scholarly journals Highly Selective and Simple Zero and First Order Derivative Spectrophotometric Determination of Palladium by Using α-Benzilmonoxime in Triton X-100 Micellar Solution

2003 ◽  
Vol 24 (12) ◽  
pp. 1731-1736 ◽  
Keyword(s):  
Spectrophotometric Determination ◽  
Micellar Solution ◽  
Simple Zero ◽  
Order Derivative ◽  
First Order ◽  
Triton X

First Order Derivative Spectrophotometric Determination of Thorium in Geological Samples Using Diacetylmonoxime p-hydroxybenzoylhydrazone

2012 ◽  
Vol 11 (1) ◽  
pp. 15-30
Author(s):  
Anitha Varghese ◽  
A M A Khadar
Keyword(s):  
Spectrophotometric Method ◽  
Molar Absorptivity ◽  
Order Derivative ◽  
Geological Samples ◽  
Trace Level ◽  
First Order ◽  
Quantitation Limit ◽  
Triton X ◽  
Trace Level Determination

A simple, selective and sensitive spectrophotometric method has been developed for the determination of trace amounts of thorium using a newly synthesised reagent diacetylmonoximep-hydroxybenzoylhydrazone (DMPHBH) in the presence of Triton X-100. The molar absorptivity and Sandell’s sensitivity of the coloured species at pH 4.4 were found to be 4.20 x 104 L mol-1 cm-1 and 5.5 ng cm-2, respectively. Beer’s law is obeyed in the range 0.35 -3.8 mg mL-1 of thorium(IV) at 410 nm. The stoichiometry of the complex was found to be 1:2 (Th(IV): DMPHBH). A highly selective first order derivative spectrophotometric method for the determination of thorium in the presence of uranium is also reported. The detection limit and quantitation limit of first order derivative spectrophotometry were found to be 0.03 and 0.11 mg mL-1, respectively. The developed procedure has been successfully applied for the trace level determination of thorium in rock samples and synthetic mixtures.

scholarly journals Derivative spectrophotometric determination of acetamiprid in the presence of 6-chloronicotinic acid

2012 ◽  
Vol 77 (7) ◽  
pp. 911-917 ◽  
Author(s):  
Valéria Guzsvány ◽  
Sanja Lazic ◽  
Natasa Vidakovic ◽  
Zsigmond Papp
Keyword(s):  
Simultaneous Determination ◽  
Spectrophotometric Determination ◽  
Spectrophotometric Method ◽  
Detection Limits ◽  
Model Systems ◽  
Order Derivative ◽  
Zero Crossing ◽  
First Order ◽  
Relative Standard

A simple first-order derivative spectrophotometric method was developed for the simultaneous determination of acetamiprid and 6-chloronicotinic acid (6-CNA) at pH 7.0. By using the zero-crossing approach, acetamiprid was determined at 269.0 nm and 6-CNA at 216.0 nm with the detection limits of 7.19x10-7 and 8.25x10-7 mol dm-3, respectively and relative standard deviations not exceeding 1.2% in the case of model systems.

APPLICATION OF UV-SPECTROPHOTOMETRY FOR DETERMINATION OF ZILEUTON IN BULK AND IN TABLETS

INDIAN DRUGS ◽  
2013 ◽  
Vol 50 (06) ◽  
pp. 40-44
Author(s):  
S. B. Ganorkar ◽  
◽  
D. M Dhumal ◽  
A. A Shirkhedkar
Keyword(s):  
Simple Zero ◽  
Zero Order ◽  
Order Derivative ◽  
Uv Spectrophotometry ◽  
Active Inhibitor ◽  
First Order ◽  
Ich Guidelines ◽  
Orally Active ◽  
Derivative Uv Spectrophotometry

Zileuton is an orally active inhibitor of 5-lipoxygenase and found to inhibit leukotrienes (LTB4 , LTC4, LTD4 , and LTE4) formation and well-known for the effective treatment of asthma. Rapid, economical and simple ‘Zero order UV-spectrophotometry’ and ‘First order derivative UV-spectrophotometry’ have been developed for estimation zileuton in bulk and in-house tablets. Zileuton showed maximum absorbance at 258.4 nm in 0.01M NaOH. For Zero order UV-spectrophotometric method (Method I), two wavelengths 243.4 nm and 271.0 nm were selected for the determination of area under curve (AUC). In First order derivative UV-spectrophotometry (Method II), two wavelengths 260.0 nm and 279.60 nm were selected for determination of AUC. For both these methods, zileuton followed linearity in the concentration range of 4 - 24 µg/ mL with correlation coefficient value of 0.999. Both methods were validated as per ICH guidelines.

scholarly journals UV Spectrophotometric Simultaneous Determination of Paracetamol and Ibuprofen in Combined Tablets by Derivative and Wavelet Transforms

2014 ◽  
Vol 2014 ◽  
pp. 1-13 ◽  
Author(s):  
Vu Dang Hoang ◽  
Dong Thi Ha Ly ◽  
Nguyen Huu Tho ◽  
Hue Minh Thi Nguyen
Keyword(s):  
Simultaneous Determination ◽  
Wavelet Transforms ◽  
Hybrid Approach ◽  
Uv Spectra ◽  
Order Derivative ◽  
First Order ◽  
Spectrophotometric Methods ◽  
Combined Use ◽  
Linear Concentration

The application of first-order derivative and wavelet transforms to UV spectra and ratio spectra was proposed for the simultaneous determination of ibuprofen and paracetamol in their combined tablets. A new hybrid approach on the combined use of first-order derivative and wavelet transforms to spectra was also discussed. In this application, DWT (sym6 and haar), CWT (mexh), and FWT were optimized to give the highest spectral recoveries. Calibration graphs in the linear concentration ranges of ibuprofen (12–32 mg/L) and paracetamol (20–40 mg/L) were obtained by measuring the amplitudes of the transformed signals. Our proposed spectrophotometric methods were statistically compared to HPLC in terms of precision and accuracy.

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