Development of Efficient Nitroxyl Radical-Catalyzed Oxidation Systems —Selective Oxidation from Primary Alcohols to Carboxylic Acids—

2016 ◽  
Vol 74 (10) ◽  
pp. 965-974
Author(s):  
Masatoshi Shibuya
Keyword(s):  
Carboxylic Acids ◽  
Selective Oxidation ◽  
Nitroxyl Radical ◽  
Primary Alcohols ◽  
Catalyzed Oxidation

ChemInform Abstract: A Novel Chromium Trioxide Catalyzed Oxidation of Primary Alcohols to the Carboxylic Acids.

ChemInform ◽  
2010 ◽  
Vol 29 (42) ◽  
pp. no-no
Author(s):  
M. ZHAO ◽  
J. LI ◽  
Z. SONG ◽  
R. DESMOND ◽  
D. M. TSCHAEN ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Chromium Trioxide ◽  
Primary Alcohols ◽  
Catalyzed Oxidation

scholarly journals A green and sustainable phosphine-free NHC-ruthenium catalyst for selective oxidation of alcohols to carboxylic acids in water

2015 ◽  
Vol 44 (39) ◽  
pp. 17409-17414 ◽  
Author(s):  
Jagadeesh Malineni ◽  
Helmut Keul ◽  
Martin Möller
Keyword(s):  
Oxygen Atom ◽  
Carboxylic Acids ◽  
Selective Oxidation ◽  
Direct Synthesis ◽  
Ruthenium Catalyst ◽  
Catalytic Dehydrogenation ◽  
Oxidizing Agent ◽  
Primary Alcohols ◽  
Oxidation Of Alcohols ◽  
Atom Source

An efficient novel protocol is applied for direct synthesis of carboxylic acids from primary alcohols through catalytic dehydrogenation. This reaction occurs in water as the solvent and as the oxygen-atom source and no toxic oxidizing agent is involved.

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