Mitigating CO2 Corrosion of Natural Gas Steel Pipelines by Thermal Spray Aluminum Coatings

CORROSION ◽  
10.5006/3797 ◽  
2021 ◽  
Author(s):  
Zineb belarbi ◽  
Joseph Tylczak ◽  
Margaret Ziomek-Moroz

Internal pipeline corrosion due to CO2 is a major challenge facing the oil and gas industry. To protect the pipelines and equipment from the ravages of CO2 corrosion, novel sacrificial coatings can be used. The objective of this study was to investigate the corrosion behavior of Al-based alloys as sacrificial coatings to protect pipelines in a CO2-saturated aqueous electrolyte (3.5 wt.% NaCl) at 4 bar CO2 partial pressure (3 barg) and 40 oC. The corrosion resistance of Al-based alloys and thermal spray coatings was evaluated in an electrochemical reaction autoclave using electrochemical methods (potentiodynamic polarization, linear polarization resistance, and electrochemical impedance spectroscopy). Post-corrosion surface characterization was performed by scanning electron microscopy equipped with energy dispersive X-ray spectroscopy. The obtained data show Al-based alloys demonstrated promising protection against CO2 corrosion with no breakaway degradation issues.

The impact of corrosion within the refining industry ends up in the failure of components. This failure leads to closing down the plant to scrub the corroded components. Additionally, corrosion normally causes serious environmental issues, namely spills and releases. A vital resource for all those that are concerned within the corrosion management of oil and gas infrastructure, corrosion management within the oil and gas industry provides engineers and designers with the tools and strategies to plan and implement comprehensive corrosion-management programs for oil and gas infrastructures. Control of corrosion is important for continuous production and evading the well control losses. Materials to be used in down hole have to meet certain characteristics to avoid corrosion and provide additional mechanical strenght. It is potential to determine a logical series of steps for material choice, incorporating analysis of the surroundings, corrosion rate calculations, and final material choice based on established limits. Several developments have taken place in refinement the calculation of CO2 corrosion rates. Moreover, the definition of bitter examination has been reviewed and a way wider evaluation of the relevance of varied established and new materials for various service conditions has been created.


CORROSION ◽  
10.5006/3233 ◽  
2019 ◽  
Vol 75 (10) ◽  
pp. 1246-1254 ◽  
Author(s):  
Z. Belarbi ◽  
J.M. Dominguez Olivo ◽  
F. Farelas ◽  
M. Singer ◽  
D. Young ◽  
...  

Carbon dioxide (CO2) corrosion mitigation is a challenge in the oil and gas industry. In order to decrease the severity of CO2 corrosion of carbon steel pipelines and equipment, different mitigation practices are recommended. One such strategy is the application of surface-active chemical inhibitors. The aim of this research was to evaluate the inhibition effectiveness of decanethiol in a CO2-saturated aqueous electrolyte (1 wt% NaCl). The inhibition properties of decanethiol were evaluated by electrochemical measurements (linear polarization resistance, potentiodynamic sweeps, and electrochemical impedance spectroscopy) and the steel surface was characterized by scanning electron microscopy. The obtained data show that decanethiol can successfully prevent corrosion of carbon steels in a CO2 environment. An inhibition mechanism was also proposed based on adsorption characteristics and inhibitor film formation.


2021 ◽  
Vol 63 (11) ◽  
pp. 1018-1024
Author(s):  
Huan Xie ◽  
Xiang Chen ◽  
Yongxin Lu ◽  
Qian Zhang ◽  
Haitao Wang

Abstract A finite element (FE) model is presented in this work that is used to analyze the effect of pitting corrosion on the CO2 corrosion behavior of oil and gas pipeline welds. The FE model contains two parts, i. e., stress calculation of the welded joint using Abaqus software, and of the chemical reaction at the welded joint using COMSOL Multiphysics® software. The effect of transportation pressure, pit depth and welding material on the CO2 corrosion behavior of weld metal was investigated using the FE model. It turned out that the FE model is helpful to instruct the management and to assess the remaining service life prediction of pipelines in the oil and gas industry.


2020 ◽  
Vol 78 (7) ◽  
pp. 861-868
Author(s):  
Casper Wassink ◽  
Marc Grenier ◽  
Oliver Roy ◽  
Neil Pearson

2004 ◽  
pp. 51-69 ◽  
Author(s):  
E. Sharipova ◽  
I. Tcherkashin

Federal tax revenues from the main sectors of the Russian economy after the 1998 crisis are examined in the article. Authors present the structure of revenues from these sectors by main taxes for 1999-2003 and prospects for 2004. Emphasis is given to an increasing dependence of budget on revenues from oil and gas industries. The share of proceeds from these sectors has reached 1/3 of total federal revenues. To explain this fact world oil prices dynamics and changes in tax legislation in Russia are considered. Empirical results show strong dependence of budget revenues on oil prices. The analysis of changes in tax legislation in oil and gas industry shows that the government has managed to redistribute resource rent in favor of the state.


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