Review of: Aircraft vertical profiles during summertime regional and Saharan dust scenarios over the north-western Mediterranean Basin: aerosol optical and physical properties

Abstract. Accurate measurements of the horizontal and vertical distribution of atmospheric aerosol particle optical properties are key for a better understanding of their impact on the climate. Here we present the results of a measurement campaign based on instrumented flights over NE Spain. We measured vertical profiles of size segregated atmospheric particulate matter (PM) mass concentrations and multi-wavelength scattering and absorption coefficients in the Western Mediterranean Basin (WMB). The campaign took place during typical summer conditions, characterized by the development of a vertical multi-layer structure, under both summer regional pollution episodes (REG) and Saharan dust events (SDE). REG patterns in the region form under high insolation and scarce precipitation in summer, favoring layering of highly-aged fine PM strata in the lower few km a.s.l. The REG scenario prevailed during the entire measurement campaign. Additionally, African dust outbreaks and plumes from North African wildfires influenced the study area. The vertical profiles of climate relevant intensive optical parameters such as single scattering albedo (SSA), asymmetry parameter (g), scattering, absorption and SSA Angstrom exponents (SAE, AAE, SSAAE), and PM mas scattering and absorption cross sections (MSC and MAE) were derived from the measurements. Moreover, we compared the aircraft measurements with those performed at two GAW/ACTRIS surface measurement stations located in NE Spain, namely: Montseny (MSY; regional background) and Montsec d'Ares (MSA; remote site). Airborne in-situ measurements and ceilometer ground-based remote measurements identified aerosol air masses at altitude up to more than 3.5 km a.s.l. The vertical profiles of the optical properties markedly changed according to the prevailing atmospheric scenarios. During SDE the SAE was low along the profiles, reaching values 2.0 and the asymmetry parameter g was rather low (0.5–0.6) due to the prevalence of fine PM which were characterized by an AAE close to 1.0 suggesting a fossil fuel combustion origin. During REG, some of the layers featured larger AAE (> 1.5), relatively low SSA at 525 nm ( 9 m2 g−1) and were associated to the influence of PM from wildfires. Overall, the SSA and MSC near the ground ranged around 0.85 and 3 m2 g−1, respectively and increased at higher altitudes, reaching values above 0.95 and up to 9 m2 g−1. The PM, MSC and MAE were on average larger during REG compared to SDE due to the larger scattering and absorption efficiency of fine PM compared with dust. The SSA and MSC had quite similar vertical profiles and often both increased with height indicating the progressive shift toward PM with larger scattering efficiency with altitude. This study contributes to our understanding of regional aerosol vertical distribution and optical properties in the WMB and the results will be useful for improving future climate projections and remote sensing/satellite retrieval algorithms.

Download Full-text

Changes in Carbon Isotope Discrimination in Grain Cereals From the North-Western Mediterranean Basin During the Past Seven Millenia

Functional Plant Biology ◽

10.1071/pp9930117 ◽

1993 ◽

Vol 20 (1) ◽

pp. 117 ◽

Cited By ~ 33

Author(s):

JL Araus ◽

R Buxo

Keyword(s):

Middle Ages ◽

Mediterranean Basin ◽

Carbon Isotope Discrimination ◽

Western Mediterranean ◽

Isotope Discrimination ◽

The North ◽

Western Mediterranean Basin ◽

Use Efficiency ◽

North Western ◽

The Middle Ages

Carbon isotope discrimination (Δ) was determined for kernels of six-row barley and durum wheat cultivated in the north-western Mediterranean basin during the last seven millennia. Samples from the Neolithic, Bronze, Iron and Middle Ages came from different archaeological sites in Catalonia. Samples for the period 1910-20 and 1990 were also analysed. There was a slight decrease (P=0.10, carbonisation-corrected values) in Δ from the Neolithic to the Iron Age period and a much steeper decrease from the Middle Ages to 1910-20 (P<0.01). Since water-use efficiency and isotope discrimination are negatively correlated, from the pattern of change in Δ it is suggested that there has been a progressive increase in the water-use efficiency (WUE) of these cereals. Since the Middle Ages this has coincided with increases in atmospheric CO2 concentration. Thus, for a given relative humidity and air temperature, the estimated WUE (measured as the ratio of CO2 assimilation to transpiration) from the Neolithic to the Middle Ages samples ranged between 65-70% of present time WUE values, whereas WUE for 1910-20 was about 86% of present values.

Download Full-text

Aircraft vertical profiles during summertime regional and Saharan dust scenarios over the north-western Mediterranean basin: aerosol optical and physical properties

Atmospheric Chemistry and Physics ◽

10.5194/acp-21-431-2021 ◽

2021 ◽

Vol 21 (1) ◽

pp. 431-455

Author(s):

Jesús Yus-Díez ◽

Marina Ealo ◽

Marco Pandolfi ◽

Noemí Perez ◽

Gloria Titos ◽

...

