Fabrication of Carbon Paste Electrode Modified with Phenol Imprinted Polyaniline as a Sensor for Phenol Analysis by Potentiometric

2018 ◽  
Vol 936 ◽  
pp. 71-76 ◽  
Author(s):  
Sri Rahmadhani ◽  
Henry Setiyanto ◽  
Muhammad Ali Zulfikar

A phenol imprinted polymer modified electrode has been prepared by electropolymerization technique in the solution containing aniline as monomer and phenol as a template onto carbon paste electrode surface. A potentiometric method was used to evaluate the performance of the electrodes. Optimization of aniline and phenol composition and a number of polymerization cycles was investigated based on the Nernstian factor. The performance of the electrode sensor is affected by the pH of the analyte solution. Based on the potential response of three different electrodes, it is known that MIP modified electrode has better sensitivity than non-imprinted electrode or bare carbon paste electrode.

2019 ◽  
Vol 84 (2) ◽  
pp. 175-185 ◽  
Author(s):  
Mohadeseh Safaei ◽  
Hadi Beitollahi ◽  
Masoud Shishehbore ◽  
Somayeh Tajik ◽  
Rahman Hosseinzadeh

A carbon paste electrode (CPE) was modified with N-(ferrocenylmethylidene) fluorene-2-amine and graphene/ZnO nanocomposite. The electrooxidation of captopril (CAP) at the surface of the modified electrode was studied using electrochemical approaches. The electrochemical study of the modified electrode, as well as its efficiency for the electrocatalytic oxidation of captopril, is described. The electrode was used to study the electrocatalytic oxidation of captopril, by cyclic voltammetry (CV), chronoamperometry (CHA) and differential pulse voltammetry (DPV) as diagnostic techniques. It has been found that the oxidation of captopril at the surface of modified electrode occurs at a potential of about 340 mV less positive than that of an unmodified CPE. DPV of captopril at the electrochemical sensor exhibited two linear dynamic ranges (0.1?100.0 and 100.0?800.0 ?M) with a detection limit (3?) of 0.05 ?M.


2017 ◽  
Vol 97 (14-15) ◽  
pp. 1378-1392 ◽  
Author(s):  
Malena Karla Lombello Coelho ◽  
Hanna Leijoto De Oliveira ◽  
Fernanda Garcia De Almeida ◽  
Keyller Bastos Borges ◽  
César Ricardo Teixeira Tarley ◽  
...  

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