerization ◽  
Kinetics Of ◽  
Comprehensive Study

A comprehensive study of the kinetics of reactions of binary copolymerization of vinyl acetate with N-vinyl (N-vinylsuccinimide and N-vinyl-3(5)-methylpyrazole) and acrylic (2-hydroxyethylmethacrylate) monomers in different media was conducted. It is shown that the use of manganese triacetylacetonate as an initiator makes it possible to bring together the relative activities of monomers due to the complexation of manganese trisacetylacetonate and vinyl acetate molecules. This leads to a change in the microstructure of copolymers and to the production of macrochains with improved interleaving of monomeric links.

scholarly journals Cobalt-Mediated Radical Copolymerization of Chlorotrifluoroethylene and Vinyl Acetate

Polymers ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 101 ◽  
Author(s):  
Pucheng Wang ◽  
Hu Wang ◽  
Qibao Dong ◽  
Ruke Bai
Keyword(s):  
Vinyl Acetate ◽  
Molar Mass ◽  
Radical Copolymerization ◽  
Chain Extension

Controlled radical copolymerization of chlorotrifluoroethylene (CTFE) and vinyl acetate (VAc) was successfully achieved in the presence of bis(acetylacetonato)cobalt(II) (Co(acac)2) as a mediated agent and 2,2′-azo-bis-isobutyronitrile (AIBN) as initiator. Both the molar mass and the fluorinated unit content of the copolymer could be controlled, and the chain extension polymerization of the obtained fluorinated copolymer was also achieved.

scholarly journals Organometallic-Mediated Alternating Radical Copolymerization of tert -Butyl-2-Trifluoromethacrylate with Vinyl Acetate and Synthesis of Block Copolymers Thereof

2017 ◽  
Vol 38 (15) ◽  
pp. 1700203 ◽  
Author(s):  
Sanjib Banerjee ◽  
Vincent Ladmiral ◽  
Antoine Debuigne ◽  
Christophe Detrembleur ◽  
S. M. Wahidur Rahaman ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Vinyl Acetate ◽  
Radical Copolymerization ◽  
Tert Butyl

Solvent effect on radical copolymerization of N,N-diallyl-N,N-dimethylammonium chloride and vinyl acetate

2009 ◽  
Vol 82 (8) ◽  
pp. 1461-1466 ◽  
Author(s):  
A. I. Vorob’eva ◽  
D. R. Sagitova ◽  
S. V. Kolesov ◽  
Yu. B. Monakov
Keyword(s):  
Solvent Effect ◽  
Vinyl Acetate ◽  
Radical Copolymerization ◽  
Dimethylammonium Chloride
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