Keyword(s):

Optical Properties ◽

Vertical Distribution ◽

Asymmetry Parameter ◽

Mediterranean Basin ◽

Western Mediterranean ◽

Saharan Dust ◽

Vertical Profiles ◽

Measurement Campaign ◽

Western Mediterranean Basin ◽

North Eastern

Abstract. Accurate measurements of the horizontal and vertical distribution of atmospheric aerosol particle optical properties are key for a better understanding of their impact on the climate. Here we present the results of a measurement campaign based on instrumented flights over north-eastern Spain. We measured vertical profiles of size-segregated atmospheric particulate matter (PM) mass concentrations and multi-wavelength scattering and absorption coefficients in the western Mediterranean basin (WMB). The campaign took place during typical summer conditions, characterized by the development of a vertical multi-layer structure, under both summer regional pollution episodes (REGs) and Saharan dust events (SDEs). REG patterns in the region form under high insolation and scarce precipitation in summer, favouring layering of highly aged fine-PM strata in the lower few kma.s.l. The REG scenario prevailed during the entire measurement campaign. Additionally, African dust outbreaks and plumes from northern African wildfires influenced the study area. The vertical profiles of climate-relevant intensive optical parameters such as single-scattering albedo (SSA); the asymmetry parameter (g); scattering, absorption and SSA Ångström exponents (SAE, AAE and SSAAE); and PM mass scattering and absorption cross sections (MSC and MAC) were derived from the measurements. Moreover, we compared the aircraft measurements with those performed at two GAW–ACTRIS (Global Atmosphere Watch–Aerosol, Clouds and Trace Gases) surface measurement stations located in north-eastern Spain, namely Montseny (MSY; regional background) and Montsec d'Ares (MSA; remote site). Airborne in situ measurements and ceilometer ground-based remote measurements identified aerosol air masses at altitudes up to more than 3.5 kma.s.l. The vertical profiles of the optical properties markedly changed according to the prevailing atmospheric scenarios. During SDE the SAE was low along the profiles, reaching values < 1.0 in the dust layers. Correspondingly, SSAAE was negative, and AAE reached values up to 2.0–2.5, as a consequence of the UV absorption increased by the presence of the coarse dust particles. During REG, the SAE increased to > 2.0, and the asymmetry parameter g was rather low (0.5–0.6) due to the prevalence of fine PM, which was characterized by an AAE close to 1.0, suggesting a fossil fuel combustion origin. During REG, some of the layers featured larger AAE (> 1.5), relatively low SSA at 525 nm (< 0.85) and high MSC (> 9 m2 g−1) and were associated with the influence of PM from wildfires. Overall, the SSA and MSC near the ground ranged around 0.85 and 3 m2 g−1, respectively, and increased at higher altitudes, reaching values above 0.95 and up to 9 m2 g−1. The PM, MSC and MAC were on average larger during REG compared to SDE due to the larger scattering and absorption efficiency of fine PM compared with dust. The SSA and MSC had quite similar vertical profiles and often both increased with height indicating the progressive shift toward PM with a larger scattering efficiency with altitude. This study contributes to our understanding of regional-aerosol vertical distribution and optical properties in the WMB, and the results will be useful for improving future climate projections and remote sensing or satellite retrieval algorithms.

Download Full-text

Continental pollution in the Western Mediterranean Basin: vertical profiles of aerosol and trace gases measured over the sea during TRAQA 2012 and SAFMED 2013

Atmospheric Chemistry and Physics Discussions ◽

10.5194/acpd-15-8283-2015 ◽

2015 ◽

Vol 15 (6) ◽

pp. 8283-8328 ◽

Cited By ~ 1

Author(s):

C. Di Biagio ◽

L. Doppler ◽

C. Gaimoz ◽

N. Grand ◽

G. Ancellet ◽

...

Keyword(s):

Urban Areas ◽

Mediterranean Basin ◽

Trace Gases ◽

Western Mediterranean ◽

Saharan Dust ◽

Vertical Profiles ◽

Free Troposphere ◽

Aerosol Formation ◽

Western Mediterranean Basin ◽

Wide Range

Abstract. In this study we present airborne observations of aerosol and trace gases obtained over the sea in the Western Mediterranean Basin during the TRAQA (TRansport and Air QuAlity) and SAFMED (Secondary Aerosol Formation in the MEDiterranean) campaigns in summers 2012 and 2013. A total of 23 vertical profiles were measured up to 5000 m a.s.l. over an extended area (40–45° N latitude and 2° W–12° E longitude) including the Gulf of Genoa, Southern France, the Gulf of Lion, and the Spanish coast. TRAQA and SAFMED successfully measured a wide range of meteorological conditions which favoured the pollution export from different sources located around the basin. Also, several events of dust outflows were measured during the campaigns. Observations from the present study indicate that continental pollution largely affects the Western Mediterranean both close to coastal regions and in the open sea as far as ~250 km from the coastline. Aerosol layers not specifically linked with Saharan dust outflows are distributed ubiquitously which indicates quite elevated levels of background pollution throughout the Western Basin. The measured aerosol scattering coefficient varies between ~20 and 120 M m−1, while carbon monoxide (CO) and ozone (O3) mixing ratios are in the range of 60–170 and 30–85 ppbv, respectively. Pollution reaches 3000–4000 m in altitude and presents a very complex and highly stratified structure characterized by fresh and aged layers both in the boundary layer and in the free troposphere. Within pollution plumes the measured particle concentration in the Aitken (0.004–0.1 μm) and accumulation (0.1–1.0 μm) modes is between $\\sim 100$ and 5000–6000 s cm−3 (standard cm−3), which is comparable to the aerosol concentration measured in continental urban areas. Additionally, our measurements indicate the presence of highly concentrated Aitken layers (10 000–15 000 s cm−3) observed both close to the surface and in the free troposphere, possibly linked to the influence of new particle formation (NPF) episodes over the basin.

Download Full-text