scholarly journals Synthesis and Spectroscopic Characterization of Manganese(II), Iron(III) and Cobalt(III) Complexes of Macrocyclic Ligand. Potential of Cobalt(III) Complex in Biological Activity

2011 ◽  
Vol 55 (6) ◽  
pp. 919-925 ◽  
Author(s):  
Abdou S. El-Tabl ◽  
Mohamad M.E. Shakdofa ◽  
Ahmed M.A. El-Seidy
2001 ◽  
Vol 23 (1) ◽  
pp. 35-40 ◽  
Author(s):  
Maritza Díaz ◽  
Irene Lezcano ◽  
Jesús Molerio ◽  
Frank Hernández

2017 ◽  
Vol 57 (3) ◽  
Author(s):  
Ignacio E. León ◽  
Susana B. Etcheverry ◽  
Beatriz S. Parajón-Costa ◽  
Enrique J. Baran

The oxovanadium(IV) complex of oxodiacetic acid (H<sub>2</sub>ODA) and 2,2’-bipyridine (bipy) of stoichiometry [VO(ODA)(bipy)]⋅H<sub>2</sub>O, was thoroughly characterized by infrared, Raman and electronic spectroscopies. The biological activity of the complex on the cell proliferation was tested on osteoblast-like cells (MC3T3E1 osteoblastic mouse calvaria-derived cells and UMR106 rat osteosarcoma-derived cells) in culture. The complex caused inhibition of cellular proliferation in both osteoblast-like cells in culture, but its action was statistically stronger in the tumoral cells. This effect was specially marked with increasing concentrations of the complex. Based on these preliminary biological results, [VO(ODA)(bipy)]⋅H<sub>2</sub>O can be considered as a good candidate to be further investigated in relation to cancer treatment.


2016 ◽  
Vol 40 (2) ◽  
pp. 101-108
Author(s):  
Md Mahbubul Alam ◽  
Ramkrishna Saha ◽  
Md Rezwan Miah ◽  
Belal Ahmed ◽  
Iqbal Ahmed Siddiquey

Rhodizonic acid (H2RHOD) was reacted with Co(PF6)2.6H2O in the presence of pyridine modified large macrocyclic ligand (H2Lopy) and triethylamine in N,N-dimethylformamide under argon atmosphere. Instead of [Co4(RHOD)2(Lopy)](PF6)2 (1), the main product of this reaction was a crystalline compound [Co4(CROC)2(Lopy)](PF6)2, which was isolated in low yield (< 25%). Based on the elemental analysis, ESI-mass spectroscopy, and infrared spectrum, the isolated compound was confirmed to be [Co4(CROC)2(Lopy)](PF6)2 (2), where CROC2- is croconate anion C5O52-.Journal of Bangladesh Academy of Sciences, Vol. 40, No. 2, 101-108, 2016


2019 ◽  
Vol 35 (4) ◽  
pp. 475-484
Author(s):  
SHIVA ARUN ◽  
◽  
PRABHA BHARTIYA ◽  
AMREEN NAZ ◽  
SUDHEER RAI ◽  
...  

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