On the Mitigation of Corrosion Under Insulation (CUI) of Mild Steel Using Local Cathodic Protection

CORROSION ◽  
10.5006/3197 ◽  
2019 ◽  
Vol 75 (12) ◽  
pp. 1541-1551 ◽  
Author(s):  
Q. Cao ◽  
M. Brameld ◽  
N. Birbilis ◽  
S. Thomas

A strategy based on cathodic protection (CP) could be a practically feasible means to protect steel piping from corrosion under insulation. However, experimental studies investigating CP of steel through moist insulation are scarce. Herein, CP was explored to protect insulated steel specimens using sacrificial zinc anodes. The conditions to effectively impart CP through the moist insulation have been discussed. The “throwing power” or protection achieved using sacrificial zinc anodes coupled with mild steel specimens in moist insulation was also estimated using copper electroplating. It was validated that the efficacy of CP depends upon the ionic resistivity of the moist insulation and the moisture content (by volume) must be >25% for efficient ionic conductivity through the insulation. The maximum throwing power of CP through the insulation was achieved when zinc was in direct physical contact with mild steel, with zinc to mild steel area ratio being 1:10.

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 989
Author(s):  
Feihu Tan ◽  
Hua An ◽  
Ning Li ◽  
Jun Du ◽  
Zhengchun Peng

All-solid-state batteries (ASSBs) are attractive for energy storage, mainly because introducing solid-state electrolytes significantly improves the battery performance in terms of safety, energy density, process compatibility, etc., compared with liquid electrolytes. However, the ionic conductivity of the solid-state electrolyte and the interface between the electrolyte and the electrode are two key factors that limit the performance of ASSBs. In this work, we investigated the structure of a Li0.33La0.55TiO3 (LLTO) thin-film solid electrolyte and the influence of different interfaces between LLTO electrolytes and electrodes on battery performance. The maximum ionic conductivity of the LLTO was 7.78 × 10−5 S/cm. Introducing a buffer layer could drastically improve the battery charging and discharging performance and cycle stability. Amorphous SiO2 allowed good physical contact with the electrode and the electrolyte, reduced the interface resistance, and improved the rate characteristics of the battery. The battery with the optimized interface could achieve 30C current output, and its capacity was 27.7% of the initial state after 1000 cycles. We achieved excellent performance and high stability by applying the dense amorphous SiO2 buffer layer, which indicates a promising strategy for the development of ASSBs.


2015 ◽  
Vol 76 (13) ◽  
Author(s):  
Bishir Usman ◽  
Hasmerya Maarof ◽  
Hassan H. Abdallah ◽  
Rosmahida Jamaludin ◽  
Mohamed Noor Hasan ◽  
...  

Corrosion inhibition of mild steel in 0.5M H2SO4 at 30oC with thiophene-2- ethylamine (TEA) as inhibitor has been assess by quantitative structure activity relation (QSAR) model and quantum chemical calculations. The results were evaluated using weight loss and electrochemical methods such as potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS). The results showed good performance of TEA in corrosion protection which behaves as mixed inhibitor from PDP. The micrograph from FESEM and EDX dot mapping showed that the inhibitor adsorbed onto the metal surface with different distribution for S, C and N atoms which indicate less damage on the metal surface in the presence of TEA.


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