Electrolytic Hydriding of La(Fe, Si)13 Based Materials and its Magnetocaloric Effect

2014 ◽  
Vol 809-810 ◽  
pp. 443-448 ◽  
Author(s):  
Kun Yang ◽  
Na Tian ◽  
Cai Yin You
Keyword(s):  
Phase Transition ◽  
Magnetic Properties ◽  
External Field ◽  
Curie Temperature ◽  
Surface Morphology ◽  
Order Phase Transition ◽  
Magnetic Entropy Change ◽  
Entropy Change ◽  
Magnetic Entropy ◽  
Second Order Phase Transition

In this paper, the hydriding of La (Fe, Fe)13 based alloys was realized by the electrolytic method and the effect of electrolytic temperature on the hydriding was investigated. The phase components and surface morphology were analyzed by XRD and SEM. The magnetic properties of samples were characterized using VSM. Results showed that the electrolytic hydriding process was enhanced by increasing the electrolytic temperature. The Curie temperature was increased from 196 K to 325 K. Through Arrot-plot analyses, it was found that the phase transition of samples tends to be a second order phase transition. The magnetic entropy change was reduced from 8.03 J/(kg•K) to 2.03 J/(kg•K) under a maximum external field of 1.5 T.

scholarly journals Magnetic properties of the non-stoichiometric TbCo2Nix alloys

2018 ◽  
Vol 185 ◽  
pp. 04021
Author(s):  
Alexander Inishev ◽  
Evgeny Gerasimov ◽  
Nikolay Mushnikov ◽  
Pavel Terentev ◽  
Vasily Gaviko
Keyword(s):  
Magnetic Properties ◽  
Curie Temperature ◽  
Concentration Dependence ◽  
Magnetic Moment ◽  
Magnetic Entropy Change ◽  
Entropy Change ◽  
Magnetic Entropy ◽  
Thermodynamic Relation ◽  
Temperature Dependences

The magnetic and magnetothermal properties of the non-stoichiometric TbCo2Nix (0 ≤ x ≤ 0.2) alloys were studied. It was found that the concentration dependence of the Curie temperature and magnetic moment of the 3d-sublattice have a maximum at x = 0.025. The obtained experimental magnetic properties of the TbCo2Nix alloys were discussed under assumption that the Co magnetic moment in the compounds changes with increasing x. The magnetic entropy change was determined using the temperature dependences of the magnetization and Maxwell’s thermodynamic relation. The obtained results for TbCo2Nix were compared with those for the ErCo2Mnx alloys.

Enhanced Curie temperature and magnetic entropy change of Gd50Co50−xNix amorphous alloys

2019 ◽  
Vol 34 (04) ◽  
pp. 2050050 ◽  
Author(s):  
M. N. Song ◽  
L. W. Huang ◽  
B. Z. Tang ◽  
D. Ding ◽  
Q. Zhou ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Amorphous Alloy ◽  
Curie Temperature ◽  
Binary Alloy ◽  
Metallic Glasses ◽  
Amorphous Alloys ◽  
Magnetic Entropy Change ◽  
Entropy Change ◽  
Magnetic Entropy ◽  
Ni Addition

Small amount of Ni was added in the [Formula: see text] binary alloy to replace the Co element for improving the formability and magnetic properties of the binary amorphous alloy. It was found that the glass formability of the [Formula: see text] amorphous alloy was significantly improved by Ni addition. The Curie temperature [Formula: see text] of the [Formula: see text] metallic glasses decreases with the Ni addition, and the maximum magnetic entropy change [Formula: see text] was also improved. The mechanism for the effect of adding a small quantity of Ni on the [Formula: see text] and [Formula: see text] of the [Formula: see text] amorphous alloy was studied.

scholarly journals Magnetic properties and magnetic entropy change of Ce2Fe16Al near Curie temperature

2003 ◽  
Vol 52 (5) ◽  
pp. 1250
Author(s):  
Shen Jun ◽  
Li Yang-Xian ◽  
Hu Feng-Xia ◽  
Wang Guang-Jun ◽  
Zhang Shao-Ying
Keyword(s):  
Magnetic Properties ◽  
Curie Temperature ◽  
Magnetic Entropy Change ◽  
Entropy Change ◽  
Magnetic Entropy

Magnetic Phase Transition and Magnetic Proporties of LaFe11.6Si1.4Bx Compounds

2013 ◽  
Vol 750-752 ◽  
pp. 919-922
Author(s):  
Kun Xie ◽  
Yin Liu ◽  
Mei Qing Cao ◽  
Peng Cheng Xia ◽  
Li Jie Yue
Keyword(s):  
Phase Transition ◽  
Curie Temperature ◽  
Magnetic Phase Transition ◽  
Magnetic Entropy Change ◽  
Magnetic Phase ◽  
Magnetic Transition ◽  
Entropy Change ◽  
Magnetic Entropy ◽  
First Order ◽  
Melt Spun

The magnetic phase transition and magnetic entropy change of melt-spun LaFe11.6Si1.4Bx(x=0.0, 0.3, 0.5, 0.7) ribbons were investigated by measuring the magnetization as the function of temperature. Comparing with LaFe11.6Si1.4, the NaZn13-type structure of LaFe11.6Si1.4Bxdid not change after introducing B atoms, while the amount of α-Fe phase in the ribbons significantly decreased. The Curie temperature slightly changes after the addition of B. The LaFe11.6Si1.4Bx(x=0.3, 0.5) exhibits first-order magnetic transition and large magnetic entropy change as observed in LaFe11.6Si1.4compound.

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