Spin Disorder Resistivity and Electronic Specific Heat of Gd4(Co1-xCux)3 Compounds

2008 ◽  
Vol 587-588 ◽  
pp. 333-337
Author(s):  
T.M. Seixas ◽  
M.A. Salgueiro da Silva ◽  
O.F. de Lima ◽  
J. Lopez ◽  
Hans F. Braun ◽  
...  

In this work, we present a study of the spin disorder resistivity ( ρm∞) and the electronic specific heat coefficient ( γ) in Gd4(Co1-xCux)3 compounds, with x = 0, 0.05, 0.10, 0.20, 0.30. The experimental results show a strongly non-linear dependence of ρm∞ on the de Gennes factor which, in similar intermetallic compounds, is usually attributed to the existence of spin fluctuations on the Co 3d bands and its amplification by the thermal disorder of the Gd magnetic moments through the Gd-Co exchange coupling. Using a novel combined analysis of ρm∞ and γ, we show, however, that only electron band structure changes are involved in the anomalous behaviour of ρm∞ and that a linear dependence of ρm∞ on the de Gennes factor is obtained when the variation of the effective mass is properly taken into account.

1969 ◽  
Vol 47 (10) ◽  
pp. 1077-1081 ◽  
Author(s):  
Douglas L. Martin

Face-centered-cubic alloys of gold with 10 atomic % zinc (divalent) and 10 atomic % indium (trivalent), respectively, were measured in the range 0.4 to 3.0 °K. The coefficients of the nuclear specific-heat term were 1.80 ± 0.07 μcal °K/g atom for AuZn and 1.29 ± 0.06 μcal °K/g atom for AuIn (95% confidence limits). For a gold–10 atomic % silver (monovalent) alloy (Martin 1968) the nuclear term was 0.44 μcal °K/g atom. These results show that electric field gradients in alloys are not simply proportional to the valence difference of the components, a conclusion which may be drawn from NMR results. For the AuZn alloy the electronic specific-heat coefficient (γ) is 153.4 ± 0.7 μcal/°K2 g atom and the limiting value of the Debye temperature (θ0c) is 177.0 ± 0.5 °K. For the AuIn alloy γ is 185.9 ± 0.7 μcal/°K2 g atom and θ0c is 159.1 ± 0.3 °K.


2007 ◽  
Vol 62 (7) ◽  
pp. 977-981 ◽  
Author(s):  
Ladislav Havela ◽  
Khrystyna Miliyanchuk ◽  
Laura C. J. Pereira ◽  
Eva Šantavá

Abstract U2Co2InH1.9, synthesized by high-pressure hydrogenation of U2Co2In, crystallizes in the tetragonal structure similar to the parent compound, expanded by 8.4 %. Although U2Co2In is a weak paramagnet, its hydride shows properties suggesting a proximity to the magnetic order. Its magnetic susceptibility exhibits a maximum at T = 2.4 K, ascribed to spin fluctuations. Magnetization at low temperatures goes through a metamagnetic transition between 2 - 3 T. The specific heat characteristics, with a pronounced upturn of Cp/T vs. T at low temperatures which can be fitted using an additional −T 1/2 term, resemble the behaviour of U2Co2Sn. The γ coefficient of the electronic specific heat, reaching 244 mJ mol−1 K−2, is gradually suppressed by high magnetic fields.


1993 ◽  
Vol 209 (4) ◽  
pp. 553-558 ◽  
Author(s):  
Takashi Nishikawa ◽  
Shin-ichi Shamoto ◽  
Masafumi Sera ◽  
Masatoshi Sato ◽  
Shigeki Ohsugi ◽  
...  

1995 ◽  
Vol 7 (22) ◽  
pp. 4183-4191 ◽  
Author(s):  
Y Hattori ◽  
K Fukamichi ◽  
K Suzuki ◽  
A Niikura ◽  
A P Tsai ◽  
...  

1993 ◽  
Vol 73 (10) ◽  
pp. 5427-5429 ◽  
Author(s):  
C. J. Fuller ◽  
Z. W. Chen ◽  
N. Anbalagan ◽  
C. L. Lin ◽  
T. Mihalisin

1993 ◽  
Vol 07 (01n03) ◽  
pp. 370-373 ◽  
Author(s):  
N. BARANOV ◽  
E. BAUER ◽  
E. GRATZ ◽  
R. HAUSER ◽  
A. MARKOSYAN ◽  
...  

The temperature dependence of the resistivity and the thermopower in the region from 4.2K up to 1000K for the six isostructural paramagnetic compounds TCo 2 (T=Y, Lu, Sc, Hf, Zr, Ce) is studied. The resistivity ρ (T) follows a T 2 dependence at low temperatures in all these compounds. Plotting the A values into an A vs. γ2 diagram shows that YCo 2, LuCo 2, and ScCo 2 are spinfluctuation systems (A and γ denote the coefficients in ρ (T) = ρ0 + AT 2 and that of the electronic specific heat, respectively) HfCo 2 and ZrCo 2 do not fit into this general tendency in the ( A , γ2)-diagram. The temperature dependent thermopower S(T) in YCo 2, LuCo 2 and ScCo 2 exhibits a pronounced minimum in the low temperature region. These minima are obviously connected with the existence of spin fluctuations (paramagnon-drag). Spin fluctuations in HfCo 2 and ZrCo 2 are less important. This we conclude also from the ten times smaller A-values and the missing minimum in the thermopower at low temperatures.


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