Identification of the Mechanism of Synthesis of SDRL Rubber

2022 ◽  
Vol 1049 ◽  
pp. 211-217
Author(s):  
Elvira Garifullina ◽  
Galiya Manuyko ◽  
Guzel Aminova ◽  
Veronika Bronskaya ◽  
Denis Balzamov ◽  
...  

Modelling and identification of the synthesis of SDRL rubber in the presence of toluene and modifier was carried out. The mechanism of the polymerization of butadiene on the lithium catalytic system. One of the most characteristic differences between the processes of ionic, in particular, anionic, polymerization and radical polymerization is that even when using initiators that seem to be individual, several forms of active centres, that differ in their reactivity, can simultaneously be present in systems.

2017 ◽  
Vol 8 (23) ◽  
pp. 3574-3585 ◽  
Author(s):  
Wenchao Ma ◽  
Xianhong Zhang ◽  
Yuhong Ma ◽  
Dong Chen ◽  
Li Wang ◽  
...  

Under 23 W CFL irradiation, block copolymers are obtained starting from a Pn-I macroinitiator in the presence of a benzaldehydic molecule-based catalytic system.


1984 ◽  
Vol 20 (5) ◽  
pp. 429-432 ◽  
Author(s):  
I.V. Berlinova ◽  
C.B. Tsvetanov ◽  
I.M. Panayotov ◽  
L.V. Vinogradova

2015 ◽  
Vol 6 (10) ◽  
pp. 1875-1882 ◽  
Author(s):  
Francisco Catalão ◽  
Joana R. Góis ◽  
A. S. M. Trino ◽  
Arménio C. Serra ◽  
Jorge F. J. Coelho

The detailed synthesis of poly(glycidyl methacrylate) (PGMA) by atom transfer radical polymerization (ATRP) using a catalytic system of Fe(0)/Cu(ii)Br2 at room temperature is reported.


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