Atomic Bonding and Properties of Al-Li Alloy in Earlier Ageing Stage

2007 ◽  
Vol 546-549 ◽  
pp. 819-824
Author(s):  
Ying Jun Gao ◽  
Qi Feng Mo ◽  
Yu Ling Wang ◽  
Iina Zhang ◽  
Chuang Gao Huang

The atomic bonding of the segregated cell of Al-Li alloy in earlier ageing condition was calculated according to the empirical electron theory (EET) in solid. The results showed that the strongest covalent bond was the Al-Al bond in the segregated cell without vacancy, while the strongest covalent bond was the Al-Li bond in the cell containing vacancy. Since the difference of electronagativity between the Al and Li atoms was obvious, it was inclined to form the Al-Li segregated cell of short range order structure in the condition of vacancy joining. The short range order structure with vacancy was probably the embryo or precursor structure of the metastable phase ' δ (Al3Li). As the ' δ (Al3Li) was coherence with matrix, the bond net strength was enhanced by the precipitation of ' δ (Al3Li) and hence the alloy was strengthened.

1979 ◽  
Vol 22 (5) ◽  
pp. 484-486
Author(s):  
Ya. I. Dutchak ◽  
N. M. Klym ◽  
S. I. Mudryi ◽  
V. S. Frenchko

2004 ◽  
Vol 100 (4) ◽  
pp. 567-572 ◽  
Author(s):  
S. L. Votyakov ◽  
A. V. Porotnikov ◽  
Yu. V. Shchapova ◽  
E. I. Yuryeva ◽  
A. L. Ivanovskii

1989 ◽  
Vol 158 (1-3) ◽  
pp. 465-466 ◽  
Author(s):  
A. Krol ◽  
L.Y. Jang ◽  
S.C. Woronick ◽  
F. Xu ◽  
Y.D. Yao ◽  
...  

1977 ◽  
Vol 20 (12) ◽  
pp. 1626-1629
Author(s):  
E. S. Levin ◽  
Yu. S. Alekseev ◽  
P. V. Gel'd

2007 ◽  
Vol 55 (16) ◽  
pp. 5382-5388 ◽  
Author(s):  
Takumi Hasegawa ◽  
Keiichi Osaka ◽  
Toshihiko Takama ◽  
Haydn Chen

1978 ◽  
Vol 34 (5) ◽  
pp. 667-681 ◽  
Author(s):  
J. E. Epperson ◽  
P. Fürnrohr ◽  
C. Ortiz

1984 ◽  
Vol 40 (3) ◽  
pp. 264-269 ◽  
Author(s):  
W. O. Milligan ◽  
D. F. Mullica ◽  
H. O. Perkins ◽  
C. K. C. Lok ◽  
J. J. McCoy ◽  
...  

1996 ◽  
Vol 51 (3) ◽  
pp. 179-186 ◽  
Author(s):  
Uwe Hoppe ◽  
Günter Walter ◽  
Dörte Stachel ◽  
Alex C. Hannon

The short-range order of KPO3 glass has been studied by diffraction methods in order to make evident the different behaviour of the P-O bonds within the PO4 tetrahedron. The oxygen sites are devided into bridging and terminal (non-bridging) oxygen sites, corresponding to two P-O bond lengths, the difference of which amounts to 14.5 pm. Previous conclusions about the changes of the P-O bond lengths under the influence of modifier cations of different electric field strength are corroborated. The K-O environments reveal two apparently different distances rKO with equal contributions to the total K-O coordination number of about 6.7. To explain this phenomenon, the K+ cations are suggested to be located in non-spherical cavities


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