Thermionic Emission of Yttrium Dodecaboride Single Crystal

2019 ◽  
Vol 289 ◽  
pp. 47-52 ◽  
Author(s):  
Daniil Voronovych ◽  
Anatoliy Taran ◽  
Oksana Podshyvalova ◽  
Natalya Shitsevalova ◽  
Volodymyr Filipov ◽  
...  

Experimental data on thermionic current density and electron work function of YB12 (100) at T = 1218 – 1978 K in high vacuum (p < 10-4 Pa) are first introduced. Temperature dependences of the thermionic current density and effective electron work function are presented without extrapolation to the zero-field currents because of the anomalous Schottky effect. The temperature dependences of theYB12 electron work function can be described by linear functions at certain temperature intervals. Preferential boron evaporation and additional ion bombardment by the residual gases ions and evaporated boron ions results in appearance of new phases depleted of boron on the YB12 surface. As a result, an YB4 – YB6 double layer on the YB12 single crystal surface has formed. The appearance of the new boride phases, depleted of boron, on the emitting surface causes an increase of thermionic current density compared with individual YB12.

1989 ◽  
Author(s):  
E. J. Petit ◽  
V. M. Humblet ◽  
A. Brezini ◽  
R. Caudano ◽  
A. Gouskov ◽  
...  

Author(s):  
Н.А. Торхов ◽  
В.А. Новиков

Abstract Using atomic-force-microscopy investigations of the electrostatic system of the crystal surface of AuNi/ n – n ^+-GaN planar Schottky diodes, it is shown that the electron work function for the surface of metal Schottky contacts depends on their linear size (diameter D ). At D > 120 μm, the work function of the central contact region approaches the work function e φ_Au ≈ 5.40 eV of a continuous metallic gold film. A decrease in the diameter leads to a decrease in the work function to 5.34 eV at D = 120 μm, 5.21 eV at D = 40 μm, 5.18 eV at D = 10 μm, and 5.14 eV at D = 5 μm. The observed decrease in the work function with diameter is related to the increasing influence of the built-in periphery electrostatic field E _ l , which is determined by the area and perimeter of the Schottky contact. The fundamental differences between the thermodynamic and electrostatic systems of TiAlNiAu/ n ^+-GaN ohmic contacts, in contrast to analogous AuNi/ n -GaN Schottky systems, are indicative of the absence of a Schottky barrier in them and the decisive role of the thermionic transport of mobile carriers.


1990 ◽  
Vol 208 ◽  
Author(s):  
D. N. Dunn ◽  
L. D. Marks ◽  
J. P. Zhang

ABSTRACTWe investigate the evolution of the microstructure of a reconstructed Au (001) single crystal surface using ultra high vacuum transmission electron microscopy (UHV-TEM). Bulk single crystal Au (001) surfaces were prepared via standard metallographic techniques and sputter anneal cycles. After a clean surface was obtained, the (001) surface was found to reconstruct into two nearly orthogonal domains of dimensions (5 × ∼ 20 ) along the <110> directions of the unreconstructed F.C.C. (001) surface. Transmission electron diffraction patterns (TED) and dark field microscopy are the two primary techniques used to determine the symmetry and dimensions of the reconstructed surface.


1974 ◽  
Vol 52 (17) ◽  
pp. 1589-1593 ◽  
Author(s):  
R. P. Leblanc ◽  
B. C. Vanbrugghe ◽  
F. E. Girouard

A spherical projection diode was used to determine the Richardson constants from a niobium spherical single crystal. Work function and AR values are reported for the [110], [111], [112], [113], [116], [001], and [310] crystallographic directions. Examination of the crystal surface revealed plateau-like surface structure, thermal etch pits, and whisker growth.


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